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Kinetics of the mediatory reduction ofgem-dichlorocyclopropanes

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The effect of the nature of organic electron transfer agents and of PtII, PdII, RhII, CoII, NiII, CuII, CrIII, MnII, TiIII, VIII, ZnII, and AgI metal ions on the kinetics of the homogeneous reduction ofgem-dichlorocyclopropanes has been studied. PtII, PdII, RhIII, CoII, and NiII ions accelerate this process, VIII and AgI ions exert practically no effect on the reduction rate, and the rest of the metal ions exhibit inhibitor properties.

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References

  1. V. V. Yanilkin, N. I. Maksimyuk, E. I. Gritsenko, and Yu. M. Kargin,Izv. Akad. Nauk SSSR, Ser. Khim., 1991,261 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991,40, 241 (Engl. Transl.)].

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan', Russian Federation

    V. V. Yanilkin, N. I. Maksimyuk, E. I. Strunskaya, B. M. Garifullin & Yu. M. Kargin

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  1. V. V. Yanilkin
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  2. N. I. Maksimyuk
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  3. E. I. Strunskaya
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  4. B. M. Garifullin
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  5. Yu. M. Kargin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1407–1410, August, 1993.

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Yanilkin, V.V., Maksimyuk, N.I., Strunskaya, E.I. et al. Kinetics of the mediatory reduction ofgem-dichlorocyclopropanes. Russ Chem Bull 42, 1340–1343 (1993). https://doi.org/10.1007/BF00699927

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  • DOI: https://doi.org/10.1007/BF00699927

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