Abstract
The group contribution concept proposed by Savage and Wood is used for characterization of hydrophobic hydration. A parameter is proposed to measure hydrophobic hydration that has additive properties and can be applied to both nonelectrolytes and electrolytes. Theoretical and practical arguments are given for its use. The given results are in agreement with the published experimental data and theoretical results concerning hydrophobic hydration and interaction.
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References
J. J. Savage and R. H. Wood,J. Solution Chem. 5, 733 (1976).
R. K. Mohanty, T. S. Sarma, S. Subramanian, and J. C. Ahluwalia,Trans. Faraday Soc. 67, 305 (1971).
R. Fuchs and C. P. Hagan,J. Phys. Chem. 77, 1797 (1973).
C. De Visser and G. Somsen,J. Phys. Chem. 76, 1719 (1974).
O. N. Shatnager and A. N. Campbell,Can. J. Chem. 52, 203 (1974).
M. J. Mastroianni, M. J. Pikal, and S. Lindenbaum,J. Phys. Chem. 76, 3050 (1972).
J. S. Falcone and R. H. Wood,J. Solution Chem. 3, 233 (1974).
W. J. M. Heuvelsland, C. De Visser, and G. Somsen,J. Phys. Chem. 82, 29 (1978).
W. J. M. Heuvelsland, C. De Visser, G. Somsen, A. Losurdo, and Wen-Yang Wen,J. Solution Chem. 8, 25 (1979).
W. J. M. Heuvelsland, M. Blomendal, G. De Visser, and G. Somson,J. Phys. Chem. 84, 2391 (1980).
M. Booij and G. Somsen,J. Chem. Soc. Faraday Trans. I 78, 2851 (1982).
Y. Nozaki and C. Tanford,J. Biol. Chem. 246, 2211 (1971).
W. G. McMillan and J. E. Mayer,J. Chem. Phys. 13, 276 (1945).
W. J. M. Heuvelsland, C. De Visser, and G. Somsen,J. Chem. Soc. Faraday Trans. I 77, 1191 (1981).
A. C. Rouw and G. Somsen,J. Chem. Thermodyn.,13, 67 (1981).
S. Cabani, P. Gianni, V. Mollica, and L. Lappori,J. Solution Chem. 10, 56 (1981).
B. Y. Okamoto, R. H. Wood, and P. T. Thompson,J. Chem. Soc., Faraday Trans. I 74, 1990 (1978).
I. R. Tasker and R. H. Wood,J. Solution Chem. 11, 729 (1982).
P. Molyneux and M. Cornarakie-Lentzos,Colloid and Polymer Sci. 257, 855 (1979).
C. Tanford, inThe Hydrophobic Effect, (Wiley, New York, 1973).
G. Nemethy and H. A. Scheraga,J. Phys. Chem. 66, 1773 (1962).
M. H. Abraham,J. Amer. Chem. Soc. 104, 2085 (1982).
A. C. Rouw and G. Somsen,J. Solution Chem. 10, 533 (1981).
G. L. Amidon, S. H. Yalkowsky, S. T. Anik, and S. C. Valvani,J. Phys. Chem. 79, 2239 (1975).
G. L. Amidon and S. T. Anik,J. Pharmaceut. Sci. 65, 801 (1976).
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Cifra, P., Romanov, A. Group contributions and hydrophobic hydration. J Solution Chem 13, 431–441 (1984). https://doi.org/10.1007/BF00644073
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DOI: https://doi.org/10.1007/BF00644073