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Vibrational analysis of the Raman, infrared and electronic spectra of hexafluoromanganate(IV)

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Abstract

From the Raman, infrared and electronic spectra all of the fundamental vibrational frequencies were determined for both the ground state4 A 2g and the excited2 E g In addition some fundamental frequencies were established for the4 T 2g and4 T 1g excited states from low temperature absorption spectra.

Zusammenfassung

Aus den Raman-, Infrarot- und Elektronenspektren wurden alle Grundschwingungsfrequenzen für den Grundzustand4 A 2g und den angeregten2 E g-Zustand bestimmt. Ferner wurden noch einige der entsprechenden Größen für die angeregten Zustände4 T 2g und4 T 1g aus Tieftemperatur-Absorptionsspektren ermittelt.

Résumé

Toutes les fréquences fondamentales de vibration ont été déterminées pour l'état fondamental4 A 2g et l'état excité2 E g à partir des spectres Raman, infra-rouge et électronique. De plus, certaines fréquences fondamentales des états excités4 T 2g et4 T 1g ont été obtenues à partir des spectres d'absorption à basse température.

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Dedicated to the memory of Prof. Hans-Ludwig Schläfer.

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Pfeil, A. Vibrational analysis of the Raman, infrared and electronic spectra of hexafluoromanganate(IV). Theoret. Chim. Acta 20, 159–170 (1971). https://doi.org/10.1007/BF00569262

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  • DOI: https://doi.org/10.1007/BF00569262

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