Skip to main content
SpringerLink
Log in

Contribution to the study of SnO2-based ceramics

Part I High-temperature interactions of tin(IV)oxide with antimony(III)oxide and copper(II)oxide

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Sintered SnO2-based ceramics are considered to be promising construction materials for manufacturing stable electrodes for various technological applications. The high-temperature interactions of components, important with respect to the sintering capacity and consequently the densification, have been investigated in the binary systems SnO2-Sb2O3 and SnO2-CuO, and the ternary system SnO2-Sb2O3-CuO. In contrast to the Sno2-Sb2O3 mixtures with a poor sintering ability, the binary SnO2-CuO and ternary SnO2-Sb2O3-CuO mixtures exhibit significantly improved sintering properties owing to the formation of liquid phase (eutectic melt) in the presence of copper(II)oxide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Billehaug and H. A. Øye, Aluminium 57 (1981) 146.

    CAS  Google Scholar 

  2. W. Ziemba and B. Ziemba, Szklo i Ceram. 24 (1973) 12.

    CAS  Google Scholar 

  3. T. Chvatal, Sprechsaal Keram. Glass Baust. B107 (1974) 1057.

    Google Scholar 

  4. H. Alder, US Patent 4 057 480 (1977).

  5. Idem, US Patent 3 930 967 (1976).

  6. Idem, US Patent 3 960 678 (1976).

  7. J. M. Clark and D. R. Secrist, US Patent 4 379 033 (1983).

  8. D. R. Secrist and J. M. Clark, US Patent 4448997 (1984).

  9. L. D. Loch, J. Electrochem. Soc. 110 (1963) 108.

    Article  Google Scholar 

  10. R. W. Mar, J. Phys. Chem. Solids 33 (1972) 220.

    Article  CAS  Google Scholar 

  11. E. V. Degtyareva, B. G. Alapin, V. J. Drozd, I. I. Kabakova, S. V. Lysak and N. V. Gulko, Ogneupory 10 (1978) 40.

    Google Scholar 

  12. B. G. Alapin, E. U. Degtyareva, V. J. Drozd, N. V. Gulko and S. V. Lysak, Izv. Akad. Nauk SSSR, Neorg. Mat. 17 (1981) 923.

    CAS  Google Scholar 

  13. C. Pascal, Nouveau traité de chimie mineral, Vol. 4, 8 (Masson et Cie., Paris, 1958, 1963).

    Google Scholar 

  14. JCPDS Powder Diffraction File: 19081 (1973).

  15. E. M. Levin, C. R. Robbins and H. F. McMurdie, “Phase Diagrams for Ceramists” (The American Ceramic Society, Columbus, Ohio, 1964) (Supplement 1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Centre of Physical Chemistry, Romanian Academy, Bucharest, Romania

    M. Zaharescu, S. Mihaiu & S. Zuca

  2. Institute of Inorganic Chemistry, Centre for Chemical Research, Slovak Academy of Sciences, Bratislava, Czech Republic

    K. Matiasovsky

Authors
  1. M. Zaharescu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Mihaiu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Zuca
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. Matiasovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zaharescu, M., Mihaiu, S., Zuca, S. et al. Contribution to the study of SnO2-based ceramics. J Mater Sci 26, 1666–1672 (1991). https://doi.org/10.1007/BF00544680

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00544680

Keywords

Search

Navigation