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Study of some nitrogen compounds of 2,2′-dithienyl

III. Nitration of 5-formyl-2,2′-dithienyl

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

5-Formyl-5′-nitro-2,2′-dithienyl and 5-formyl-3′-nitro-2,2t'-dithienyl were obtained by nitration of 5-formyl-2,2t'-dithienyl with copper nitrate in acetic anhydride. The structures of the nitroaldehydes were established by their oxidation to the corresponding nitro acids of the 2,2′-dithienyl series, the decarboxylation of which yielded 5-nitro- and 3-nitr o-2,2′ -dithienyls.

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Literature cited

  1. A. E. Lipkin, Zh. Obshch. Khim., 33, 2274 (1963).

    Google Scholar 

  2. A. E. Lipkin, Zh. Obshch. Khim., 33, 196 (1963).

    Google Scholar 

  3. E. Lescot, Ng. Ph. Buu-Hoi, and N. D. Xuong, J. Chem. Soc., 3234 (1959).

  4. N. I. Putokhin, Sbornik Nauchn. Trudov Kuibyshevsk. Industr. Instit., 5, 271 (1955).

    Google Scholar 

  5. J. Volhard, Ann., 261, 380 (1891).

    Google Scholar 

  6. W. Steinkopf and W. Köhler, Ann., 522. 17 (1936).

    Google Scholar 

  7. C. Carpanelli and G. Leandri, Ann. Chem., 51, 181 (1961).

    Google Scholar 

  8. G. Baharach, J. Am. Chem. Soc., 44, 1522 (1922).

    Google Scholar 

  9. G. Baharach, Rec. Trav. Chim., 50, 732 (1931); 52, 413 (1933).

    Google Scholar 

  10. G. Baharach, Ber., 64, 2136 (1931).

    Google Scholar 

  11. J. B. Menke, Rec. Trav. Chim., 44, 141, 269 (1925).

    Google Scholar 

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See [1] for communication II.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 918–919, July, 1971.

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Vakhreeva, K.I., Lipkin, A.E. Study of some nitrogen compounds of 2,2′-dithienyl. Chem Heterocycl Compd 7, 857–858 (1971). https://doi.org/10.1007/BF00475710

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  • DOI: https://doi.org/10.1007/BF00475710

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