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The relaxation field for the general case of electrolyte mixtures

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Abstract

The relaxation field for solutions of mixed electrolytes of any type is calculated. the calculation is based on the well-known treatment due to Fuoss-Onsager with the same distance parameter for all the ions in solution. A general conductance-continuity equation has been established and an improved iterative method of calculation, using Laplace transforms, is proposed. The relaxation-field results are derived to the second iteration in the perturbation method of integration.

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References

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Authors and Affiliations

  1. Laboratoire de Thermodynamique et Cinétique Chimique, U.E.R. des Sciences Exactes et Naturelles, Université de Clermont-Ferrand 2, B.P., 45-63170, Aubière, France

    J. Quint & A. Viallard

Authors
  1. J. Quint
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  2. A. Viallard
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Quint, J., Viallard, A. The relaxation field for the general case of electrolyte mixtures. J Solution Chem 7, 137–153 (1978). https://doi.org/10.1007/BF00650522

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  • DOI: https://doi.org/10.1007/BF00650522

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