Abstract
A review is given of the results obtained in the field of materials science using the comparatively new technique of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Particular emphasis is placed on the determination of the atomic distribution functions in amorphous and multi-component materials, especially metallic and oxide glasses, catalysts and alloys. The advantages and disadvantages of the technique compared to diffraction studies are discussed.
Similar content being viewed by others
References
T. M. Hayes, J. Non-Cryst. Solids 31 (1978) 57.
S. J. Gurman, in “Extended X-ray Absorption Fine Structure” edited by R. W. Joyner (Plenum Press, New York 1981) Chap. 4.
R. F. Pettifer, in Proceedings of the 4th European Physical Society General Conference, 1979” (Institute of Physics, London, 1979) p. 522.
F. W. Lytle, G. H. Via and J. H. Sinfelt, in “Synchroton Radiation Research” edited by S. Doniach and H. Winick (Plenum Press, New York, 1980) p. 401.
S. I. Chan, V. W. Hu and R. C. Gamble, J. Mol. Struct. 45 (1978) 239.
O. Gutteridge, in “Extended X-ray Absorption Fine Structure” edited by R. W. Joyner (Plenum Press, New York, 1981) Chap. V.
J. Wong, in “Metallic Glasses I” edited by H. J. Guntherodt and H. Beck (Springer-Verlag, Berlin, 1981) p. 71.
B. K. Teo and D. C. Joy (EDS) “EXAFS Spectroscopy” (Plenum Press, New York, 1981).
R. W. Joyner (ED) “Extended X-ray Absorption Fine Structure” (Plenum Press, New York, 1981).
H. A. Bethe and E. Salpeter, “Quantum Mechanics of One- and Two-Electron Systems” (Springer-Verlag, Berlin, 1959).
J. A. Victoreen, “International Tables for X-ray Crystallography” Vol 3 (Kynoch Press, Birmingham, 1962).
R. De L. Kronig, Z. Physik 70 (1931) 317.
Idem, ibid. 75 (1932) 191.
Idem, ibid. 75 (1932) 468.
D. E. Sayers, F. W. Lytle and E. A. Stern, Adv. X-ray Anal. 13 (1970) 248.
C. A. Ashley and S. Doniach, Phys. Rev. B11 (1975) 1279.
P. A. Lee and J. B. Pendry, Phys. Rev. B11 (1975) 2795.
S. J. Gurman, SRC Daresbury Laboratory (UK). Technical Memorandum DL/SCI/TM 21T (1980).
S. J. Gurman and J. B. Pendry, Solid State Commun., 20 (1976) 287.
R. F. Pettifer and P. W. McMillan, Phil. Mag. 35 (1977) 871.
R. Haensel, P. Rabe, G. Tolkiehn and A. Werner, in “Proceedings of NATO Advanced Study Institute: Liquid and Amorphous Metals” edited by E. Luscher (D. Reidel, Dodrecht, 1980).
A. Bienenstock, in “The Structure of Non-Crystalline Materials” edited by P. H. Gaskell (Taylor and Francis, London, 1977).
S. J. Gurman and R. F. Pettifer, Phil. Mag. B40 (1979) 345.
M. A. Mazid, M. T. Razi, P. J. Sadler, G. N. Greaves, S. J. Gurman, M. H. J. Koch and J. C. Phillips, J. Chem. Soc. Chem. Commun. (1980) 1261.
G. N. Greaves, A. Fontaine, P. Lagarde and D. Raoux, S.R.C. Daresbury Laboratory (UK) DL/SCI/R17, (1981).
P. H. Citrin, P. Eisenberger and B. M. Kincaid, Phys. Rev. Lett. 36 (1976) 1346.
A. Cox and P. W. McMillan, J. Non-Cryst. Solids 44 (1981) 257.
G. S. Brown, P. Eisenberger and P. Schmidt, Solid State Commun. 24 (1977) 201.
P. Rabe, G. Martens, N. Schwenter and A. Werner, Phys. Rev. Lett. 39 (1977) 1411.
P. Rabe, G. Tolkiehn and A. Werner, J. Phys. C12 (1979) 1173.
H. J. Guntherodt and H. Beck (EDS) “Metallic Glasses I” (Springer-Verlag, Berlin, 1981).
B. K. Agrawal, “X-ray Spectroscopy” (Springer-Verlag, Berlin 1979).
I. W. Donald and H. A. Davies, J. Non-Cryst. Solids 30 (1978) 77.
G. S. Cargill III, Solid State Phys. 30 (1975) 227.
J. D. Bernal, Proc. Roy. Soc. A280 (1964) 299.
L. Von Heimendahl, J. Phys. F9 (1979) 161.
J. Hafner, Phys. Rev. B21 (1980) 406.
R. Kumaravadivel and R. Evans, J. Phys. C9 (1976) 3877.
A. Sadoc, D. Raoux, P. Lagarde and A. Fontaine, J. Non-Cryst. Solids, to be published.
D. Raoux, J. F. Sadoc, P. Lagarde, A. Sadoc and A. Fontaine, J. Phys. Colloq. C8 (1980) 207.
M. De Crescenzi, A. Balzarotti, F. Comin, L. Incoccia, S. Mobilio and N. Motta, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems”, edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 199.
