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Thermodynamics of the compression of poly(isobutyl cyanoacrylate) monolayers at acid, neutral and basic pH

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Abstract

Poly(isobutyl cyanoacrylate) (PIBCA) monolayers, unlike those of most substances, respond to increased temperature with a decrease in area per monomer unit and a fall in the surface pressures at which surface phase transition and collapse occur. These effects are associated with an increase in entropy during isothermal compression of the film, and are attributed to the rise in temperature causing loss of solvation water, rather than to increased solubility of PIBCA.

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Authors and Affiliations

  1. Departmento de Quimica Fisica Facultad de Farmacia, Universidad de Santiago, 15706, Santiago de Compostela, La Coruna, Spain

    J. Minones Trillo, E. Yebra-Pimentel, E. Iribarnegaray, O. Conde & M. Casas Parada

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  1. J. Minones Trillo
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  2. E. Yebra-Pimentel
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  3. E. Iribarnegaray
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  4. O. Conde
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  5. M. Casas Parada
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Minones Trillo, J., Yebra-Pimentel, E., Iribarnegaray, E. et al. Thermodynamics of the compression of poly(isobutyl cyanoacrylate) monolayers at acid, neutral and basic pH. Colloid Polym Sci 273, 53–57 (1995). https://doi.org/10.1007/BF00655674

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  • DOI: https://doi.org/10.1007/BF00655674

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