Skip to main content
SpringerLink
Log in

Spectroscopic study of the association of 6Zh rhodamine in mixtures of carbon tetrachloride with various polar solvents

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

The concentration-dependent changes in the absorption spectrum of 6Zh rhodamine dye in binary mixtures of CCl4 with eleven polar solvents has been investigated. The degrees of association of the dye in the solvents have been computed and the absorption bands of its monomers and associates determined. It is shown that all the polar solvents hinder the association of 6Zh rhodamine. The magnitude of this effect, however, depends on the structure of the solvent molecules. It is determined by the strength of their interaction with the dye molecules. In most cases this interaction is of the donor-acceptor type.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. V. Levshin, Izv. AN SSSR, ser. fiz.,29, 1295, 1965.

    Google Scholar 

  2. L. V. Levshin and D. M. Akbarova, Vestnik MGU, no. 2, 16, 1964.

    Google Scholar 

  3. L. V. Levshin and D. M. Akbarova, ZhPS [Journal of Applied Spectroscopy],2, 69, 1965.

    Google Scholar 

  4. V. G. Bocharov and L. V. Levshin, Izv. AN SSSR, ser. fiz.,27, 590, 1963.

    Google Scholar 

  5. V. G. Bocharov and L. V. Levshin, Vestnik MGU, no. 4, 78, 1965.

    Google Scholar 

  6. L. V. Levshin and I. S. Lonskaya, Opt. i spektr.,11, 278, 1961.

    Google Scholar 

  7. D. N. Shigorin in: the Hydrogen Bond [in Russian], Izd. “Nauka,” Moscow, p. 195, 1964.

    Google Scholar 

  8. D. Roberts, Nuclear Magnetic Resonance [Russian translation], IL. Moscow, p. 93, 1961.

    Google Scholar 

  9. A. E. Chichibabin, Basic Principles of Organic Chemistry [in Russian], Goskhimizdat, Moscow, vol. 1, 1954; vol. 2, 1958.

    Google Scholar 

  10. K. Whetsel and R. Kagarise, Spectrochim. acta.,18, 315, 1962.

    Google Scholar 

  11. K. N. Kovalenko et al., ZhFKh,29, 685, 1955.

    Google Scholar 

  12. K. Medhi and D. Kastha, Indian J. Phys.,37, 139, 1963.

    Google Scholar 

  13. N. D. Sokolov, UFN,57, 205, 1955.

    Google Scholar 

  14. V. I. Malyshev, UFN,63, 323, 1957.

    Google Scholar 

  15. L. Bellon, C. r. Acad. sci.,254, 3346, 1962.

    Google Scholar 

Download references

Authors
  1. L. V. Levshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. M. Akbarova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The authors are grateful to D. N. Shigorin for his useful comments on the results obtained.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Levshin, L.V., Akbarova, D.M. Spectroscopic study of the association of 6Zh rhodamine in mixtures of carbon tetrachloride with various polar solvents. J Appl Spectrosc 3, 326–331 (1965). https://doi.org/10.1007/BF00618399

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00618399

Keywords

Search

Navigation