P. A. Lee and G. Beni, Phys. Rev. B15 (1977) 2862.
P. Eisenberger and G. S. Brown, Solid State Commun. 29 (1979) 481.
H. S. Chen and Y. Waseda, Phys. Stat. Sol. A51 (1979) 593.
J. Chang and D. B. Dove, J. Non-Cryst. Solids 16 (1974) 72.
M. Sakata, N. Cowlam and H. A. Davies, J. Phys. Colloq. C8 (1980) 190.
R. F. Pettifer, J. Bordas, I. Donald, B. G. Lewis and H. A. Davies, to be published.
E. A. Stern, S. Rinaldi, E. Callen, S. Heald and B. Bunker, J. Magn. Magn. Mater. 7 (1978) 188.
D. E. Polk, Acta Metall. 20 (1972) 485.
S. K. Mitra and R. W. Hockney, J. Phys. C13 (1980) L739.
D. S. Boudreaux, Phys. Rev. B18 (1978) 4039.
J. F. Sadoc and J. Dixmier, in ‘The Structure of Non-Crystalline Materials” edited by P. H. Gaskell (Taylor and Francis, London, 1977).
T. M. Hayes, J. W. Allen, J. Tauc, B. C. Geissen and J. J. Hauser, Phys. Rev. Lett. 40 (1978) 1282.
G. N. Greaves, S. R. Elliott and E. A. Davis, Adv. Phys. 28 (1979) 49.
H. Oyanagi, K. Tsuji, S. Hosoya, S. Minomura and T. Fukamachi, J. Non-Cryst. Solids 35 (1980) 555.
K. Yamada, unpublished thesis, Tohoku University.
K. Tamura, J. Fukushima, H. Endo, S. Kishi, S. Ikeda and S. Minomura, J. Phys. Soc. Japan 36 (1974) 565.
N. F. Mott and E. A. Davis, “Electronic Processes in Non-Crystalline Materials” 2nd edn. (Oxford University Press, Oxford, London, New York, 1979).
H. S. Chen, in “The Structure of Non-Crystalline Materials” edited by P. H. Gaskell (Taylor and Francis, London, 1977).
R. Hasegawa and R. Ray, J. Appl. Phys. 49 (1978) 4174.
A. P. Malozemoff, M. Grimsditch, J. Aboaf and A. Braunsch, ibid. 50 (1979) 5885.
M. De Crescenzi, A. Balzarotti, F. Comin, L. Incoccia, S. Mobilio and D. Bacci, J. Phys. Colloq. C8 (1980) 238.
G. S. Cargill III, in “Proceedings of the Fourth International Conference on Rapidly Quenched Metals”, Sendai, 1981 (Physical Society of Japan).
B. K. Teo and P. A. Lee, J. Amer. Chem. Soc. 101 (1979) 2815.
Y. Waseda and H. S. Chen, Phys. Stat. Sol. A49 (1978) 387.
J. Wong, H. H. Liebermann and R. P. Messmer, J. Mater. Sci. to be published.
Y. Waseda and H. S. Chen, Solid State Commun. 27 (1978) 809.
P. Lagarde, D. Raoux and A. Fontaine, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems” edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 122.
R. F. Pettifer, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems”, edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 57.
J. Stohr, L. Johansson, I. Lindau and P. Pianetta, Phys. Rev. B20 (1979) 664.
R. Fox and S. J. Gurman, J. Phys. C13, (1980) L249.
Idem, Phys. Chem. Glasses 22 (1981) 32.
G. N. Greaves, A. Fontaine, P. Lagarde, D. Raoux, S. J. Gurman and S. Parke, in “Proceedings of the 1st EPS Condensed Matter Conference, Antwerp 1980” (in press).
