Abstract
Temporal trends in acid-base chemistry are reported for surface waters in 6 regions of the United States. The lakes and streams are low ANC, dilute systems, selected to represent acid-sensitive aquatic resources in the 6 regions. The predominant trends observed were decreases in lake and stream SO4 2− concentrations in sites east of the Mississippi River, and increases in NO3 − in the Adirondack lake and Catskill stream sites (both located in eastern New York State). Correlations of trend results from all sites with other factors indicated that trends in precipitation volume were highly correlated with the observed trend patterns. From the surface water trend results, three distinct clusters were identified that corresponded to three trend patterns: ‘dilution,’ ‘recovery,’ and ‘acidification.’ These were distributed across the LTM regions, with no particular geographic patterns.
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References
Alley, W.M.: 1988, Water Resources Res., 24, 1955.
Altshuller, A.P. and MacBean, G.A.: 1980, Second Report of the U.S.-Canada Research Consultation Group on Long-Range Transport of Air Pollutants, Environment Canada, Ottawa.
Asbury, C.E., Vertucci, F.A., Mattson, M.D., Likens, G.E.: 1989, Environ. Science and Technol., 23, 362.
Baker, L.A.: 1984, Mineral and Nutrient Cycles and their Effect on the Proton Balance of a Soft-Water, Acidic Lake, Ph.D. dissertation, Univ. of Florida, Gainesville, FL.
Baker, L.A., Herlihy, A.T., Kaufmann, P.R., Eilers, J.E.: 1991, Science 252, 1151.
Climatedata: 1988, Climatedata User's Manual, U.S.West Optical Publishing, Denver, Co.
Craig, D. and Johnston, L.M.: 1988, Can. J. Fish. Aquat. Sci. 45, 59.
Dillon, P.J., Reid, R.A. and de Grosbois, E.: 1987, Nature 329, 45.
Driscoll, C.T., Likens, G.E., Hedin, L.O., Eaton, J.S., Bormann, F.H.: 1989, Environ. Sci. and Technol. 23, 137.
Driscoll, C.T. and Van Dreason, R.: Water, Air and Soil Pollut, this volume.
Eilers, J.M. and Selle, A.R.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, D.F. Charles, ed. Springer Verlag, New York, pp 107.
Galloway, J.N.: 1984, in The Acidic Deposition Phenomenon and Its Effects. Critical Assessment Review Papers, Vol. II: Effects Sciences, Altshuller, A.P. and Linthurst, R.A., editors. EPA-600/8-83-016, U.S.Environmental Protection Agency, Washington, D.C.
Hendrey, G.R., Galloway, J.N., Norton, S.A., Schofield, C.L., Shaffer, P.W. and Burns, D.A.: 1980, Geological and Hydrochemical Sensitivity of the Eastern U.S. to Acid Precipitation, EPA/600/3-80-024, U.S.Environmental Protection Agency, Corvallis, OR.
Hirsch, R.M. and Slack, J.R.: 1984, Water Resources Research 20, 727.
Hirsch, R.M., Slack, J.R. and Smith, R.A.: 1982, Water Resources Research 18, 107.
Husar, R.B., Sullivan, T.J., Charles, D.F.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, D.F. Charles, ed. Springer Verlag, New York, pp. 65.
Husar, R.B.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, D.F. Charles, ed. Springer Verlag, New York, pp. 653.
Irwin, J.G.: 1989, Arch. Environ. Contam. and Toxicol. 18, 95.
Kahl, J.S., Norton, S.A., Haines, T.A., Davis, R.B.: Water, Air and Soil Pollut., this volume.
Kaufmann, P.R., Herlihy, A.T., Elwood, J.W., Mitch, M.E., Overton, W.S., Sale, M.J., Messer, J.J., Cougan, K.A., Peck, D.V., Reckhow, K.H., Kinney, A.J., Christie, S.J., Brown, D.D., Hagley, C.A., Jager, H.I.: 1988, Chemical Characteristics of Streams in the Mid-Atlantic and Southeastern United States. Volume I: Population Descriptions and Physico-Chemical Relationships. EPA/600/3-88/021a. U.S.E.P.A., Washington, D.C.
Kenoyer, G.J. and Anderson, M.P.: 1989, J. Hydrol. 109, 206.
Kelso, J.R.M., Jeffries, D.S.: 1988, Can. J. Fish. Aquat. Sci. 45, 1905.
Landers, D.H., Eilers, J.M., Brakke, D.F., Overton, S.W., Kellar, P.E., Silverstein, M.E., Schonbrod, R.D., Crowe, R.E., Linthurst, R.A., Omernik, J.M., Teague, S.A., Meier, E.P.: 1987, Western Lake Survey Phase I, Characteristics of Lakes in the Western United States, Volume I: Population Descriptions and Physico-Chemical Relationships. EPA/600/3-86/054a. U.S.E.P.A., Washington, D.C.
