Abstract
The rates of benzene hydrogenation and of n-heptane hydroconversion were measured simultaneously over a series of bifunctional catalysts. The catalysts were Y zeolites containing a Ni or Mo sulfide. At 280 °C, and for the more acidic catalysts, both rates appeared linearly correlated, suggesting that the hydrogenation function was limiting.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
W. Döhler, in:Proc. 8th Int. Congr. in Catalysis (Verlag Chemie, 1984) Vol. III, 499.
P. Dufresne and C. Marcilly, US Patent 4738940 (1988).
T.Y. Yan, Ind. Eng. Chem. Res. 29 (1990) 1995.
A.A. Martin, J.K. Chen, V.T. John and D.B. Dadybarjor, Ind. Eng. Chem. Res. 28 (1989) 1613.
J.A. Martens, P.A. Jacobs and J. Weitkamp, Appl. Catal, 20 (1986) 283.
J. Leglise, A. Janin, J.C. Lavalley and D. Cornet, J. Catal. 114 (1988) 388.
S. Delahaie, A. Chambellan, D. Cornet and J.F. Hémidy, in:Perspectives in Molecular Sieves Science, eds. W.H. Flanck and T.E. Whyte, ACS Symp. Ser., 368 (1988) 579.
J. Lynch, F. Raatz and P. Dufresne, Zeolites 7 (1987) 333.
A. Ezzamarty, E. Catherine, D. Cornet, J.F. Hémidy, A. Janin, J.C. Lavalley, J. Leglise and P. Mériaudeau, in:Zeolites, Facts, Figures, Future, eds. P.A. Jacobs and R.A. Van Santen (Elsevier, 1989) 1025.
J. Weitkamp, in:Hydrocracking and Hydrotreating, ed. J.W. Ward, ACS Symp. Ser. 20 (1975) 1.
M.I. Vasquez, A. Escardino and A. Aucejo, Can. J. Chem. Eng. 66 (1988) 313.
G.E. Giannetto, G.R. Perot and M.R. Guisnet, Ind. Eng. Chem. Prod. Res. Dev. 25 (1986) 481.
D. Barthomeuf, Mat. Chem. Phys. 17 (1987) 49.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Leglise, J., el Qotbi, M., Goupil, J.M. et al. Competitive reactions catalyzed by NiMo-containing zeolites. Catal Lett 10, 103–109 (1991). https://doi.org/10.1007/BF00764741
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00764741