A. Fontaine, P. Lagarde, D. Raoux and J. M. Esteva, J. Phys. F9 (1979) 2143.
R. L. Mozzi and B. E. Warren, J. Appl. Crystallogr. 2 (1969) 164.
G. N. Greaves, A. Fontaine, P. Lagarde, D. Raoux and S. J. Gurman, Nature 293 (1981) 611.
T. F. Soules, J. Chem. Phys. 71 (1979) 4570.
C. A. Coulson, “Valence”, 2nd edn. (Oxford University Press, Oxford, London and New York, 1961).
W. L. Bragg and G. F. Claringbull, “Crystal Structures of Minerals” (G. Bell, London, 1965).
W. H. Zachariasen, J. Amer. Chem. Soc. 54 (1932) 3841.
D. R. Sandstrom, F. W. Lytle, P. S. P. Wei, R. B. Greegor, J. Wong and P. Schultz, J. Non-Cryst. Solids 41 (1980) 201.
J. Petiau, G. Calas, P. Bondot, C. Lapeyre, P. Levitz and G. Loupias, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems”, edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 127.
R. F. Pettifer, in “Proceedings of the 4th E.P.S. General Conference, York, 1979” (Institute of Physics, London, 1979) p. 522.
J. Wong and C. A. Angell, “Glass: Structure by Spectroscopy” (Marcel Dekker, New York, 1976).
W. F. Nelson, I. Siegel and R. W. Wagner, Phys. Rev. 127 (1962) 2025.
D. E. Sayers, F. W. Lytle and E. A. Stern, J. Non-Cryst. Solids 8–10 (1972) 401.
J. Wong and F. W. Lytle, ibid. 37 (1980) 273.
J. H. Sinfelt, Rev. Mod. Phys. 51 (1979) 569.
J. J. Burton, Catal. Rev. 9 (1974) 209.
G. H. Via, J. H. Sinfelt and F. W. Lytle, J. Chem. Phys. 71 (1979) 690.
B. Moraweck, G. Clugnet and A. J. Renouprez, Surf. Sci. 81 (1979) L631.
B. Moraweck and A. J. Renouprez, ibid. 106 (1981) 35.
R. W. Joyner, J. Chem. Soc. Faraday I 76 (1980) 357.
I. W. Bassi, F. W. Lytle and G. Parravano, J. Catal. 42 (1976) 139.
G. Apai, J. F. Hamilton, J. Stohr and A. Thompson, Phys. Rev. Lett. 43 (1979) 165.
R. W. Joyner, B. Lang and G. A. Somorjai, J. Catal. 27 (1972) 405.
R. B. Greegor and F. W. Lytle, J. Catal. 63 (1980) 476.
T. Uchijima, J. M. Hermann, Y. Inoue, R. L. Burwell, Jr, J. B. Butt and J. B. Cohen, ibid. 50 (1977) 464.
M. Boudart, A. Aldag, J. E. Benson, N. A. Dougharty and C. G. Harkins, ibid. 6 (1966) 92.
J. H. Sinfelt, G. H. Via and F. W. Lytle, J. Chem. Phys. 72 (1980) 4832.
R. W. Joyner, J. Chem. Soc. Faraday I, to be published.
G. Vlaic, J. C. J. Bart, W. Cavigiolo, S. Mobilio and G. Navarra, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems”, edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 133.
G. Martens, P. Rabe, N. Schwentner and A. Werner, Phys. Rev. B17 (1978) 1481.
J. Reed, P. Eisenberger and J. Hastings, Inorg. Chem. 17 (1978) 481.
E. L. Gal'perin and R. A. Sandler, Sov. Phys. Cryst. 7 (1972) 169.
F. W. Lytle, D. E. Sayers and E. B. Moore, Appl. Phys. Lett. 24 (1974) 45.
L. Alagna, A. A. G. Tomlinson, C. Ferragina and A. La Ginestra, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems” edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 98.
B. Lengeler and P. Eisenberger, Phys. Rev. B21 (1980) 4507.
H. Maeda, T. Tanimoto, H. Terauchi and M. Hida, Phys. Stat. Sol. A58 (1980) 629.
S. K. Prasad, S. P. Singhal, H. Herman, J. A. Del Cueto and N. J. Shevchik, Scr. Metall. 13 (1979) 549.
A. Fontaine, P. Lagarde, A. Naudon, D. Raoux and D. Spanjaard, Phys. Mag. B40 (1979) 17.
A. M. Flank, A. Fontaine, P. Lagarde, M. Lemmonier, J. Mimault, D. Raoux and A. Sadoc, in “Proceedings of the Daresbury Study Weekend: EXAFS for Inorganic Systems” edited by C. D. Garner and S. S. Hasnain (S.R.C. Daresbury Laboratory, 1981) p. 70.
A. Sur, J. L. Lebowitz, J. Marro and M. K. Kalos, Phys. Rev. B15 (1977) 3014.
W. J. Pardee, W. M. Robertson and M. R. James, Scr. Metall. 14 (1980) 1333.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gurman, S.J. EXAFS studies in materials science. J Mater Sci 17, 1541–1570 (1982). https://doi.org/10.1007/BF00540779
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00540779