Skip to main content
SpringerLink
Log in

Carbyne — the third allotropic form of carbon

  • Reviews
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The history of the discovery of carbyne, the chemical and physical methods used to obtain it, the analysis of its structure, and some of its properties are briefly considered. The prospects for its practical applications are discussed

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. I. Man, Yu. A. Malinovskiy, and S. A. Semiletov,Kristallograftya, 1990,35, 1029 (in Russian).

    Google Scholar 

  2. V. I. Kasatochkin,Structural Chemistry of Carbon and Coals, Ed. V. I. Kasatochkin, Nauka, Moscow, 1969, 7 (in Russian).

    Google Scholar 

  3. Acc. Chem. Res., 1992,25, No.3 (special issue on fullerenes).

  4. Proc.5th London Int. Carbon Graphite Conf., 1978,3 (Publ. 1979), 104.

  5. A. Baeyer,Ber., 1885,18, 674, 2269.

    Google Scholar 

  6. V. V. Vil'yams, V. S. Smirnov, and V. P. Gol'mov,Zh. Obshch. Khim., 1935,5, 1195 [J. Gen. Chem. USSR, 1935, 5 (Engl. Transl.)].

    Google Scholar 

  7. J. D. Bu'Lock,Q. Rev. Chem. Soc., 1956,10, 371.

    Google Scholar 

  8. G. Nakaminami,J. Soc. Org. Synth. Chem., Jpn., 1963,21, 751.

    Google Scholar 

  9. C. Glaser,Ann. Chem., 1870,154, 137.

    Google Scholar 

  10. Yu. P. Kudryavtsev,Progress of Polymer Chemistry, Ed. V. V. Korshak, Nauka, Moscow, 1969, 87 (in Russian).

    Google Scholar 

  11. V. V. Korshak, A. M. Sladkov, and Yu. P. Kudryavtsev,Vysokomol. Soedin., 1960,2, 1824 [Polymer Sci. USSR 1960,2 (in Russian)].

    Google Scholar 

  12. V. V. Korshak, V. I. Kasatochkin, A. M. Sladkov, Yu. P. Kudryavtsev, and K. Usenbaev,Dokl. Akad. Nauk SSSR, 1961,136, 1342 [Docl. Chem., 1961,136 (Engl. Transl.)].

    Google Scholar 

  13. R. Eastmond, T. R. Johnson, and D. R. M. Walton,Tetrahedron, 1972,28, 4601.

    Google Scholar 

  14. A. M. Sladkov and Yu. P. Kudryavtsev,Priroda, 1964, No. 5, 88 (in Russian).

    Google Scholar 

  15. V. V. Korshak, A. M. Sladkov, Yu. P. Kudryavtsev, and V. I. Kasatochkin,Vestn. Akad. Nauk SSSR, 1968, 89 (in Russian).

  16. A. M. Sladkov, V. I. Kasatochkin, Yu. P. Kudryavtsev, and V. V. Korshak,Izv. Akad. Nauk SSSR, Ser. Khim., 1968, 2697 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1968,17 (Engl. Transl.)].

  17. V. I. Kasatochkin, A. M. Sladkov, Yu. P. Kudryavtsev, and V. V. Korshak,Structural Chemistry of Carbon and Coals, Ed. V. I. Kasatochkin, Nauka, Moscow, 1969, 17 (in Russian).

    Google Scholar 

  18. A. M. Sladkov and Yu. P. Kudryavtsev,Priroda, 1969, No. 5, 37 (in Russian).

    Google Scholar 

  19. V. V. Korshak, Yu. P. Kudryavtsev, and A. M. Sladkov,Vestn. Akad. Nauk SSSR, 1978, 70 (in Russian).

  20. V. I. Kasatochkin, A. M. Sladkov, Yu. G. Aseev, Yu. P. Kudryavtsev, O. I. Egorova, and V. V. Korshak,Dokl. Akad. Nauk SSSR, 1963, 153, 346 [Docl. Chem., 1963,153 (Engl. Transl.)].

    Google Scholar 

  21. I. P. Sergushin, Yu. P. Kudryavtsev, V. M. Elizen, A. P. Sadovskiy, A. M. Sladkov, V. I. Nefedov, and V. V. Korshak,Zh. Strukt. Khim., 1977,18, 598 [J. Struct. Chem., 1977,18 (Engl. Transl.)].

    Google Scholar 

  22. V. I. Kasatochkin, A. M. Sladkov, Yu. P. Kudryavtsev, N. M. Popov, and V. V. Korshak,Dokl. Akad. Nauk SSSR, 1967,177, 358 [Docl. Chem., 1967,177 (Engl. Transl.)].

