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A model for sorption, flux and plant uptake of cadmium in a soil profile: Model structure and sensitivity analysis

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Abstract

Fluxes of cadmium in a soil profile are simulated by coupling a model for linear and nonlinear equilibrium sorption to an existing hydrological model. The aim is to develop a model for Cd transport in soil systems. A separate flow model is used to calculate the water fluxes, which are then used in an equilibrium sorption model, allowing different Freundlich isotherms to be chosen. The model is tested and a sensitivity analysis is made. The variation of soil compartment sizes gave small changes in the results, which is interpreted as a measure of the solution stability. The factor influencing Cd transport most, according to these simulations, is the sorption isotherm. The degree to which Cd sorbs to soil decides how much will be available in the soil water for plant uptake or transport through the soil to the ground water. Other studied factors such as root distribution and hydrological properties influence the result only to a limited degree. With an application of 10 mg Cd/m2 in the given range of Freundlich isotherms, the simulations gave a plant uptake of between 0 and 30% of the applied Cd in two years. At the concentration mainly used in this study (with 10 mg Cd/m2 applied), the nonlinear isotherms found in the literature gave Cd lower mobility than the linear isotherms used for comparison. For high Cd concentrations the situation would be the reverse.

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References

  • Bache, C. A., and Lisk, D. J.: 1990. J. Agric. Food Chem. 38, 190–194.

    Google Scholar 

  • Bell, F. B., James R. J., and Chaney R.: 1991. J. Environ. Qual. 20, 481–486.

    Google Scholar 

  • Bramryd, T.: 1985. Torv- och vedaska som gödselmedel. Effekter på Produktion, näringsbalans och tungmetallupptag. SNV pm 1997. English abstract. Swedish Environmental Protection Agency.

  • Chardon, W. J.: 1984. Mobiliteit van cadmium in de bodem. Dissertation (in Dutch). Wageningen.

  • Christensen, T. H.: 1989. Cadmium soil sorption at low concentrations. Dissertation. Department of Environmental Engineering. Technical University of Denmark, Polyteknisk Forlag.

    Google Scholar 

  • Eriksson, J. E.: 1990. Factors influencing adsorption and plant uptake of cadmium from agricultural soils. Department of Soil Sciences. Reports and Dissertations 4. Swedish University of Agricultural Sciences, Uppsala.

    Google Scholar 

  • Ertel, J., Pröhl, G., and Paretzke, H. G.: 1991. Joint Int. Symp. on Environmental Consequences of Hazard. Waste Disp. Proceedings Vol II. Allmänna Förlaget, Stockholm, pp 299–308.

    Google Scholar 

  • Friberg, L., Piscator, M., and Nordberg, G.: 1971. Cadmium in the environment, CRC Press, The Chemical Rubber company, Cleveland, Ohio.

    Google Scholar 

  • Jansson, P.-E.: 1990. SOIL water and heat model. Technical description. Department of Soil Science, Swedish University of Agricultural Sciences, Uppsala.

    Google Scholar 

  • Jansson, P.-E.: 1991. SOIL model. User's manual. Department of Soil Science, Swedish University of Agricultural Sciences, Uppsala,

    Google Scholar 

  • de Marsily, G.: 1986. Quantitative Hydrogeology. Academic Press, Inc.

  • Monteith, J. L., and Unsworth, M. H.: 1990. Principles of Environmental Physics. Second edition. Edward Arnold.

  • Nielsen, D. R., van Genuchten, M., and Biggar, J. W.: 1986. Water Resources Research 22, 89S-108S.

    Google Scholar 

  • Nilsson, J., and Timm, B.: 1983. Miljöeffekter av ved- och torvförbränning. SNV pm 1708. English abstract. Swedish Environmental Protection Agency.

  • Nilsson, R.: 1990. Cadmium — An analysis of Swedish Regulatory Experience. KEMI report No 6/90. The Swedish national chemicals inspectorate.

  • Persson, G.: 1991. Hydrologiska konsekvenser av energiskogsodling. Slutrapport (in Swedish). Inst. för Markvetenskap, Swedish University of Agricultural Sciences, Uppsala.

    Google Scholar 

  • Poelstra, P., Frissel, M. J., and El-Bassam, N.: 1979. Z. Planzenernaehr. Bodenkd. 142, 848–864.

    Google Scholar 

  • Richards, L. A.: 1931. Physics 1, 318–333.

    Google Scholar 

  • Sigfrid, L., Tamaddon, R, and Hogland, W.: 1992. Kadmium i produkter och avfall. Bedömning av mängder samt åtgärdsförslag. (in Swedish). Institutionen för teknisk vattenresurslära, University of Lund.

  • Sposito, G.: 1984. The surface chemistry of soils. Clarendon Press, Oxford.

    Google Scholar 

  • Travis, C. C., and Etnier, E. L.: 1981. J. Environ. Qual. 10, 8–17.

    Google Scholar 

  • Wiklert, P., Andersson, S., and Weidow, B.: 1983. Studier av markprofiler i svenska åkerjordar. En faktasammanställning. Del V. Skaraborgs län. (in Swedish). Inst. för Markvetenskap, Swedish University of Agricultural Sciences, Uppsala.

    Google Scholar 

  • Zöttl, H. W.: 1985. Experientia 41, Birkhäuser Verlag 1104–1113.

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  1. Swedish Environmental Research Institute, Box 210 60, S-100 31, Stockholm, Sweden

    V. Palm

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  1. V. Palm
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Palm, V. A model for sorption, flux and plant uptake of cadmium in a soil profile: Model structure and sensitivity analysis. Water Air Soil Pollut 77, 169–190 (1994). https://doi.org/10.1007/BF00483056

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  • DOI: https://doi.org/10.1007/BF00483056

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