Skip to main content
Log in

Viscosity B-coefficients of the aqueous cyanide and azide ions

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

A number of factors have led us to re-examine the literature assignments of the viscosity B-coefficients of the individual cyanide and azide ions in aqueous solutions at 25°C. The revised values, obtained from mutually confirmatory correlations, are: B(CN)=−0.020±0.007 and B(N 3 )=−0.014#±#0.006>dm3-mol−1

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Y. Marcus and A. Loewenschuss,Annu. Rep. C, 1984 81 (1985).

  2. H. L. Friedman and C.V. Krishnan, inWater. A Comprehensive Treatise, Vol. 3, ed. F. Franks, (Plenum, New York, 1973).

    Google Scholar 

  3. G. Engel and H. G. Hertz,Ber. Bunsenges. Phys. Chem. 72, 808 (1968).

    Google Scholar 

  4. G. Jones and M. Dole,J. Am. Chem. Soc. 51, 2950 (1929).

    Google Scholar 

  5. Y. Marcus,Ion Solvation, (Wiley, Chichester, 1985).

    Google Scholar 

  6. R. A. Robinson and R.H. Stokes, 2nd ed.,Electrolyte Solutions, (Butterworth, London, 1959).

    Google Scholar 

  7. E. R. Nightingale, Jr.,J. Phys. Chem. 63, 1381 (1959).

    Google Scholar 

  8. B. S. Krumgalz,Russ. J. Phys. Chem. 47, 956 (1973).

    Google Scholar 

  9. H. D. B. Jenkins and M. S. F. Pritchett,J. Chem. Soc., Faraday Trans. 1 80, 721 (1984).

    Google Scholar 

  10. E.C. Bingham,J. Phys. Chem. 45, 885 (1941).

    Google Scholar 

  11. G. A. Krestov,Thermodynamics of Solvation, (Ellis Horwood, New York, 1991).

    Google Scholar 

  12. R. W. Gurney,Ionic Processes in Solution, (McGraw Hill, New York, 1953).

    Google Scholar 

  13. E. Asmus,Z. Naturf. 4a, 589 (1949).

    Google Scholar 

  14. M. Kaminsky,Z. Naturf. 12a, 424 (1957).

    Google Scholar 

  15. W. M. Cox and J. H. Wolfenden,Proc. Roy. Soc. (London) A145, 475 (1934).

    Google Scholar 

  16. P. K. Mandal, B. K. Seal, and A. S. Basu,Z. Phys. Chem.(NF) 87, 295 (1975).

    Google Scholar 

  17. Y. Marcus,J. Chem. Soc., Faraday Trans. 1 83, 339 (1987).

    Google Scholar 

  18. H. F. Halliwell and S.C. Nyburg,Trans. Faraday Soc. 59, 1126 (1963).

    Google Scholar 

  19. M. J. Pellerite, R.L. Jackson, and J.I. Brauman,J. Phys. Chem. 85, 1624 (1981).

    Google Scholar 

  20. L. H. Ahrens,Geochim. Cosmochim. Acta 2, 155 (1952).

    Google Scholar 

  21. R.D. Shannon and C. T. Prewitt,Acta Cryst. B25, 925 (1969).

    Google Scholar 

  22. K. B. Yatsimirskii,Izv. Akad. Nauk SSSR, Otdel Khim Nauk, 453 (1947); 398 (1948).

  23. A. F. Kapustinskii and K.B. Yatsimirskii,Zh. Obshch. Khim. 19, 2191 (1949); A. F. Kapustinskii,Quart. Rev. (London) 10, 283 (1956).

    Google Scholar 

  24. H. D. B. Jenkins and K.P. Thakur,J. Chem. Educ. 56, 576, (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Donald, H., Jenkins, B. & Marcus, Y. Viscosity B-coefficients of the aqueous cyanide and azide ions. J Solution Chem 22, 95–98 (1993). https://doi.org/10.1007/BF00647058

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00647058

Key words

Navigation