Skip to main content
Log in

Ground water discharge and the related nutrient and trace metal fluxes into Quincy bay, Massachusetts

  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

Measurement of the rate and direction of ground water flow beneath Wollaston Beach, Quincy, Massachusetts by use of a heat-pulsing flowmeter shows a mean velocity in the bulk sediment of 40 cm d−1. The estimated total discharge of ground water into Quincy Bay during October 1990 was 1324–2177 m3 d−1, a relatively low ground water discharge rate. The tides have only a moderate effect on the rate and direction of this flow. Other important controls on the rate and volume of ground water flow are the limited thickness, geographic extent, and permeability of the aquifer. Comparisons of published streamflow data and estimates of ground water discharge indicate that ground water makes up between 7.4–12.1% of the gaged freshwater input into Quincy Bay. The data from this study suggest the ground water discharge is a less important recharge component to Quincy Bay than predicted by National Urban Runoff Program (NURP) models.

The high nitrate and low nitrite and ammonia concentrations in the ground water at the backshore well sites and low nitrate and high nitrite and ammonia concentrations in the water flowing from the foreshore suggests that denitrification is active in the sediments. The low ground water flow rates and low nitrate concentrations in the foreshore samples suggest that little or no nitrate is surviving the denitrification process to affect the planktonic community. Similarly, oxidizing conditions in the aquifer and low trace metal concentrations in the ground water samples suggest that the metals may be precipitating and binding to sedimentary phases before impacting the bay.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • American Public Health Association: 1980, ‘Standard Methods for the Examination of Water and Wastewater’, American Public Health Association, 15th Edition, 685 pp.

  • Bendschneider, K. and Robinson, R.J.: 1952, ‘A New Spectrophotometric Method for the Determination of Nitrite in Sea Water’, J. Mar. Res. 11, 87–96.

    Google Scholar 

  • Bokuniewicz, H.: 1980, ‘Ground Water Seepage into Great South Bay, New York’, Estuar. Coast. Mar. Sci. 10, 437–444.

    Google Scholar 

  • Brackley, R.A., Fleck, W.B. and Meyer, W.R.: 1973, ‘Hydrology and Water Resources of the Neponset and Weymouth River Basins, Massachusetts’, U.S. Geol. Sur. Hydrol. Invest. Atlas HA-484, 3 sheets.

  • Burns, R.G. and Burns, V.M.: 1975, ‘Mechanism for Nucleation and Growth of Manganese Nodules’, Nature 225, 130–131.

    Google Scholar 

  • Capone, D.G. and Bautista, M.F.: 1985, ‘A Ground Water Source of Nitrate in Nearshore Marine Sediments’, Nature 313, 214–216.

    Google Scholar 

  • Capone, D.G. and Slater, J.M.: 1990, ‘International Patterns of Water Table Height and Ground Water Derived Nitrate in Nearshore Sediments’, Biogeochem. 10, 277–288.

    Google Scholar 

  • Davies-Colley, R.J., Nelson, P.O. and Williamson, K.J.: 1984, ‘Copper and Cadmium Uptake by Estuarine Sedimentary Phases’, Environ. Sci. Tech. 18, 491–499.

    Google Scholar 

  • D'Elia, C.F., Webb, K.L. and Porter, J.W.: 1981, ‘Nitrate-Rich Ground Water Inputs to Discovery Bay, Jamaica: A Significant Source of N to Local Coral Reefs’, Bull. Mar. Sci. 31, 903–910.

    Google Scholar 

  • Frimpter, M.H. and Gay, F.B.: 1979, ‘Chemical Quality of Ground Water on Cape Cod, Massachusetts’, U.S. Geol. Sur. Water-Res. Invest. 79–65, 11 pp.

  • Gadoury, R.A., Socolow, R.W., Bell, R.W. and Calderini, T.J.: 1990, ‘Water Resources Data, Massachusetts and Rhode Island, Water Year 1988’, U.S. Geol. Sur. Water-Data Report MA-RI-88-1, 231 pp.

  • Gaines, A.G., Giblin, A.E. and Moldzinska-Kijowski, Z.: 1983, ‘Freshwater Discharge and Nitrate Input into Town Cove’, In J.M. Teal (Ed.) The Coastal Impact of Ground Water Discharge: An Assessment of Anthrogogenic Nitrogen Loading in Town Cove, Orleans, MA, Final Report, Woods Hole Oceanographic Institution, Woods Hole, MA.

