Skip to main content
Log in

Ring inversion in 5,5-disubstituted 1,3-dioxanes

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The conformational mobility was studied by dynamic PMR and the free energies of activation of the conformational transitions of 5,5-bis(chloromethyl)-, 5,5-bis(iodomethyl)- and 2,3-pentamethylene-bis-5,5-bis(chloromethyl)-1,3-dioxanes were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature Cited

  1. Yu. Yu. Samitov, Atlas of Nuclear Magnetic Resonance Spectra of Steric Isomers [in Russian], Vol. 1, Izd-vo-Kazan'sk. Univ. Kazan' (1978).

  2. N. S. Zefirov and I. V. Kazimirchik, Usp. Khim., 43, 252 (1974).

    Google Scholar 

  3. E. L. Eliel and R. J. Enanoza, J. Am. Chem. Soc., 94, 8072 (1972).

    Google Scholar 

  4. L. H. Piette and W. A. Anderson, J. Chem. Soc., No. 3, 899 (1959).

    Google Scholar 

  5. I. E. Anderson and I. C. Brand, Trans. Faraday Soc., 62, 39 (1966).

    Google Scholar 

  6. H. Friebolin, S. Kabyss, and W. Maier, Tetrahedron Lett., No. 16, 683 (1962).

    Google Scholar 

  7. H. Friebolin and H. G. Schmid, Org. Magn. Reson., 1, 67 (1969).

    Google Scholar 

  8. E. Goene and M. Anteunis, Bull. Soc. Chim. Belges, 79, 37 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 607–608, May, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bochkor, S.A., Lapuka, L.F., Kurmaeva, E.S. et al. Ring inversion in 5,5-disubstituted 1,3-dioxanes. Chem Heterocycl Compd 23, 500–502 (1987). https://doi.org/10.1007/BF00476374

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00476374

Keywords

Navigation