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Organic reagents in inverse voltammetry: A review

Organische Reagentien in der Iversen Voltammetrie. Ein Überblick

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Zusammenfassung

Ein Überblick wird gegeben über elektrochemische und Adsorptionsverfahren zur Anreicherung anorganischer Ionen und organischer Verbindungen mit Hilfe organischer Reagentien, die mit den zu bestimmenden Elementen unlösliche Verbindungen auf der Elektrodenoberfläche oder oberflächenaktive Komplexe bilden. Quantitative Messungen beruhen auf der elektrochemischen Oxidation oder Reduktion des an der Elektrode gebildeten Konzentrates. Die behandelten Verfahren umfassen die Inverse Voltammetrie von Ionen variabler Wertigkeit sowie die Inverse Adsorptionsvoltammetrie. Anwendungsbeispiele für die Verwendung organischer Reagentien werden gegeben für Antimon, Iod, Cobalt, Nickel, Cer, Aluminium, Vanadium und Molybdän.

Summary

A review is presented on electrochemical and adsorption processes for the preconcentration of inorganic ions and organic compounds by the use of organic reagents forming with the elements to be determined insoluble compounds on the electrode surface or surface-active complexes. Quantitative determinations are based on the electrochemical oxidation or reduction of the concentrate formed on the electrode. The processes examined comprise inverse voltammetry of variable-valence ions and adsorption inverse voltammetry. Examples are given of the use of organic reagents in the inverse voltammetry of antimony, iodine, cobalt, nickel, cerium, aluminium, vanadium and molybdenum.

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References

  1. Bengston G (1969) Acta Chem Scand 23:448

    Google Scholar 

  2. Berge H, Jeroschewski P (1965) Fresenius Z Anal Chem 207:140

    Google Scholar 

  3. Blum IA (1970) Extractionno-fotometricheskie metody analyza. Moskva, Nauka

    Google Scholar 

  4. Bodforss S, Arhland S, Cigen R (1954) Z Physik Chem 303:73

    Google Scholar 

  5. Brainina KhZ (1964) Dokl Akad Nauk SSSR 154:665

    Google Scholar 

  6. Brainina KhZ (1966) Zh Anal Khim 21:529

    Google Scholar 

  7. Brainina KhZ, Sapozhnikova EYa (1966) Zh Anal Khim 21:807

    Google Scholar 

  8. Brainina KhZ, Sapozhnikova EYa (1966) Zh Anal Khim 21:1342

    Google Scholar 

  9. Brainina KhZ, Krapivkina TA (1967) Zh Anal Khim 22:74

    Google Scholar 

  10. Brainina KhZ, Krapivkina TA (1967) Zh Anal Khim 22:1382

    Google Scholar 

  11. Brainina KhZ, Sapozhnikova EYa (1968) Zh Anal Khim 23:231

    Google Scholar 

  12. Brainina KhZ, Krapivkina TA (1968) Anal Letters 2(5):269

    Google Scholar 

  13. Brainina KhZ (1971) Talanta 18:513

    Google Scholar 

  14. Brainina KhZ, Neiman EYa, Truhacheva LN (1971) Zavodsk Lab 37:16

    Google Scholar 

  15. Brainina KhZ (1972) Inversionnaja voltamperometrija tverdich phaz. Khimia Moskva. Translated into English: Stripping Voltammetry in Chemical Analysis. Halsted Press 1974, New York, Toronto

    Google Scholar 

  16. Brainina KhZ, Tchernyshova AV (1974) Talanta 21:287

    Google Scholar 

  17. Brainina KhZ, Fedorova ND, Fokina LS (1974) Zh Anal Khim 29:254

    Google Scholar 

  18. Brainina KhZ, Tchernyshova AV (1975) Gidrochim Mater 62:119

    Google Scholar 

  19. Brainina KhZ, Tchernyshova AV (1976) Zavodsk Lab 42:640

    Google Scholar 

  20. Brainina KhZ, Tchernyshova AV (1977) in Polarografija, Problemy i Perspektivy. Zinatne Riga, p 242

  21. Brainina KhZ, Blum IA, Tchernyshova AV (1978) Zavodsk Lab 44:1173

    Google Scholar 

  22. Brown AP, Koval C, Anson FC (1976) J Electroanal Chem 72:379

    Google Scholar 

  23. Cigen R (1958) Acta Chem Scand 12:1456

    Google Scholar 

  24. Dakar GM, Iofa BZ, Nesmejanov AN (1963) Radiokhimija 5:428

    Google Scholar 

  25. Doblhofer K (1980) J Heyrovsky Memorial Congress on Polarography, Prague 1:63

    Google Scholar 

  26. Fetter K (1967) Electrokhimicheskaja Kinetika. Khimija Moskva

  27. Gerenrot UE, Gogel TL (1973) Electrokhimija 9:204

    Google Scholar 

  28. Gerenrot UE, Gogel TL, Landis VV (1973) Electrokhimija 9:375

    Google Scholar 

  29. Gerenrot UE, Gogel TL (1973) Electrokhimija 9:546

    Google Scholar 

  30. Kemula V, Axt-Zak A (1962) Roczn Chem 36:737

    Google Scholar 

  31. Kutner W, Nowak RJ, Mark HB (1978) Wiad Chem 32:817

    Google Scholar 

  32. Lenderman B, Monien H, Specker H (1972) Anal Lett 5:837

    Google Scholar 

  33. Lipkowski J (1978) Pr Nauk Inst Technol Nieorgan i Nawoz Mineral PWr N13, 3

  34. Monien H, Zinke K (1970) Fresenius Z Anal Chem 250:178

    Google Scholar 

  35. Monien H, Jacob P, Janisch B (1973) Fresenius Z Anal Chem 267:108

    Google Scholar 

  36. Monien H (1970) Chem-Ing-Techn 42:857

    Google Scholar 

  37. Monien H, Bodenkerk R, Kringe KP, Rath D (1980) Fresenius Z Anal Chem 300:363

    Google Scholar 

  38. Pantani F, Desideri PG (1959) Gazz Chim Ital 89:1360

    Google Scholar 

  39. Specker H, Monien H, Lendermann B (1971) Chem Anal (Warsaw) 17:1003

    Google Scholar 

  40. Stromberg AG (1962) Izvest SO Akad Nauk SSSR Ser Khim Nauk, N 5, 76

    Google Scholar 

  41. Tarajan VM, Arstamjan JM, Manugarjan YaM (1974) in Uspehy Anal Khimii. Nauka Moskva, p 188

    Google Scholar 

  42. Usatenko UI, Tulupa FM (1958) Izvest VUZ'ov Khimija i Khim Tekhnol 3:56

    Google Scholar 

  43. Vdovenko VM, Alekseeva NA, Bulaniza LS (1972) Zh Anal Khim 27:2363

    Google Scholar 

  44. Vydra F, Štulik K, Julakova E (1978) Electrochemical Stripping Analysis. Halsted Press, New York Toronto

    Google Scholar 

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Authors and Affiliations

  1. Sverdlovsk Institute of National Economy, 620001, Sverdlovsk, USSR

    K. Z. Brainina

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  1. K. Z. Brainina
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Brainina, K.Z. Organic reagents in inverse voltammetry: A review. Z. Anal. Chem. 312, 428–437 (1982). https://doi.org/10.1007/BF00625023

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  • DOI: https://doi.org/10.1007/BF00625023

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