Skip to main content
SpringerLink
Log in

Separation of aliphatic and aromatic organic acids on starch thin-layers

Trennung von aliphatischen und aromatischen Säuren mit Hilfe der Dünnschicht-Chromatographie auf Stärke

Chromatographic behaviour and chemical structure

  • Original Papers
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Zusammenfassung

Aliphatische Monocarbon-, Dicarbon-, Hydroxy-, Keto und Aminosäuren wurden dünnschicht-chromatographisch auf Reisstärke getrennt (Fließmittel: Äthanol/ Wasser/Ammoniak [78∶20∶13]). Verschiedene aromatische Säuren wurden auf der gleichen Schicht mit dem Fließmittel Äthanol/n-Butanol/Wasser/Ammoniak (40∶30∶15∶15) getrennt. Rf- und RM-Werte wurden bestimmt. Aufgrund der theoretischen Aufstellungen von Martin für die Beziehung zwischen Rf-Werten in der Verteilungs- chromatographie und chemischen Strukturen wurden Gruppen- und Grundkonstanten bestimmt.

Summary

Aliphatic monocarboxylic, dicarboxylic, hydroxy, keto and amino acids were separated on rice starch thin layers with the solvent system: ethanol/water/ammonia (78∶20∶13). Different aromatic acids were separated on the same support with the solvent system: ethanol/n-butanol/water/ammonia (40∶30∶15∶15). Rf- and RM-values were determined and the validity of Martin's theoretical postulates on the relationship between chemical structure and Rf-values in partition chromatography was displayed. Calculation of group and basic constants was also carried out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Bark, L. S., Graham, R. J. T.: J. Chromatog.23, 120 (1966)

    Google Scholar 

  2. Bark, L. S., Graham, R. J. T.: J. Chromatog.23, 417 (1966)

    Google Scholar 

  3. Bark, L. S., Graham, R. J. T.: J. Chromatog.23, 357 (1966)

    Google Scholar 

  4. Bark, L. S., Graham, R. J. T.: J. Chromatog.27, 109 (1967)

    Google Scholar 

  5. Bate-Smith, E. C., Westall, R. G.: Biochim. Biophys. Acta4, 427 (1950)

    Google Scholar 

  6. Brenner, M., Pataki, G.: Helv. Chim. Acta44, 1420 (1961)

    Google Scholar 

  7. Canić, V. D., Perišić-Janjić, N. U.: Hemijska Indust.2, 66 (1970)

    Google Scholar 

  8. Canić, V. D., Petrović, S. M.: Mikrochim. Acta1969, 1599

  9. Graham, R. J. T.: J. Chromatog.33, 118, 125 (1968)

    Google Scholar 

  10. Graham, R. J. T., Bark, L. S., Daly, J.: J. Chromatog.33, 107 (1968)

    Google Scholar 

  11. Gütlbauer, F.: J. Chromatog.45, 104 (1969)

    Google Scholar 

  12. Martin, A. J. P.: Biochem. Soc. Symp. (Cambridge)3, 4 (1949)

    Google Scholar 

  13. Nover, L., Baumgarten, G., Luckner, M.: J. Chromatog.32, 123 (1968)

    Google Scholar 

  14. Nover, L., Baumgarten, G., Luckner, M.: J. Chromatog.39, 450 (1969)

    Google Scholar 

  15. Pataki, G.: J. Chromatog.17, 327 (1965)

    Google Scholar 

  16. Petrović, S. E., Belia, B. E., Vukajlović, D. B.: Anal. Chem.40, 1007 (1968)

    Google Scholar 

  17. Petrović, S. M., Petrović, S. E.: J. Chromatog.21, 313 (1966)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Technology, University of Novi Sad, Yugoslavia

    V. D. Canić & N. U. Perišić-Janjić

Authors
  1. V. D. Canić
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. U. Perišić-Janjić
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Canić, V.D., Perišić-Janjić, N.U. Separation of aliphatic and aromatic organic acids on starch thin-layers. Z. Anal. Chem. 270, 16–19 (1974). https://doi.org/10.1007/BF00595876

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00595876

Search

Navigation