Abstract
On the basis of a study of the13C NMR spectra of a base fromVinca erecta previously regarded as “kopsanone,” and the known alkaloid kopsinilam, it has been shown that the former is 5,22-dioxokopsane.
Similar content being viewed by others
Literature cited
D. A. Rakhimov, M. R. Sharipov, Kh. N. Aripov, V. M. Malikov, T. T. Shakirov, and S. Yu. Yunusov, Khim. Prir. Soedin., 713 (1970).
H. Achenbach and K. Biemann, J. Am. Chem. Soc.,87, 4944 (1965).
A. Chatterjee, D. J. Roy, and S. Mukhopadhyay, Indian J. Chem.,17B, 651 (1979).
J. M. Ferreira, B. Gilbert, M. Kitagawa, L. A. Paes Leme, L. J. Durham, J. Chem. Soc., (C), 1260 (1966).
C. Kump and H. Schmid, Helv. Chim. Acta,45, 1090 (1962).
D. A. Rakhimov, V. M. Malikov, and S. Yu. Yunusov, Khim. Prir. Soedin., 354 (1967).
A. Ahond, M.-M. Janot, L. Langois, G. Lukacs, P. Potier, P. Rasoanaivo, M. Sangare, N. Neuss, M. Plat, J. Le Men, E. W. Hagaman, and E. Wenkert, J. Am. Chem. Soc.,96, 633 (1974).
M. R. Yugudaev, Khim. Prir. Soedin., 334 (1984).
Chen Wei-shin, Li Sao-han, A. Kurfel, G. Will, and E. Breitmaier, Ann. Chem., 1886 (1981).
F. Bohlmann and R. Zeisberg, Chem. Ber.,108, 1043 (1975).
E. Breitmaier and W. Voelter,13C NMR Spectroscopy, Verlag Chemie, Weinheim (1974).
P. J. Garrat and R. Riguera, J. Org. Chem.,41, 465 (1965).
Additional information
Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 344–346, May–June, 1984.
Rights and permissions
About this article
Cite this article
Yagudaev, M.R. The NMR investigation of alkaloids. VII.13C NMR spectra and structure of “kopsanone” and kopsinilam. Chem Nat Compd 20, 320–322 (1984). https://doi.org/10.1007/BF00575758
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00575758