Skip to main content
SpringerLink
Log in

The ageing characteristics of an Fe-19 wt% Ni-9 wt% Co-5 wt% W alloy

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

In the present paper, we compare the behaviour during ageing in the temperature range 380 to 530° C of the two martensitic alloys Fe-18.65 Ni-8.99 Co-4.87 Mo and Fe-18.65 Ni-8.99 Co-4.87 W (wt %). The kinetics of precipitation were followed by measurements of hardness, by resistometric measurements and electron microscopy. In the case of the alloy with Mo, Mo at first concentrates in local clusters, then an ω phase is formed, and above 450° C, finally a Ni3Mo or Laves phase (Fe, Ni, Co)2 Mo is formed. In the case of the alloy with W, ω phase formation was not observed but an intermetallic precipitate isomorphous with Ni3Mo, (Fe, Ni, Co)3 W = A3W was found. The precipitates are rod-shaped, of several nm in length. The preferred direction of growth of these precipitates is 〈1 1 1〉 of the martensitic matrix and the orientation relationship with the martensitic matrix is (0 1 1)M ∥ (0 1 0)A3W and [1 1 1]M ∥ [1 0 0]A3W, identical to that found for the Ni3Mo precipitate in the (Fe, Ni, Co, Mo, Ti) industrial maraging steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. “Les aciers Maraging à 18% de Ni au Co, Mo”, Revue du Nickel, 28 (1962).

  2. S. Floreen and R. F. Decker, Trans. Quart. ASM 55 (1962) 518.

    Google Scholar 

  3. J. Pitaud, “Les aciers Maraging”, Extrait de la Revue du Nickel, 29 (1963).

  4. B. G. Reisdorf, Trans. ASM 56 (1963) 783.

    Google Scholar 

  5. G. P. Speich, Trans. Met. Soc. AIME 227 (1963) 1426.

    Google Scholar 

  6. S. Floreen, Trans. Quart. ASM 57 (1964) 38.

    Google Scholar 

  7. A. J. Baker and P. R. Swann, Trans. ASM 57 (1964) 1008.

    Google Scholar 

  8. R. K. Pitler and G. S. Ansell, Trans. ASM 57 (1964) 220.

    Google Scholar 

  9. G. P. Miller and W. I. Mitchell, J. Iron Steel Inst. 203 (1965) 899.

    Google Scholar 

  10. H. Marcus, L. H. Schwartz and M. E. Fine, Trans. ASM 59 (1966) 468.

    Google Scholar 

  11. R. B. Banerjee, J. M. Capenos and J. J. Hauser, “Advances in electron metallography” 6 ASTM STP 396 (American Society for Testing Metals, Metals Park, Ohio, 1966) p. 115.

    Google Scholar 

  12. D. T. Peters and C. R. Cupp, Trans. Metal. Soc. AIME 236 (1966) 1420.

    Google Scholar 

  13. K. Detert, Arch. Eisenhüttenwesen 37 (1966) 579.

    Google Scholar 

  14. J. R. Mihalisin, Trans. ASM 59 (1966) 60.

    Google Scholar 

  15. R. D. Garwood and R. D. Jones, J. Iron Steel Inst. 204 (1966) 512.

    Google Scholar 

  16. M. J. Fleetwood, G. M. Higgins and G. P. Miller, J. Appl. Phys. 16 (1965) 645.

    Google Scholar 

  17. J. M. Chilton and C. J. Barton, Trans ASM 60 (1967) 528.

    Google Scholar 

  18. W. R. Bandi, J. L. Intz and L. M. Melnick, J. Iron Steel Inst. 207 (1969) 348.

    Google Scholar 

  19. C. Servant and G. Cizeron, Mém. Sci. Rev. Mét. LXVI (1969) 531.

    Google Scholar 

  20. C. Servant, G. Maeder, G. Cizeron and P. Lacombe, Mém. Sci. Rev. Mét. LXVIII (1971) 201–213.

    Google Scholar 

  21. J. Bourgeot, P. Maitrepierre, J. Manenc and B. Thomas, Fifth International Symposium, University of California, Berkeley, California (1971).

    Google Scholar 

  22. Ken'ichi Shimizu and Hisaki Okamoto, Trans. Japan Inst. Metals 12 (1971) 273.

    Google Scholar 

  23. C. Servant, Thèse de Doctorat ès-Sciences Université Paris-Sud, Orsay (1972).

  24. A. F. Yedneral and M. D. Perkas, Fiz. metal. metalloved 33 (1972) 315.

    Google Scholar 

  25. R. Courrier, Thèse de Doctorat ès-Sciences, Université de Nancy (1972).

  26. R. Courrier and G. Le Caer, Mém. Sci. Rev. Mét. LXXI (1974) 692.

    Google Scholar 

  27. C. Servant, G. Maeder and G. Cizeron, Met. Trans. 6A (1975) 981.

    Google Scholar 

  28. G. Maeder, Thèse de Doctorat ès-Sciences, Université de Paris-Sud, Orsay (1975).

    Google Scholar 

  29. A. Agnel, F. Hedin, G. Maeder, C. Servant and P. Lacombe, Acta Met. 25 (1977) 1445.

    Google Scholar 

  30. C. Servant and P. Lacombe, J. Mater. Sci. 12 (1977) 1807.

    Google Scholar 

  31. C. Servant, G. Maeder and P. Lacombe, Met. Trans. (to be published).

  32. A. F. Yedneral, O. P. Zhukov and M. D. Perkas, Fiz. Met. Metalloved 36 (1973) 339 and; 569.

    Google Scholar 

  33. J. Burke, “La cinétique des changements de phase dans les métaux”, (Masson, Paris, 1968).

    Google Scholar 

  34. A. H. Cottrell and B. A. Bilby, Proc. Phys. Soc. A62 (1949) 49.

    Google Scholar 

  35. S. Harper, Phys. Rev. 83 (1951) 209.

    Google Scholar 

  36. P. L. Gruzin, Dokl. Akad. Nauk. 94 (1954) 81.

    Google Scholar 

  37. M. Hansen, “Constitution of Binary Alloys” (McGraw-Hill, New York, 1958) p. 1057.

    Google Scholar 

  38. N. Karlson, J. Inst. Metals. 79 (1951) 391.

    Google Scholar 

  39. Shozo Saito and P. A. Beck, Trans. AIME 215 (1959) 938.

    Google Scholar 

  40. G. H. Smith and R. E. Burge, Acta Cryst. 15 (1962) 182.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Métallurgie Physique, associé au CNRS no. 177, Université de Paris-Sud, Centre d'Orsay, 91405, Orsay Cedex, France

    C. Servant & P. Lacombe

  2. Laboratoire de Métallurgie de l'Ecole Nationale Supérieure des Arts et Métiers, 151 bd de l'Hôpital, 75640, Paris Cedex 13, France

    M. Griveau

Authors
  1. C. Servant
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Lacombe
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Griveau
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Servant, C., Lacombe, P. & Griveau, M. The ageing characteristics of an Fe-19 wt% Ni-9 wt% Co-5 wt% W alloy. J Mater Sci 15, 859–870 (1980). https://doi.org/10.1007/BF00552095

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00552095

Keywords

Search

Navigation