Lettenmeier, D.P., Hooper, E.R., Wagoner, C., Faris, K.: 1991, Water Resour. Res. 27, 327.
Linthurst, R.A., Landers, D.H., Eilers, J.M., Brakke, D.F., Overton, W.S., Meier, E.P., Crowe, R.E.: 1986, Characteristics of Lakes in the Eastern United States, Volume I: Population Descriptions and Physico-Chemical Relationships. EPA/600/3-86/007a. U.S.E.P.A., Washington, D.C.
Magnuson, J.J, Bowser, C.J. and Beckel, A.L.: 1983, L & S Magazine Fall, 3.
Magnuson, J.J.: 1990, Bioscience 40, 501.
Murdoch, P.S. and Stoddard, J.L.: in press, Water Resour. Res.
Murdoch, P.S. and Stoddard, J.L.: Water, Air and Soil Pollut. this volume.
Neary, B.P. and Dillon, P.J.: 1988, Nature 333, 340.
Newell, A.D. and Morrison, M.L.: Water, Air and Soil Pollut., this volume.
Newell, A.D., Powers, C.F. and Christie, S.J.: 1987, Analysis of Data from Long-Term Monitoring of Lakes, EPA/600/4-87/014.
Pollman, C.D., Lee, T.M. Andrews, W.J., Sacks, L.A., Gherini, S.A., Munson, R.K.: 1991, Water Resour. Res. 27, 2321.
Rapp, G., Luikkonen, B.W., Allert, J.D., Sorenson, J.A., Glass, G.E., Loucks, O.L.: 1987, Environ. Geol. Water Sci. 9, 155.
Ryan, P.F., Hornberger, G.M., Cosby, B.J., Galloway, J.N., Webb, J.R. and Rastetter, E.B.: 1989, Water Resour. Res. 25, 2091.
SAS: 1985, SAS User's Guide: Statistics, Version 5 Edition, SAS Institute, Inc., Cary, NC, pp 259.
Schaefer, D.A and Driscoll, C.T.: Water, Air, Soil Poll., this volume.
Schindler, D.W., Mills, K.H., Malley, D.F., Findlay, D.L., Shearer, J.A., Davies, I.J., Turner, M.A., Linsey, G.A. and Cruikshank, D.R.: 1985, Science 228, 1395.
Simpson, J.C. and Olsen, A.R.: 1990, 1987 Wet Deposition Temporal and Spatial Patterns in North America, Batelle Pacific Northwest Laboratory Report PNL-7208/UC-402, Richland, WA.
Smith, R.A. and Alexander, R.B.: 1983, Evidence for Acid-Precipitation-Induced Trends in Stream Chemistry at Hydrologic Bench-Mark Stations, Geological Survey Circular 910.
Smith, R.A. and Alexander, R.B.: 1986. Nature 322, 722.
Stoddard, J.L. and Kellogg, J.H.: Water, Air and Soil Pollut., this volume.
Stoddard, J.L. and Murdoch, P.S.: 1991, in Acidic Deposition and Aquatic Ecosystems: Regional Case Studies, Charles, D.F., ed., Springer-Verlag, New York, pp. 237.
Sullivan, T.J., Charles, D.F, Smol, J.P., Cummings, B.F., Selle, A.R., Thomas, D.R., Bernert, J.A. and Dixit, S.S.: 1990, Nature 345, 54.
Sullivan, T.J., Eilers, J.M., Church, M.R., Blick, D.J., Eshelman, K.N., Landers, D.H., DeHaan, M.S.: 1988, Nature 331, 607.
Turk, J.T.: 1983, An Evaluation of Trends in the Acidity of Precipitation and the Related Acidification of Surface Water in North America, U.S. Geological Survey Water-Supply Paper 2249.
Turk, J.T., Campbell, D.H. and Spahr, N.E.: Water, Air and Soil Pollut., this volume.
Wampler, S.J. and Olsen, A.R.: 1987, Preprint Volume: Tenth Conference on Probability and Statistics, October, 1987. Publ. American Meteorological Society, Boston, MA.
Watras, C.J. and Frost, T.M.: 1989, Arch. Environ. Contam. Toxicol. 18, 157.
Webster, K.E., Brezonik, P.L. and Holdhusen, B.J.: Water, Air and Soil Pollut, this volume.
Webster, K.E., Newell, A.D., Baker, L.A. and Brezonik, P.L.: 1990. Nature 347, 374.
Wright, R.F., Lotse, E. and Semb, A.: 1988. Nature 334, 670.
USEPA: 1991, Data User's Guide to the USEPA Long-Term Monitoring Project: Quality Assurance Plan and Data Dictionary, EPA/600/3-91/072.
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Newell, A.D. Inter-regional comparison of patterns and trends in surface water acidification across the United States. Water Air Soil Pollut 67, 257–280 (1993). https://doi.org/10.1007/BF00478149
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DOI: https://doi.org/10.1007/BF00478149