    Google Scholar 

  23. V. I. Kasatochkin, V. V. Korshak, Yu. P. Kudryavtsev, A. M. Sladkov, and L. E. Sterenberg,Carbon, 1973,11, 70.

    Google Scholar 

  24. V. I. Kasatochkin, V. V. Korshak, Yu. P. Kudryavtsev, A. M. Sladkov, and V. M. Elizen,Dokl. Akad. Nauk SSSR, 1974,214, 587 [Docl. Chem., 1974,214 (Engl. Transl.)].

    Google Scholar 

  25. A. M. Sladkov, V. I. Kasatochkin, V. V. Korshak, and Yu. P. Kudryavtsev, No. 107,Byull. Izobret., 1972, No. 6, 3 (in Russian).

    Google Scholar 

  26. A. M. Sladkov, V. V. Korshak, and V. P. Nepochatykh,Izv. Akad. Nauk SSSR, Ser. Khim., 1968, 196 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1968,17, No. 1 (Engl. Transl.)].

    Google Scholar 

  27. A. M. Sladkov, B. V. Lokshin, V. P. Nepochatykh, and V.V. Korshak,Vysokomol. Soedin. Ser. A, 1968,10, 1312 [Polymer Sci. USSR, 1968,10 (in Russian)].

    Google Scholar 

  28. S. E. Evsyukov, Yu. P. Kudryavtsev, and Yu. V. Korshak,Usp. Khim., 1991,60, 764 [Russ.Chem. Rev., 1991,60 (Engl. Transl.)].

    Google Scholar 

  29. V. V. Korshak, Yu. P. Kudryavtsev, Yu. V. Korshak, S. E. Evsyukov, V. V. Khvostov, V. G. Babaev, and M. B. Guseva,Makromol. Chem., Rapid Commun., 1988,9, 135.

    Google Scholar 

  30. S. E. Evsyukov, Yu. P. Kudryavtsev, Yu. V. Korshak, V. V. Khvostov, V. G. Babaev, M. B. Guseva, and V. V. Korshak,Vysokomol. Soedin. Ser. A, 1989,31, 27 [Polymer Sci. USSR, 1989, 31 (Engl. Transl.)].

    Google Scholar 

  31. V. V. Korshak, Yu. P. Kudryavtsev, S. E. Evsyukov, Yu. V. Korshak, V. V. Khvostov, V. G. Babaev, and M. B. Guseva,Dokl. Akad. Nauk SSSR, 1988,300, 889 [Docl. Chem., 1988,300 (Engl. Transl.)].

    Google Scholar 

  32. S. E. Evsyukov,Ph. D. Thesis, Istitute of Organoelement Compounds, Moscow, 1990 (in Russian).

    Google Scholar 

  33. V. V. Korshak, Yu. P. Kudryavtsev, G. D. Litovchenko, and O. B. Varfolomeeva,Dokl. Akad. Nauk SSSR, 1985,283, 1411 [Docl. Chem., 1985,283 (Engl. Transl.)].

    Google Scholar 

  34. Yu. P. Kudryavtsev, S. E. Evsyukov, and V. G. Babaev,Izv. Akad. Nauk SSSR, Ser. Khim., 1992, 1223 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1992,41, 966 (Engl. Transl.)].

    Google Scholar 

  35. V. V. Korshak, Yu. P. Kudryavtsev, S. E. Evsyukov, Yu. V. Korshak, M. B. Guseva, V. G. Babaev, and B. M. Kostishko,Docl. Akad. Nauk SSSR, 1988,298, 1421 [Docl. Chem., 1988,298 (Engl. Transl.)].

    Google Scholar 

  36. V. V. Berdyugin, Yu. P. Kudryavtsev, S. E. Evsyukov, Yu.V. Korshak, P. P. Shorygin, and V. V. Korshak,Dokl. Akad. Nauk SSSR, 1989,305, 362 [Docl. Chem., 1989,305 (Engl. Transl.)].

    Google Scholar 

  37. V. V. Korshak, Yu. P. Kudryavtsev, V. V. Khvostov, M. B. Guseva, V. G. Babaev, and O. Yu. Rylova,Dokl. Akad. Nauk SSSR, 1987,293, 393 [Docl. Chem., 1987,293 (Engl. Transl.)].

    Google Scholar 

  38. V. V. Korshak, Yu. P. Kudryavtsev, V. V. Khvostov, M. B. Guseva, V. G. Babaev, and O. Yu. Rylova,Carbon, 1987,25, 735.

    Google Scholar 

  39. Yu. P. Kudryavtsev, S. E. Evsyukov, V. G. Babaev, M. B. Guseva, V. V. Khvostov, and L. M. Krechko,Carbon, 1992,30, 213.

