Skip to main content
Log in

The aggregation of Span 80 in toluene

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The aggregation equilibria of the non-ionic surfactant Span 80 in toluene has been studied by vapour pressure osmometry (VPO) at different temperatures. The experimental data, treated both graphically and numerically using the LETAGROP-SUMPA program, can be explained by assuming the formation of dimers. The thermodynamics of Span 80 in toluene have also been calculated from the van't Hoff equation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. H. Lee, D. F. Evans, and E. L. Cussler,A.I.Ch.E. Journal 24, 860 (1978).

    Google Scholar 

  2. J. Strzelbicki and W. Charewicz,J. Inorg. Nucl. Chem. 40, 1415 (1978).

    Google Scholar 

  3. D. Melzner, J. Tilkowski, A. Mohrmann, W. Poppe, W. Holwarchs, and K. Schürgerl,Hydrometallurgy 13, 105 (1984).

    Google Scholar 

  4. N. N. Li, US Patent 3410794, (1968).

  5. N. N. Li,Ind. Eng. Chem. Process. Des. Dev. 10, 215 (1971).

    Google Scholar 

  6. J. Paatero, Abo Akademi, Abo, Finland, Report no. 98. Vol 34, no. 10, (1975).

  7. D. Attwood and C. M. McDonald,Colloid & Polymer Sci. 252, 138 (1974).

    Google Scholar 

  8. D. Attwood, C. E. Jagielski, C. McDonald, and A. E. Wilkinson,Colloid & Polymer Sci. 252, 991 (1974).

    Google Scholar 

  9. P. R. Danesi, M. Magini, and G. Scibona,J. Inorg. Nucl. Chem. 30, 2513 (1968).

    Google Scholar 

  10. O. Levy, G. Markovits, and A. S. Kertes,J. Inorg. Nucl. Chem. 33, 551 (1971).

    Google Scholar 

  11. P. R. Danesi, B. De Luca, and P. Susini, in “Solvent Extraction”,Proc.Int. Solv. Extr. Conf., The Hague, eds. J. G. Gregory, B. Evans, and P. C. Weston, (Soc. Chem. Ind., London, 1971), p. 1229.

    Google Scholar 

  12. A. S. Kertes, H. Gutmann, O. Levy, and G. Markovits,Proc. VI Int.Conf.Surface Activity, Zurich, (1972).

  13. M. P. Elizalde, J. M. Castresana, M. Aguilar, and M. Cox,Chemica Scripta 25, 300 (1985).

    Google Scholar 

  14. K. Takashi, F. Ohtsubo and H. Takeuchi,Kagaku Kogaku Ronbunshu 8, 399 (1982).

    Google Scholar 

  15. J. Coello, Licenciat i Teknologi thesis, The Royal Inst. of Technol. Stockholm, (1986).

  16. J. Paatero,Acta. Acad. Aboensis. 34, 1 (1974).

    Google Scholar 

  17. S. Sundstrand, Dept. of Inorg.Chem., The Royal Inst. of Technol. Stockholm, 1975, internal report.

  18. B. Warnqvist,Chemica Scripta 1, 49 (1971).

    Google Scholar 

  19. N. Ingri, W. Kakolowicz, L. G. Sillén, and B. Warnqvist,Talanta 14, 1261 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Almela, A., Elizalde, M.P. & Benito, R. The aggregation of Span 80 in toluene. J Solution Chem 22, 231–241 (1993). https://doi.org/10.1007/BF00649246

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00649246

Key Words

Navigation