    Google Scholar 

  • Gorhan, E. and Swaine, D.J.: 1965, ‘The Influence of Oxidizing and Reducing Conditions upon the Distribution of Some Elements in Lake Sediments’, Limnol. Ocean. 10, 268–279.

    Google Scholar 

  • Guthrie, M.: 1986, ‘Use of a Geo Flowmeter for the Determination of Ground Water Flow’, Ground Water Monitor. Rev. 6, 81–86.

    Google Scholar 

  • Johannes, R.E.: 1980, ‘The Ecological Significance of the Submarine Discharge of Ground Water’, Mar. Ecol. 3, 365–373.

    Google Scholar 

  • Jorgensen, K.S. and Sorensen, J.: 1988, ‘Two Annual Maxima of Nitrate Reduction and Denitrification in Estuarine Sediments (Norsminde Fjord, Denmark)’, Mar. Ecol. Progr. Ser. 48, 147–154.

    Google Scholar 

  • Kaye, C.A.: 1980, ‘Bedrock Geology, Boston North, Boston South, and Newton Quadrangles, Massachusetts’, U.S. Geol. Sur. Misc. Field Study Map MF-1241, 2 sheets.

  • Kerfoot, W.B.: 1988, ‘Monitoring Well Construction, and Recommended Procedures for Direct Ground-Water Flow Measurements Using a Heat-Pulsing Flowmeter’, In A.G. Collins and A.I. Johnson (Eds.) Ground-Water Contamination: Field Methods, ASTM STP 963, American Society Testing Materials, Philadelphia, 146–161.

    Google Scholar 

  • Kopp, J.F. and McKee, G.D.: 1979, ‘Methods for Chemical Analysis of Water and Wastewater’, U.S. Environ. Pro. Agency Man, EPA-600/4-79-020, THird Edition, ORD Publications, Cincinatti, 460 pp.

    Google Scholar 

  • Koroleff, F.: 1976, ‘Determination of Silicon’, IN K. Grasshoff (Ed.) Methods of Seawater Analysis, Weinheim and York, Verlag Chemie, 317 pp.

    Google Scholar 

  • LaForge, L.: 1932, ‘Geology of the Boston Area, Massachusetts’, U.S. Geol. Sur. Bull. 839, 105 pp.

  • Massachusetts Division of Water Pollution Control: 1984, ‘Boston Harbor 1984 Water Quality and Wastewater Discharge Data’, Mass. Depart. Environ. Qual. Eng. Publication No. 14, 270-47-100-12-85-CR, 46 pp.

  • Massachusetts Division of Water Pollution Control: 1986, ‘Boston Harbor 1985 Water Quality and Wastewater Discharge Date’, Mass. Depart. Environ. Qual. Eng. Publication No. 14, 471-80-20-10-86-CR, 72 pp.

  • Melville, J.G., Molz, F.J. and Guven, O.: 1985, ‘Laboratory Investigation and Analysis of a Ground Water Flowmeter’, Ground Water 23, 486–495.

    Google Scholar 

  • Menzie, C. and Cura, J.J.: 1990, ‘Boston Harbor Estimates of Loadings’, Report to the Massachusetts Water Resources Authority, Harbor Studies Group, 95 pp.

  • Murphy, J. and Riley, J.P.: 1962, ‘A Modified Single Solution Method for the Determination of Phosphate in Natural Waters’, Anal. Chimica Acta 27, 31–36.

    Google Scholar 

  • Office of Water Data Coordination: 1977, ‘National Handbook of Recommended Methods for Water-Data Acquisition’, Report to the International Hydrological Program, Ch. 1, 130 pp.

  • Pomroy, A.J., Joint, I.R. and Clarke, K.R.: 1983, ‘Benthic Nutrient Flux in a Shallow Coastal Environment’, Oecologica 60, 306–312.

    Google Scholar 

  • Pregnall, A.M. and Miller, S.L.: 1988, ‘Flux of Ammonium from Surf-Zone and Nearshore Sediments in Hahant Bay, Massachusetts, USA in Relation to Free-Living Pilayella littoralis’, Mar. Ecol. Prog. Ser. 50, 161–167.

