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The electronic behaviour of iron in U(FexAl1−x)2

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Abstract

Mössbauer effect measurements on the intermetallic compounds U(Fe x Al1−x )2 in the paramagnetic state showed two overlapping subspectra. The spectra were successfully analysed according to the statistical distribution of nearest neighbours to iron. This led to the presence of a singlet and a quadrupole doublet with a distinctly negative isomer shift. The results were qualitatively interpreted in view of charge transfers, ands andd electronic densities at the iron nuclei.

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References

  1. W.B.Pearson:The Crystal Chemistry and Physics of Metals and Alloys (Wiley Interscience, London 1972)

    Google Scholar 

  2. W.B.Pearson:Hand Book of Lattice Spacings and Structures of Metals and Alloys, Vol. 2 (Pergamon Press, London 1967)

    Google Scholar 

  3. M.Yessik: J. Appl. Phys.40, 1133 (1969)

    Google Scholar 

  4. S.Komura, N.Kunitonmi, P.K.Tseng, N.Shikazono, A.Takekoshi: J. Phys. Soc. Jpn.16, 1479 (1961)

    Google Scholar 

  5. S.T.Lin, R.E.Ogilvie: J. Appl. Phys.34, 1372 (1963)

    Google Scholar 

  6. J.C.Wright:Metallurgy in Nuclear Power Technology (Iliffe Books, London 1962)

    Google Scholar 

  7. M.K.Fayek, Y.Abass, A.A.Bahgat: A.R.E.A.E.E./Rep. (to be published)

  8. R.E.Watson: Phys. Rev.119, 1934 (1960)

    Google Scholar 

  9. P.Walker, G.Wertheim, V.Jaccarino: Phys. Rev. Lett.6, 98 (1961)

    Google Scholar 

  10. L.Pauling:The Nature of the Chemical Bond (Cornell University Press, Cornell 1963)

    Google Scholar 

  11. F. VanderWoud, G.A.Sawatzky: Phys. Rep.12, 335 (1974)

    Google Scholar 

  12. G.K.Wertheim: InProspective in Mössbauer Spectroscopy, ed. by S.G.Cohen and M.Pasternak (Plenum Press, New York 1973)

    Google Scholar 

  13. D.W.Fischer: InBand Structure Spectroscopy of Metals and Alloys, ed. by E.J.Fabian and C.M.Watson (Academic Press, New York 1973)

    Google Scholar 

  14. E.N.Kaufmann, R.J.Vianden: Rev. Mod. Phys.51, 161 (1979)

    Google Scholar 

  15. G.L.Bowden, S.P.Bunbury, A.P.Guimarees, R.E.Snyder: J. Phys. C1, 1376 (1968)

    Google Scholar 

  16. W.Steiner, R.Haferl, R.Groessinger: J. Phys. (Paris)41, C1–193 (1980)

    Google Scholar 

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Fayek, M.K., Bahgat, A.A. & Eltawansi, A. The electronic behaviour of iron in U(FexAl1−x)2 . Appl. Phys. A 26, 175–178 (1981). https://doi.org/10.1007/BF00614753

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