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Effect of the composition and topology of the coordination polyhedron on electron transfer in d 9/d 10 redox systems

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Abstract

The effect of the composition and topology of the coordination sphere on the redox potentials of d9/d10 pairs and the kinetic parameters of electron transfer reactions involving such pairs has been reviewed.

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  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences, 31 Prospekt Nauki, 252039, Kiev, Ukraine

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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 31, No. 1, pp. 1–28, January–February, 1995.

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Pavlishchuk, V.V. Effect of the composition and topology of the coordination polyhedron on electron transfer in d 9/d 10 redox systems. Theor Exp Chem 31, 1–26 (1995). https://doi.org/10.1007/BF00536133

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