Abstract
Single crystals of lead with either thallium, indium, bismuth, cadmium, mercury or antimony were tested in tension in liquid air. The critical resolved shear stress τ 0 increases linearly with increasing solute content c in a limited concentration range. The increase Δτ 0/ΔC is lowest for lead-thallium and highest for lead-antimony. When log Δτ 0/ΔC is plotted against log (sf + elf) where sf*[(d 1)Pb − (d 1)sol/(d 1)Pb]10Pb, d 1 being the closest distance of approach, and elf = ΣEn, ΣEn being the sum of the electronegativities of solvent and solute, a straight line of slope 2 results. A similar result is obtained with data from the literature for single crystals of copper alloys and of magnesium alloys. However in these cases a different size factor has to be used.
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References
P. Haasen, “Physical Metallurgy”, edited by R. W. Cahn (North Holland, Amsterdam, 1965) p. 821.
W. R. Hibbard, Trans. AIMME 1 (1958) 212.
J. O. Linde and S. Edwardson, Ark. f. Fysik 8 (1954) 511.
N. F. Mott and F. R. N. Nabarro, “Conference on Strength of Solids” (Phys. Soc, London, 1948) p. 1.
N. F. Mott, “Imperfections in Nearly Perfect Crystals” (Wiley, New York, 1952) p. 173.
R. L. Fleischer and W. R. Hibbard, “The Relation between Structure and Mechancial Properties of Metals” (Her Majesty's Stationery Office, London, 1963) p. 261.
R. L. Fleischer, Acta Metallurgica 9 (1961) 996.
Idem, ibid 11 (1963) 203.
B. Harris, Phys. Stat. Sol. 18 (1966) 715.
M. M. Hutchison and R. W. K. Honeycombe, Met. Sci. J. 1 (1967) 70.
I. Goebel, Z. Metallk. 14 (1922) 357; 388; 425; 449.
J. E. Dorn, P. Pietrowsky, and T. E. Tietz, Trans. AIMME 188 (1950) 933.
D. Hardie and R. N. Parkins, Journal Inst. Metals 85 (1956) 449.
R. L. Fleischer, Acta Metallurgica 9 (1961) 184.
F. Weinberg, Can. J. Phys. 45(2) (1967) 1189.
A. Seeger, J. Diehl, S. Mader, and H. Rebstock, Phil. Mag. 2 (1957) 323.
P. Feltham and J. D. Meakin, Acta Metallurgica 5 (1957) 555.
G. F. Bolling, L. E. Hays, and H. W. Wiedersich, ibid 10 (1962) 185.
P. W. Neurath and J. S. Koehler, J. Appl. Phys. 22 (1951) 621.
J. Van Der Planken, M. Creton, and A. Deruyttere, to be published.
W. Hofmann, “Blei und Bleilegierungen” (Springer, Berlin, 1962) p. 96.
J. Diehl, Z. Metallk. 47 (1956) 331; 412.
M. L. Shepard and J. F. Smith, Acta Metallurgica 15 (1967) 357.
Y. C. Tang and L. Pauling, Acta Cryst. 5 (1952) 39.
C. Tyzack and G. V. Raynor, ibid 7 (1954) 505.
H. W. King, J. Materials Sci. 1 (1966) 79.
E. Teatum, K. A. Gschneidner, and J. Waber, LA-2345, June (1960).
J. Waber, K. A. Gschneidner, A. C. Larson, and M. Y. Prince, Trans AIMME 227 (1963) 717.
J. R. Wilson, Metall. Rev. 10 (1965) nr. 40.
A. H. Cottrell, S. C. Hunter, and F. R. N. Nabarro, Phil. Mag. 44 (1953) 1064.
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Van Der Planken, J., Deruyttere, A. Solution hardening of lead single crystals at liquid air temperature. J Mater Sci 4, 499–508 (1969). https://doi.org/10.1007/BF00550210
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DOI: https://doi.org/10.1007/BF00550210