Skip to main content
Log in

Inter-regional comparison of patterns and trends in surface water acidification across the United States

  • Published:
Water, Air, and Soil Pollution Aims and scope Submit manuscript

Abstract

Temporal trends in acid-base chemistry are reported for surface waters in 6 regions of the United States. The lakes and streams are low ANC, dilute systems, selected to represent acid-sensitive aquatic resources in the 6 regions. The predominant trends observed were decreases in lake and stream SO4 2− concentrations in sites east of the Mississippi River, and increases in NO3 in the Adirondack lake and Catskill stream sites (both located in eastern New York State). Correlations of trend results from all sites with other factors indicated that trends in precipitation volume were highly correlated with the observed trend patterns. From the surface water trend results, three distinct clusters were identified that corresponded to three trend patterns: ‘dilution,’ ‘recovery,’ and ‘acidification.’ These were distributed across the LTM regions, with no particular geographic patterns.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Alley, W.M.: 1988, Water Resources Res., 24, 1955.

    Google Scholar 

  • Altshuller, A.P. and MacBean, G.A.: 1980, Second Report of the U.S.-Canada Research Consultation Group on Long-Range Transport of Air Pollutants, Environment Canada, Ottawa.

    Google Scholar 

  • Asbury, C.E., Vertucci, F.A., Mattson, M.D., Likens, G.E.: 1989, Environ. Science and Technol., 23, 362.

    Google Scholar 

  • Baker, L.A.: 1984, Mineral and Nutrient Cycles and their Effect on the Proton Balance of a Soft-Water, Acidic Lake, Ph.D. dissertation, Univ. of Florida, Gainesville, FL.

    Google Scholar 

  • Baker, L.A., Herlihy, A.T., Kaufmann, P.R., Eilers, J.E.: 1991, Science 252, 1151.

    Google Scholar 

  • Climatedata: 1988, Climatedata User's Manual, U.S.West Optical Publishing, Denver, Co.

    Google Scholar 

  • Craig, D. and Johnston, L.M.: 1988, Can. J. Fish. Aquat. Sci. 45, 59.

    Google Scholar 

  • Dillon, P.J., Reid, R.A. and de Grosbois, E.: 1987, Nature 329, 45.

    Google Scholar 

  • Driscoll, C.T., Likens, G.E., Hedin, L.O., Eaton, J.S., Bormann, F.H.: 1989, Environ. Sci. and Technol. 23, 137.

    Google Scholar 

  • Driscoll, C.T. and Van Dreason, R.: Water, Air and Soil Pollut, this volume.

  • Eilers, J.M. and Selle, A.R.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, D.F. Charles, ed. Springer Verlag, New York, pp 107.

    Google Scholar 

  • Galloway, J.N.: 1984, in The Acidic Deposition Phenomenon and Its Effects. Critical Assessment Review Papers, Vol. II: Effects Sciences, Altshuller, A.P. and Linthurst, R.A., editors. EPA-600/8-83-016, U.S.Environmental Protection Agency, Washington, D.C.

    Google Scholar 

  • Hendrey, G.R., Galloway, J.N., Norton, S.A., Schofield, C.L., Shaffer, P.W. and Burns, D.A.: 1980, Geological and Hydrochemical Sensitivity of the Eastern U.S. to Acid Precipitation, EPA/600/3-80-024, U.S.Environmental Protection Agency, Corvallis, OR.

    Google Scholar 

  • Hirsch, R.M. and Slack, J.R.: 1984, Water Resources Research 20, 727.

    Google Scholar 

  • Hirsch, R.M., Slack, J.R. and Smith, R.A.: 1982, Water Resources Research 18, 107.

    Google Scholar 

  • Husar, R.B., Sullivan, T.J., Charles, D.F.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, D.F. Charles, ed. Springer Verlag, New York, pp. 65.

    Google Scholar 

  • Husar, R.B.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, D.F. Charles, ed. Springer Verlag, New York, pp. 653.

    Google Scholar 

  • Irwin, J.G.: 1989, Arch. Environ. Contam. and Toxicol. 18, 95.

    Google Scholar 

  • Kahl, J.S., Norton, S.A., Haines, T.A., Davis, R.B.: Water, Air and Soil Pollut., this volume.

  • Kaufmann, P.R., Herlihy, A.T., Elwood, J.W., Mitch, M.E., Overton, W.S., Sale, M.J., Messer, J.J., Cougan, K.A., Peck, D.V., Reckhow, K.H., Kinney, A.J., Christie, S.J., Brown, D.D., Hagley, C.A., Jager, H.I.: 1988, Chemical Characteristics of Streams in the Mid-Atlantic and Southeastern United States. Volume I: Population Descriptions and Physico-Chemical Relationships. EPA/600/3-88/021a. U.S.E.P.A., Washington, D.C.

    Google Scholar 

  • Kenoyer, G.J. and Anderson, M.P.: 1989, J. Hydrol. 109, 206.

    Google Scholar 

  • Kelso, J.R.M., Jeffries, D.S.: 1988, Can. J. Fish. Aquat. Sci. 45, 1905.

    Google Scholar 

  • Landers, D.H., Eilers, J.M., Brakke, D.F., Overton, S.W., Kellar, P.E., Silverstein, M.E., Schonbrod, R.D., Crowe, R.E., Linthurst, R.A., Omernik, J.M., Teague, S.A., Meier, E.P.: 1987, Western Lake Survey Phase I, Characteristics of Lakes in the Western United States, Volume I: Population Descriptions and Physico-Chemical Relationships. EPA/600/3-86/054a. U.S.E.P.A., Washington, D.C.

