Skip to main content
SpringerLink
Log in

The thermochemistry of transition metal carbides

  • Published:
Oxidation of Metals Aims and scope Submit manuscript

Abstract

A general survey is made of the available data for the standard Gibbs energies of formation of solid carbides of transition metals. The results are plotted as standard Gibbs energy vs. temperature diagrams. The equations and the estimated accuracy when available are given for each substance.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. D. Richardson,J. Iron Steel Inst. 175, 33 (1953).

    Google Scholar 

  2. O. Kubaschewski, E. L. Evans, and C. B. Alcock,Metallurgical Thermochemistry (Pergamon Press, Oxford, 1967).

    Google Scholar 

  3. T. B. Reed,Free Energy of Formation of Binary Compounds: An Atlas of Charts for High Temperature Chemical Calculations (M.I.T. Press, Cambridge, Mass., 1971).

    Google Scholar 

  4. C. E. Wicks and F. E. Block,Bur. Mines Bull. 605 (1973).

  5. E. Rudy, “Ternary Phase Equilibria in Transition Metal-Boron, Carbon, Silicon Systems,” Part V, “Compendium of Phase Diagram Data,” AFML-TR-65-2, Wright-Patterson Air Force Base, Ohio, (1967).

  6. M. Hansen,Constitution of Binary Alloys (McGraw-Hill, New York, 1936).

    Google Scholar 

  7. R. P. Elliott,Constitution of Binary Alloys, First Supplement (McGraw-Hill, New York, 1965).

    Google Scholar 

  8. F. A. Shunk,Constitution of Binary Alloys, Second Supplement (McGraw-Hill, New York, 1969).

    Google Scholar 

  9. W. A. Moffatt,The Handbook of Binary Phase Diagrams (General Electric Co., Schenectady, N.Y., 1976).

    Google Scholar 

  10. K. K. Kelley and A. D. Mah,Bureau of Mines Report of Investigations Number 5490 (1959).

  11. S. Fujishiro and N. A. Gokcen,J. Phys. Chem. 65, 161 (1961).

    Google Scholar 

  12. E. K. Storms, A. Lowe, E. Bacca, and J. Griffin,High Temp. Sci. 5, 276 (1973).

    Google Scholar 

  13. P. V. S. Pillai and M. Sundaresan,Trans. Ind. Inst. Met. 28, 319 (1975).

    Google Scholar 

  14. W. L. Worrell and J. Chipman,J. Phys. Chem. 68, 860 (1964).

    Google Scholar 

  15. T. Kireev and R. Karapetyantes,J. Chem. Phys. 40, 68 (1966).

    Google Scholar 

  16. N. M. Volkova and P. V. Gel'd,Inz. Vyssikh. Zaved. Tsvetn. Met. 77, 8 (1965).

    Google Scholar 

  17. V. I. Alekseev and L. V. Shavartsman,Dokl. Akad. Nauk SSSR 113, 1327 (1960).

    Google Scholar 

  18. W. L. Worrell and J. Chipman,Trans. Am. Inst. Min. Metall. Pet. Eng. 230, 1682 (1964).

    Google Scholar 

  19. S. Fujishiro,Trans. Jpn. Inst. Met. 35, 997 (1971).

    Google Scholar 

  20. A. D. Mah,Bureau of Mines Report of Investigations Number 6177 (1963).

  21. A. D. Kulkarni and W. L. Worrell,Metall. Trans. 3, 2363 (1972).

    Google Scholar 

  22. H. Mabuchi and Y. Matsushita,Metall. Trans. 2, 1503 (1971).

    Google Scholar 

  23. E. K. Storms,The Refractory Carbides (Academic Press, New York, 1967).

    Google Scholar 

  24. H. Tanaka, Y. Kishida, A. Kawayuchi, and J. Moriyama, unpublished research, Department of Metallurgy, Kyoto University, Japan (1970).

  25. H. Kleykamp,Ber. Bunsenges. Phys. Chem. 73, 354 (1969).

    Google Scholar 

  26. Y. Z. Vintaikin,Fiz. Met. Metalloved. 16, 144 (1963).

    Google Scholar 

  27. K. K. Kelley, F. S. Boericke, G. E. Moore, E. H. Huffman, and W. M. Bongert, U.S. Bureau of Mines, Technical Paper 662 (1944).

  28. M. Gleiser,J. Phys. Chem. 69, 1771 (1965).

    Google Scholar 

  29. F. Moattar and J. S. Anderson,Trans. Faraday Soc. 67, 2303 (1971).

    Google Scholar 

  30. W. A. Frad,Adv. Inorg. Chem. Radiochem. 11, 188 (1968).

    Google Scholar 

  31. C. L. McCabe and R. G. Hudson,Trans. Am. Inst. Min. Metall. Pet. Eng. 209, 17 (1957).

    Google Scholar 

  32. N. A. Gokcen and S. Fujishiro,Trans. Am. Inst. Min. Metall. Pet. Eng. 227, 542 (1963).

    Google Scholar 

  33. W. Glud, K. V. Otto, and H. Ritter,Ber. Ges. Kohlentech. 3, 40 (1929).

    Google Scholar 

  34. G. Hagg,Z. Kristallogr. 89, 92 (1934).

    Google Scholar 

  35. R. Hultgren, R. L. Orr, P. D. Anderson, and K. K. Kelley,Selected Values of Thermodynamic Properties of Metals and Alloys (Wiley, New York, 1963).

    Google Scholar 

  36. B. D. Pollock,J. Phys. Chem. 65, 731 (1961).

    Google Scholar 

  37. L. B. Pankratz, W. W. Weller, and K. K. Kelley,Bureau of Mines Report of Investigations Number 6446 (1964).

  38. M. Gleiser and J. Chipman,J. Phys. Chem. 66, 1539 (1962).

    Google Scholar 

  39. T. C. Wallace, G. P. Gutierrez, and P. L. Stone,J. Phys. Chem. 67, 796 (1963).

    Google Scholar 

  40. A. Solbakken and P. H. Emmett,J. Am. Chem. Soc. 91, 31 (1969).

    Google Scholar 

  41. R. J. Fries,J. Chem. Phys. 46, 4463 (1967).

    Google Scholar 

  42. L. C. Browning and P. H. Emmett,J. Am. Chem. Soc. 74, 4773 (1952).

    Google Scholar 

  43. K. A. Gingerich,Chem. Phys. Lett. 25, 523 (1974).

    Google Scholar 

  44. M. C. Sneed and R. C. Brasted,Comprehensive Inorganic Chemistry, Vol. II (Van Nostrand, Princeton, N.J., 1954).

    Google Scholar 

  45. N. V. Sidgewick,The Chemical Elements and Their Compounds (Oxford Univ. Press, Oxford, 1950).

    Google Scholar 

  46. A. D. Kulkarni and W. L. Worrell,Metall. Trans. 4, 931 (1973).

    Google Scholar 

  47. L. B. Pankratz, W. W. Weller, and E. B. King,Bureau of Mines Report of Investigations Number 6861 (1966).

  48. D. K. Gupta and L. L. Seigle,Metall. Trans. 6A, 1939 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Materials Engineering Department, Rensselaer Polytechnic Institute, 12181, Troy, New York

    Stephen R. Shatynski

Authors
  1. Stephen R. Shatynski
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shatynski, S.R. The thermochemistry of transition metal carbides. Oxid Met 13, 105–118 (1979). https://doi.org/10.1007/BF00611975

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00611975

Key words

Search

Navigation