    Google Scholar 

  40. I. A. Udod, B. M. Bulychev, V. I. Shchurik, S. P. Sirotinkin, V. G. Babaev, M. B. Guseva, Yu. P. Kudryavtsev, and S. E. Evsyukov,Dokl. Akad. Nauk, 1992,326, 668 [Docl. Chem., 1992,326 (Engl. Transl.)].

    Google Scholar 

  41. Yu. N. Nikulin, V. M. Melnitchenko, Yu. P. Kudryavtsev, and A. M. Sladkov,Dokl. Akad. Nauk SSSR, 1981,256, 1162 [Docl. Chem., 1981,256 (Engl. Transl.)].

    Google Scholar 

  42. Yu. N. Nikulin, V. M. Melnitchenko, Yu. P. Kudryavtsev, and A. M. Sladkov,Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 1943 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981,30, 1593 (Engl. Transl.)].

    Google Scholar 

  43. K. A. Osipov, G. E. Folmanis, Yu. N. Lozinskiy, and A. M. Sladkov,Izv. Akad. Nauk SSSR, Neorganich. Mater., 1973,9, 1067 (in Russian).

    Google Scholar 

  44. V. I. Kasatochkin, M. E. Kazakov, V. V. Savranskiy, A. P. Nabatnikov, and N. P. Radimov,Dokl. Akad. Nauk SSSR, 1971,201, 1104 [Docl. Chem., 1971,201 (Engl. Transl.)].

    Google Scholar 

  45. V. I. Kasatochkin, V. V. Savranskiy, B. N. Smirnov, and V.M. Melnitchenko,Dokl. Akad. Nauk SSSR, 1974,217, 796 [Docl. Chem., 1974,217 (Engl. Transl.)].

    Google Scholar 

  46. V. M. Melnitchenko, B. N. Smimov, V. P. Varlakov, Yu.N. Nikulin, and A. M. Sladkov,Carbon, 1983,21, 131.

    Google Scholar 

  47. M. B. Guseva,Izv. Akad. Nauk SSSR, Ser. Fiz., 1986,50, 459 (in Russian).

    Google Scholar 

  48. M. B. Guseva, V. G. Babaev, N. N. Nikiforova, and N. F. Savchenko,Vopr. At. Nauki Tekhn., Ser. Fiz. Radiats. Povrezhdenii. Radiats. Materialoved., 1983, 92 (in Russian).

  49. N. F. Savchenko, M. B. Guseva, V. G. Babaev, and L. S. Palatnik,Poverkhnost′. Fizika, Khimiya, Mekhanika, 1985, No. 6, 106 (in Russian).

    Google Scholar 

  50. M. B. Guseva, N. F. Savchenko, and V. G. Babaev,Radiat. Eff. Lett., 1986,87, 215.

    Google Scholar 

  51. L. S. Palatnik, M. B. Guseva, V. G. Babaev, N. F. Savchenko, and I. I. Fal'ko,Zh. Eksp. Theor. Fiz., 1984,87, 914 (in Russian).

    Google Scholar 

  52. M. B. Guseva,Ion Implantation in Semiconductors and Other Materials, Vil'nyus, 1985, 263 (in Russian).

  53. M. B. Guseva, N. F. Savchenko, and V. G. Babaev,Dokl. Akad. Nauk SSSR, 1985,283, 1336 [Docl. Chem., 1985,283 (Engl. Transl.)].

    Google Scholar 

  54. M. J. Rice, S. R. Phillpot, A. R. Bishop, and D. K. Campbell,Phys. Rev., B., 1986,34, 4139.

    Google Scholar 

  55. N. N. Nikiforova and M. B. Guseva,Secondary-Ion and Ion-Photon Emission: Proc. All-Union Conf., Khar'kov, 1983, 30 (in Russian).

  56. K. S. Pitzer and E. Clementi,J. Am. Chem. Soc., 1959,81, 4477.

    Google Scholar 

  57. V. V. Khvostov, V. G. Babaev, and M. B. Guseva,Fiz. Tverd. Tela, 1985,27, 887 (in Russian).

    Google Scholar 

  58. V. V. Khvostov, M. B. Guseva, V. G. Babaev, and O. Yu.Rylova,Surf. Sci. Lett., 1986,169, L253.

    Google Scholar 

  59. J. M. Ziman,Principles of the Theory of Solids, Cambridge, 1972, 259.

  60. R. B. Heimann, J. Kleiman, and N. M. Salansky,Carbon, 1984,22, 147.

    Google Scholar 

  61. V. I. Kasatochkin, V. M. Melnitchenko, V. M. and Elizen,Vysokomol. Soedin., Ser. A., 1975,17, 1883 [Polymer Sci. USSR, 1975,17 (Engl. Transl.)].