    Google Scholar 

  • Lettenmeier, D.P., Hooper, E.R., Wagoner, C., Faris, K.: 1991, Water Resour. Res. 27, 327.

    Google Scholar 

  • Linthurst, R.A., Landers, D.H., Eilers, J.M., Brakke, D.F., Overton, W.S., Meier, E.P., Crowe, R.E.: 1986, Characteristics of Lakes in the Eastern United States, Volume I: Population Descriptions and Physico-Chemical Relationships. EPA/600/3-86/007a. U.S.E.P.A., Washington, D.C.

    Google Scholar 

  • Magnuson, J.J, Bowser, C.J. and Beckel, A.L.: 1983, L & S Magazine Fall, 3.

    Google Scholar 

  • Magnuson, J.J.: 1990, Bioscience 40, 501.

    Google Scholar 

  • Murdoch, P.S. and Stoddard, J.L.: in press, Water Resour. Res.

  • Murdoch, P.S. and Stoddard, J.L.: Water, Air and Soil Pollut. this volume.

  • Neary, B.P. and Dillon, P.J.: 1988, Nature 333, 340.

    Google Scholar 

  • Newell, A.D. and Morrison, M.L.: Water, Air and Soil Pollut., this volume.

  • Newell, A.D., Powers, C.F. and Christie, S.J.: 1987, Analysis of Data from Long-Term Monitoring of Lakes, EPA/600/4-87/014.

  • Pollman, C.D., Lee, T.M. Andrews, W.J., Sacks, L.A., Gherini, S.A., Munson, R.K.: 1991, Water Resour. Res. 27, 2321.

    Google Scholar 

  • Rapp, G., Luikkonen, B.W., Allert, J.D., Sorenson, J.A., Glass, G.E., Loucks, O.L.: 1987, Environ. Geol. Water Sci. 9, 155.

    Google Scholar 

  • Ryan, P.F., Hornberger, G.M., Cosby, B.J., Galloway, J.N., Webb, J.R. and Rastetter, E.B.: 1989, Water Resour. Res. 25, 2091.

    Google Scholar 

  • SAS: 1985, SAS User's Guide: Statistics, Version 5 Edition, SAS Institute, Inc., Cary, NC, pp 259.

    Google Scholar 

  • Schaefer, D.A and Driscoll, C.T.: Water, Air, Soil Poll., this volume.

  • Schindler, D.W., Mills, K.H., Malley, D.F., Findlay, D.L., Shearer, J.A., Davies, I.J., Turner, M.A., Linsey, G.A. and Cruikshank, D.R.: 1985, Science 228, 1395.

    Google Scholar 

  • Simpson, J.C. and Olsen, A.R.: 1990, 1987 Wet Deposition Temporal and Spatial Patterns in North America, Batelle Pacific Northwest Laboratory Report PNL-7208/UC-402, Richland, WA.

  • Smith, R.A. and Alexander, R.B.: 1983, Evidence for Acid-Precipitation-Induced Trends in Stream Chemistry at Hydrologic Bench-Mark Stations, Geological Survey Circular 910.

  • Smith, R.A. and Alexander, R.B.: 1986. Nature 322, 722.

    Google Scholar 

  • Stoddard, J.L. and Kellogg, J.H.: Water, Air and Soil Pollut., this volume.

  • Stoddard, J.L. and Murdoch, P.S.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, Charles, D.F., ed., Springer-Verlag, New York, pp. 237.

    Google Scholar 

  • Sullivan, T.J., Charles, D.F, Smol, J.P., Cummings, B.F., Selle, A.R., Thomas, D.R., Bernert, J.A. and Dixit, S.S.: 1990, Nature 345, 54.

    Google Scholar 

  • Sullivan, T.J., Eilers, J.M., Church, M.R., Blick, D.J., Eshelman, K.N., Landers, D.H., DeHaan, M.S.: 1988, Nature 331, 607.

    Google Scholar 

  • Turk, J.T.: 1983, An Evaluation of Trends in the Acidity of Precipitation and the Related Acidification of Surface Water in North America, U.S. Geological Survey Water-Supply Paper 2249.

  • Turk, J.T., Campbell, D.H. and Spahr, N.E.: Water, Air and Soil Pollut., this volume.

  • Wampler, S.J. and Olsen, A.R.: 1987, Preprint Volume: Tenth Conference on Probability and Statistics, October, 1987. Publ. American Meteorological Society, Boston, MA.

    Google Scholar 

  • Watras, C.J. and Frost, T.M.: 1989, Arch. Environ. Contam. Toxicol. 18, 157.

    Google Scholar 

  • Webster, K.E., Brezonik, P.L. and Holdhusen, B.J.: Water, Air and Soil Pollut, this volume.

  • Webster, K.E., Newell, A.D., Baker, L.A. and Brezonik, P.L.: 1990. Nature 347, 374.

    Google Scholar 

  • Wright, R.F., Lotse, E. and Semb, A.: 1988. Nature 334, 670.

    Google Scholar 

  • USEPA: 1991, Data User's Guide to the USEPA Long-Term Monitoring Project: Quality Assurance Plan and Data Dictionary, EPA/600/3-91/072.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Newell, A.D. Inter-regional comparison of patterns and trends in surface water acidification across the United States. Water Air Soil Pollut 67, 257–280 (1993). https://doi.org/10.1007/BF00478149

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00478149

Keywords

Navigation