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Heat capacities of Ar, Ne,4He-Ar, and4He-Ne films adsorbed on Cu at low temperatures

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Abstract

Heat capacities of Ar and Ne monolayers adsorbed on Cu are measurable at 1–4 K. Temperature dependences are similar to the low-temperature law for harmonic oscillators, but the empirical characteristic temperatures of 11–15 K are much lower than can correspond to independent adatoms oscillating in substrate sites. The magnitudes and temperature dependences do not match those predicted for surface modes of an absorbent coated with inert impurities or for the collective modes of epitaxial films. A model involving the excitations in non-epitaxial films appears to offer an explanation of the observed magnitudes and temperature dependences. The heat capacities of4He adsorbed on preplated Ar or Ne show little variation with the number of Ar layers, or between Ar and Ne coatings.

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References

  1. G. A. Stewart and J. G. Dash,Phys. Rev. A2, 918 (1970).

    Google Scholar 

  2. H. Kaplan,Phys. Rev. 125, 1271 (1962).

    Google Scholar 

  3. L. Dobrzynski and D. L. Mills,J. Phys. Chem. Solids 30, 1043 (1969).

    Google Scholar 

  4. R. E. Allen, G. Alldredge, and F. W. de Wette,J. Chem. Phys. 54 (March 1971).

  5. R. E. Peierls,Proc. Natl. Inst. Sci. India 20, 121 (1954). This paper is discussed by M. Born and K. Huang,Dynamical Theory of Crystal Lattices (Oxford, 1956), Appendix IV.

    Google Scholar 

  6. J. E. Lennard-Jones and A. F. Devonshire,Proc. Roy. Soc. (London)A158, 242 (1937).

    Google Scholar 

  7. M. Ross and W. A. Steele,J. Chem. Phys. 35, 862, 871 (1961).

    Google Scholar 

  8. R. Smoluchowski,Phys. Rev. 60, 661 (1941).

    Google Scholar 

  9. N. T. Rhodin,J. Am. Chem. Soc. 72, 5691 (1950).

    Google Scholar 

  10. A. A. Maradudin, E. W. Montroll, and G. H. Weiss, “Theory of Lattice Dynamics in the Harmonic Approximation,” Supp. 3 ofSolid State Physics, F. Seitz and D. Turnbull, eds., (Academic Press, New York, 1963).

    Google Scholar 

  11. S.-C. Ying,Phys. Rev., to be published.

  12. P. W. Palmberg,Surface Sci. 25, 598 (1971).

    Google Scholar 

  13. E. A. Mason and W. E. Rice,J. Chem. Phys. 22, 843 (1954).

    Google Scholar 

  14. G. L. Pollack,Rev. Mod. Phys. 36, 748 (1964).

    Google Scholar 

  15. W. M. Champion and G. D. Halsey,J. Phys. Chem. 57, 646 (1953).

    Google Scholar 

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Research supported by The National Science Foundation.

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Stewart, G.A., Dash, J.G. Heat capacities of Ar, Ne,4He-Ar, and4He-Ne films adsorbed on Cu at low temperatures. J Low Temp Phys 5, 1–16 (1971). https://doi.org/10.1007/BF00628225

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  • DOI: https://doi.org/10.1007/BF00628225

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