Abstract
Enthalpies of dilution ΔH D of aqueous solutions of the transition metal chlorides CdCl2, CoCl2, CuCl2, MnCl2, and NiCl2 were measured from 1.0 molal to dilute solution at 25°C. The apparent molal enthalpy equations of Pitzer were then fit to the resulting ΔH D data and the parameters for these equations are presented. The heat of dilution data for CdCl2 and CuCl2 were in good agreement with results by other workers.
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Schreiber, D.R., Schreiber, L.C. Thermodynamic properties of transition metals in aqueous solution: 1. The enthalpies of dilution of some aqueous transition metal chloride solutions at 25°C. J Solution Chem 21, 249–259 (1992). https://doi.org/10.1007/BF00647021
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DOI: https://doi.org/10.1007/BF00647021