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Literature cited
B. P. Belousov, “A periodically acting reaction and its mechanism” in: Papers on Radiation Medicine in 1958–1959 [in Russian], Medgiz, Moscow (1959), pp. 145–147.
A. M. Zhabotinskii, “Periodic oxidation reactions in the liquid phase,” Dokl. Akad. Nauk SSSR, 157, No. 2, 392–393 (1964).
V. A. Vavilin and A. M. Zhabotinskii, “Autocatalytic oxidation reaction of trivalent cerium with bromate. I,” Kinet. katal., 10, No. 1, 83–88 (1969).
G. J. Kasperek and C. Bruice, “Observation on an oscillating reaction. The reaction of potassium bromate, ceric sulfate, and dicarboxylic acid,” Inorg. Chem., 10, No. 2, 382–386 (1971).
C. Herbo, G. Schmitz, and Van Glabbeke, “Reaction oscillante de Belousov. I. Cinétique de la réaction bromate-cereux,” Can. J. Chem., 54, 2628–2638 (1976).
E. Körös, M. Burger, and A. Kis, “Reduction of bromine(V) by tris (l,10-phenanthroline)-iron(II) in aqueous sulfuric acid,” React. Kinet. Catal. Lett., 1, No. 4, 475–480 (1974).
R. G. Thompson, “Reduction of bromine(V) by cerium(III), manganese(II), and neptunium(V) in aqueous sulfurus acid,” J. Am. Chem. Soc., 93, No. 26, 7314 (1971).
R. M. Noyes, R. J. Field, and R. G. Thompson, “Mechanism of reaction of bromine(V) with weak one-electron reducing agents,” J. Am. Chem. Soc., 93, No. 26, 7314–7315 (1971).
R. J. Field, E. Körös, and R. M. Noyes, “Oscillations in chemical systems. II. Thorough analysis of temporal oscillation in the bromate-cerium-malonic acid system,” J. Am. Chem. Soc., 94, No. 25, 8649–8664 (1972).
Chemist's Handbook [in Russian], Vol. 3, Khimiya, Moscow-Leningrad (1964).
C. Hinshelwood, “Present-day chemical kinetics,” J. Chem. Soc., No. 5, 694–701 (1947).
A. Skrabal and H. Schreiner, “Reduction velocity of HClO3 and HBrO3,” Monatsh. Chem., 65, No. 3, 213–216 (1935).
G. V. Buxton and F. S. Dainton, “The radiolysis of aqueous solution of oxybromine compounds; the spectra and reactions of BrO and BrO2,” Proc. Roy. Soc., A, 304, No. 1479, 427–439 (1968).
C. A. Coulson, “The stability of H2 + and OH+ in aqueous solutions,” J. Chem. Soc., No. 3, 778–780 (1956).
E. A. Shilov and N. P. Kanyaev, “Bromine cation as a brominating agent,” Dokl. Akad. Nauk SSSR, 24, No. 9, 890–892 (1939).
W. J. Wilson and F. G. Soper, “The mechanism of bromine substitution in aqueous solution,” J. Chem. Soc., No. 13, 3376–3379 (1949).
D. H. Derbishire and W. A. Waters, “Significance of bromine cation in aromatic substitution. I. Kinetic evidence,” J. Chem. Soc., No. 2, 564–573 (1950).
A. Massagli, A. Indelli, and F. Pergola, “Kinetic investigation of the decomposition of bromite,” Inorg. Chim. Acata, 4, No. 4, 593–596 (1970).
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Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 14, No. 2, pp. 183–192, March–April, 1978.
The authors thank A. N. Zaikin for his comments on the work.
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Rovinskii, A.B., Zhabotinskii, A.M. The mechanism of the autocatalytic oxidation reaction of Ce3+ with bromate. Theor Exp Chem 14, 142–150 (1978). https://doi.org/10.1007/BF00518061
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DOI: https://doi.org/10.1007/BF00518061