Skip to main content
SpringerLink
Log in

Free energy of formation of stabilized Bi2O3 (fcc) from e.m.f. measurements

  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

Using cells with calcia stabilized zirconia as the solid electrolyte, the standard free energy of formation of stabilized Bi2O3 (fcc) was determined in the temperature range 750–950 K. The stability against reduction of stabilized Bi2O3 (fcc) is not increased with respect to pureδ-Bi2O3 (fcc). The corrosion of the calcia stabilized zirconia tube caused by Bi2O3 which took place along the grain boundaries, was investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. A. Harwig and A. G. Gerards,Thermo Chimica Acta 28 (1979) 121.

    Google Scholar 

  2. Idem, J. Solid State Chem. 26 (1978) 265.

    Google Scholar 

  3. T. Takahashi and H. Iwahara,Mater. Res. Bull. 13 (1978) 1447.

    Google Scholar 

  4. M. J. Verkerk, K. Keizer and A. J. Burggraaf,J. Appl. Electrochem. 10 (1980) 81.

    Google Scholar 

  5. M. J. Verkerket al., to be published.

  6. T. Takahashi, H. Iwahara and Y. Nagai,J. Appl. Electrochem. 2 (1972) 97.

    Google Scholar 

  7. Idem, ibid 7 (1977) 299.

    Google Scholar 

  8. K. W. Browall,Electrochem. Soc. Spring Meeting (1978) abstract no 467.

  9. D. Chatterji and J. V. Smith,J. Electrochem. Soc. 120 (1973) 889.

    Google Scholar 

  10. G. M. Mehrotra, M. G. Frohberg and M. L. Kapoor,Z. Phys. Chem. N.F. 99 (1976) 304.

    Google Scholar 

  11. H. T. Cahen, M. J. Verkerk and G. H. J. Broers,Electrochim. Acta 23 (1978) 885.

    Google Scholar 

  12. G. Pouillard, M. Trinel-Dufour, Z. Derriche and P. Perrot,Rev. Chim. Min. 16 (1979) 30.

    Google Scholar 

  13. K. Park and E. M. Logothetis,J. Electrochem. Soc. 124 (1977) 1443.

    Google Scholar 

  14. Gmelins Handbuch der Anorganische Chemie, system number 19, Verlag Chemie GmbH, Weinheim, p. 437.

  15. B. Aurivillius and L. G. Sillén,Nature 155 (1945) 305.

    Google Scholar 

  16. G. Gattow and D. Schütze,Z. Anorg. Alg. Chem. 328 (1964) 44.

    Google Scholar 

  17. E. M. Levin and R. S. Roth,J. Res. Nat. Bur. Stand. 68A (1964) 197.

    Google Scholar 

  18. J. D. Tretjakow and H. Schmalzried,Ber. Bunsenges. Phys. Chem. 69 (1965) 396.

    Google Scholar 

  19. T. Takahashi, K. Ito and H. Iwahara,Rev. Energ. Primaire 2 (1966) 42.

    Google Scholar 

  20. T. Takahashi and H. Iwahara,Denki Kagaku 34 (1966) 254.

    Google Scholar 

  21. J. Hladik, in ‘Physics of Electrolytes’, Vol. 2. (edited by J. Hladik) Academic Press, London, New York (1972) p. 850.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Materials Science, Twente University of Technology, PO Box 217, 7500, AE Enschede, The Netherlands

    M. J. Verkerk & A. J. Burggraaf

Authors
  1. M. J. Verkerk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. J. Burggraaf
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Verkerk, M.J., Burggraaf, A.J. Free energy of formation of stabilized Bi2O3 (fcc) from e.m.f. measurements. J Appl Electrochem 10, 677–681 (1980). https://doi.org/10.1007/BF00615492

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00615492

Keywords

Search

Navigation