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Conversions in epoxy-anhydride system initiated by a photogenerated donor-acceptor complex

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Abstract

Conversions of an epoxy-containing system, photoinduced by means of a charge transfer complex of maleic anhydride with tetrahydrofuran, have been studied spectrophotometrically. Opening of the epoxy and anhydride rings is accompanied by incorporation of the fragments into the polymer chain in the form of ester groupings. Specific features of these transformations are dependent on the nature of the rings, the content of donor-acceptor complex in the system, and the addition of polyols.

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References

  1. G. Ya. Menzheres, M. S. Kligshtein, A. A. Degtyareva, et al., Teor. Éksp. Khim., 26, No. 3, 325–331 (1990).

    Google Scholar 

  2. M. Irie, Y. Yamamoto, and K. Hayashi, J. Macromol. Sci. A, 9, No. 5, 817–832 (1975).

    Google Scholar 

  3. I. Tong, C. Wei-Xiao, and F. Xin-De, J. Macromol. Sci., Rev. Macromol. Chem. Phys., 29, No. 2/3, 153–199 (1989).

    Google Scholar 

  4. R. K. Sadhir and H. T. Saunders, U.S. Pat. 4,845,116, IC4 C 08 G 59/42, 59/62, Publ. 04.06.89.

  5. L. J. Bellamy, Advances in Infrared Group Frequencies, Halsted, New York (1968).

    Google Scholar 

  6. A. A. Degtyareva, G. Ya. Menzheres, N. V. Yarovaya, et al., Zh. Prikl. Khim., 64, No. 7, 1541–1546 (1991).

    Google Scholar 

  7. K. Nakanishi, Infrared Absorption Spectroscopy, Holden-Day, San Francisco (1962).

    Google Scholar 

  8. C. Serboli, Kunst.-Plast., No. 3, 150–156 (1966).

    Google Scholar 

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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 4, pp. 227–230, July–August, 1994.

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Menzheres, G.Y., Yarovaya, N.V., Degtyareva, A.A. et al. Conversions in epoxy-anhydride system initiated by a photogenerated donor-acceptor complex. Theor Exp Chem 30, 191–194 (1995). https://doi.org/10.1007/BF00534662

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  • DOI: https://doi.org/10.1007/BF00534662

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