    Google Scholar 

  62. Ya. M. Paushkin, L. M. Burova, A. M. Sladkov, V. P. Nepochatykh, Yu. P. Kudryavtsev, and V. V. Korshak,Dokl. Akad. Nauk SSSR, 1968,180, 622 [Docl. Chem., 1968, 180 (Engl. Transl.)].

    Google Scholar 

  63. Ya. M. Paushkin, I. S. Panidi, N. V. Ryabtseva, A. M. Sladkov, and Yu. P. Kudryavtsev,Dokl. Akad. Nauk SSSR, 1970,195, 101 [Docl. Chem., 1970,195 (Engl. Transl.)].

    Google Scholar 

  64. V. S. Myl'nikov, A. M. Sladkov, Yu. P. Kudryavtsev, L. K. Luneva, V. V. Korshak, and A. N. Terenin,Dokl. Akad. Nauk SSSR, 1962,195, 840 [Docl. Chem., 1962,195 (Engl. Transl.)].

    Google Scholar 

  65. V. M. Bentsa, V. S. Myl'nikov, F. I. Vilesov, Yu. P. Kudryavtsev, and A. M. Sladkov,Izv. Akad. Nauk SSSR, Ser. Khim., 1970, 955 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1970,19, 911 (Engl. Transl.)].

  66. V. I. Kasatochkin, A. M. Sladkov, Yu. P. Kudryavtsev, Z. S. Smutkina, T. M. Khrenkova, and V. V. Korshak,Izv. Akad. Nauk SSSR, Ser. Khim., 1963, 1766 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1963,12 (Engl. Transl.)].

    Google Scholar 

  67. I. B. Rabinovich, B. V. Lebedev, A. M. Sladkov, Yu. P. Kudryavtsev, L. Ya. Martynenko, and V. V. Korshak,Dokl. Akad. Nauk SSSR, 1966,168, 599 [Docl. Chem., 1966,168 (Engl. Transl.)].

    Google Scholar 

  68. V. I. Kasatochkin, M. E. Kazakov, Yu. P. Kudryavtsev, A.M. Sladkov, and V. V. Korshak,Dokl. Akad. Nauk SSSR, 1968,183, 109 [Docl. Chem., 1968,183 (Engl. Transl.)].

    Google Scholar 

  69. V. I. Kasatochkin, L. E. Sterenberg, V. N. Slesarev, and Yu. N. Nedoshivin,Dokl. Akad. Nauk SSSR, 1970,194, 801 [Docl. Chem., 1970,194 (Engl. Transl.)].

    Google Scholar 

  70. V. I. Kasatochkin, L. E. Sterenberg, M. E. Kazakov, V. N. Slesarev, and L. V. Beiousova,Dokl. Akad. Nauk SSSR, 1973,209, 388 [Docl. Chem., 1973,209 (Engl. Transl.)].

    Google Scholar 

  71. V. I. Kasatochkin, Z. S. Smutkina, M. E. Kazakov, N. P. Radimov, A. P. Nabatnikov, and T. D. Yares'ko,Dokl. Akad. Nauk SSSR, 1972,205, 1090 [Docl. Chem., 1972,205 (Engl. Transl.)].

    Google Scholar 

  72. K. E. Perepelkin, V. V. Korshak, and V. I. Kasatochkin,Dokl. Akad. Nauk SSSR, 1975,220, 1375 [Docl. Chem., 1975,220 (Engl. Transl.)].

    Google Scholar 

  73. A. S. Grigorian, V. V. Panikarovskiy, T. Khamraev, I. E. Sarkisian, A. I. Isakova, Yu. P. Kudryavtsev, S. E. Evsyukov, and A. F. Aleksandrov,Modem Approaches to the Development of Effective Dressing and Polymer Implants: Proc. 1st M. Conf., Moscow, 1992, 209 (in Russian).

  74. V. I. Kirpatovskiy, Yu. P. Kudryavtsev, I. S. Mudraya, Yu. V. Kudryavtsev, S. E. Evsyukov, V. G. Babaev, and A. F. Aleksandrov,Ibid., 213 (in Russian).

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    Yu. P. Kudryavtsev & S. E. Evsyukov

  2. Department of Physics, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    M. B. Guseva, V. G. Babaev & V. V. Khvostov

Authors
  1. Yu. P. Kudryavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. E. Evsyukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. B. Guseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Babaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Khvostov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This publication is based on a number of works on carbyne submitted for the Russian State Prize in the field of science and technology in 1993; performed at the A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences and the M. V. Lomonosov Moscow State University.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 450–463, March, 1993.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kudryavtsev, Y.P., Evsyukov, S.E., Guseva, M.B. et al. Carbyne — the third allotropic form of carbon. Russ Chem Bull 42, 399–413 (1993). https://doi.org/10.1007/BF00698417

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00698417

Key words

Search

Navigation