Abstract
Calcium borohydride reacts with sodium cyclopentadienyl compounds in tetrahydrofuran solution to give the corresponding calcium cyclopentadienyl complexes. The reaction proceeds easily and gives high yields.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
T. P. Hanusa,Polyhedron, 1990,9, 1345.
L. V. Titov,Zh. Neorg. Khim., 1968,13, 1797 [J. Inorg. Chem., 1968, No. 7 (Engl. Transl.)].
A. P. Borisov and V. D. Makhaev,Metalloorg. Khim., 1989,2, 680 [Organomet. Chem., 1989, No. 2 (Engl. Transl.)].
E. O. Fischer and G. Stolze,Chem. Ber., 1961,94, 2187.
M. G. McCormick, R. A. Williams, L. J. Levine, and T. P. Hanusa,Polyhedron, 1988,7, 725.
A. F. Zhigach and D. S. Stasinevich, inKhimiya Gidridov [Chemistry of Hydrides], Leningrad, Khimiya, 1969, 489 (in Russian).
V. D. Makhaev and A. P. Borisov,Tez. Dokl. V Vsesoyuz. Konf. po Metalloorganicheskoi Khimii [Abstr. Vth All-Union Conf. on Organometallic Chemistry], Riga, 1991, 84.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 377–378, February, 1993.
Rights and permissions
About this article
Cite this article
Borisov, A.P., Makhaev, V.D. Preparation of calcium cyclopentadienyl complexes using calcium borohydride. Russ Chem Bull 42, 339–340 (1993). https://doi.org/10.1007/BF00697091
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00697091