    Google Scholar 

  • Price, N.B.: 1967, ‘Some Geochemical Observations on Manganese Oxide Nodules from Different Depth Environments’, Mar. Geol. 5, 511–538.

    Google Scholar 

  • Reimold, R.J., Bysshe, S.E. and Cooper, C.B.: 1988, ‘Review of the Historical Data for Characterization of Quincy Bay Contamination’, Report to the U.S. Environ. Prot. Agency No. 68-02-4357, Metcaff and Eddy Inc., 45 pp.

  • Rendigs, R.R. and Oldale, R.N.: 1990, ‘Maps Showing the Results of a Subbottom Acoustic Survey of Boston Harbor, Massachusetts’, U.S. Geol. Sur. Misc. Field Study Map MF-2124, 2 sheets.

  • Robinson, W.E., Sullivan, P.A., McAndrews, R.R. and Marcou, R.D.: 1992, ‘A Five-Year Baseline of Boston Harbor Nutrient Data’, Boston Harbor/Massachusetts Bays Symposium, Proceed., p. 33.

  • Slater, J.M. and Capone, D.G.: 1987, ‘Denitrification in Aquifer Soil and Nearshore Marine Sediments Influenced by Ground Water Nitrate’, App. Environ. Microbiol. 53, 1292–1297.

    Google Scholar 

  • Solorzano, L.: 1969, ‘Determination of Ammonia in Natural Waters by the Phenolhypochtonite Method’, Limnol. Ocan. 14, 799–801.

    Google Scholar 

  • Valiela, I., Teal, J.M., Volkmann, S., Shafer, D. and Carpenter, E.J.: 1978, ‘Nutrient and Particulate Fluxes in a Salt Marsh Ecosystem: Tidal Exchanges and Inputs by Precipitation and Ground Water’, Limnol. Ocean. 23, 798–812.

    Google Scholar 

  • Valiela, I. and Costa, J.E.: 1988, ‘Eutrophication of Buttermilk Bay, a Cape Cod Coastal Embayment: Concentrations of Nutrients and Watershed Nutrient Budgets’, Environ. Manage. 12, 539–551.

    Google Scholar 

  • Van Den Berg, C.M.G.: 1987, ‘Electroanalytical Chemistry of Sea-Water’, In J.P. Riley (Ed.) Chemical Oceanography, Vol. 1, Academic Press, New York, pp. 198–245.

    Google Scholar 

  • Walker, E.H., Wandle, S.W. and Caswell, W.W.: 1975, ‘Hydrology and Water Resources of the Charles River Basin, Massachusetts’, U.S. Geol. Sur. Hydrol. Invest. Atlas HA-554, 2 sheets.

  • Wandle, S.W.: 1984, ‘Gazetteer of Hydrologic Characteristics of Streams in Massachusetts — Coastal River Basins of the North Shore and Massachusetts Bay’, U.S. Geol. Sur. Water-Resources Invest. 84-4281, 60 pp.

  • Winkler, L.W.: 1888, ‘The Determination of Dissolved Oxygen in Water’, Berichte Der Deutschen Chemischen Gesellschaft 21, 2843.

    Google Scholar 

  • Winograd, I.J. and Robertson, F.N.: 1978, ‘Deep Oxygenated Ground Water — Anomaly or Common Occurrence’, Science 216, 1227–1230.

    Google Scholar 

  • Wood, E.D., Armstrong, F.A.J. and Richards, F.A.: 1967, ‘Determination of Nitrate in Seawater by Cadmium-Copper Reduction to Nitrite’, J. Mar. Biol. Assoc. United Kingdom 47, 23–31.

    Google Scholar 

  • Zafiriou, O.C., Joussot-Dubien, J., Zepp, R.G. and Zika, R.G.: 1984, ‘Photochemistry of Natural Waters’, Environ. Sci. Tech. 18, 358A-371A.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Poppe, L.J., Moffett, A.M. Ground water discharge and the related nutrient and trace metal fluxes into Quincy bay, Massachusetts. Environ Monit Assess 25, 15–27 (1993). https://doi.org/10.1007/BF00549789

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00549789

Keywords

Navigation