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Excess enthalpies of aqueous solutions of polyols at 25°

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Abstract

The excess enthalpies of aqueous solutions of nine polyols were determined at 25°C and reported in the virial form. The most interesting and new feature of this family of solutes is that the sign of the enthalpic pair interaction coefficients hxx is positive for the first members of the series and negative for the higher homologues. Other points are the large differences found among the values of hxx for stereoisomers, whereas pairs of enantiomers show the same values within experimental errors. An application of the group additivity method is also discussed.

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References

  1. J. J. Savage and R. H. Wood,J. Solution Chem. 5, 733 (1976).

    Google Scholar 

  2. G. Barone, G. Castronuovo, V. Crescenzi, V. Elia, and E. Rizzo,J. Solution Chem. 7, 179 (1978).

    Google Scholar 

  3. G. Barone, G. Castronuovo, V. Elia, and A. Menna,J. Solution Chem. 8, 157 (1979).

    Google Scholar 

  4. G. Barone, P. Cacace, G. Castronuovo, and V. Elia,Gazz. Chim. Ital. 110, 215 (1980).

    Google Scholar 

  5. G. Barone, P. Cacace, G. Castronuovo, and V. Elia,Carbohydr. Res. 91, 101 (1981).

    Google Scholar 

  6. G. Barone, P. Cacace, G. Castronuovo, and V. Elia,Can. J. Chem. 59, 1257 (1981).

    Google Scholar 

  7. H. L. Friedman and C. V. Krishnan,J. Solution Chem. 2, 119 (1973).

    Google Scholar 

  8. F. Franks, inBiochemical Thermodynamics, Vol. I, M. N. Jones, ed., (Elsevier, Amsterdam, 1979).

    Google Scholar 

  9. B. Y. Okamoto, R. H. Wood, and P. T. Thompson,J. Chem. Soc. Faraday Trans. I 74, 1990 (1978).

    Google Scholar 

  10. R. Lumry and S. Rajander, inEnthalpy-entropy Compensation Phenomena in Water Solution and Small Molecules, M. Goodman, ed., (Interscience, New York, 1970).

    Google Scholar 

  11. G. Barone, P. Cacace, G. Castronuovo, and V. Elia,J. Chem. Soc. Faraday Trans. I 77, 1569 (1981).

    Google Scholar 

  12. M. L. Huggins, G. Natta, V. Desreux, and H. Mark,J. Polymer Sci. 56, 153 (1962).

    Google Scholar 

  13. G. Barone and E. Rizzo,Gazz. Chim. Ital. 103, 401 (1973).

    Google Scholar 

  14. G. A. Jeffrey, inCarbohydrate in Solution, Adv. Chem. Series,117, 177 (1972) and the literature quoted therein.

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Authors and Affiliations

  1. Instituto Chimica, University of Naples, via Mezzocannone 4, 80134, Naples, Italy

    Guido Barone, Bruno Bove, Giuseppina Castronuovo & Vittorio Elia

Authors
  1. Guido Barone
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  2. Bruno Bove
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  3. Giuseppina Castronuovo
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  4. Vittorio Elia
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Barone, G., Bove, B., Castronuovo, G. et al. Excess enthalpies of aqueous solutions of polyols at 25°. J Solution Chem 10, 803–809 (1981). https://doi.org/10.1007/BF00649490

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  • DOI: https://doi.org/10.1007/BF00649490

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