Abstract
5-Formyl-5′-nitro-2,2′-dithienyl and 5-formyl-3′-nitro-2,2t'-dithienyl were obtained by nitration of 5-formyl-2,2t'-dithienyl with copper nitrate in acetic anhydride. The structures of the nitroaldehydes were established by their oxidation to the corresponding nitro acids of the 2,2′-dithienyl series, the decarboxylation of which yielded 5-nitro- and 3-nitr o-2,2′ -dithienyls.
Similar content being viewed by others
Literature cited
A. E. Lipkin, Zh. Obshch. Khim., 33, 2274 (1963).
A. E. Lipkin, Zh. Obshch. Khim., 33, 196 (1963).
E. Lescot, Ng. Ph. Buu-Hoi, and N. D. Xuong, J. Chem. Soc., 3234 (1959).
N. I. Putokhin, Sbornik Nauchn. Trudov Kuibyshevsk. Industr. Instit., 5, 271 (1955).
J. Volhard, Ann., 261, 380 (1891).
W. Steinkopf and W. Köhler, Ann., 522. 17 (1936).
C. Carpanelli and G. Leandri, Ann. Chem., 51, 181 (1961).
G. Baharach, J. Am. Chem. Soc., 44, 1522 (1922).
G. Baharach, Rec. Trav. Chim., 50, 732 (1931); 52, 413 (1933).
G. Baharach, Ber., 64, 2136 (1931).
J. B. Menke, Rec. Trav. Chim., 44, 141, 269 (1925).
Author information
Authors and Affiliations
Additional information
See [1] for communication II.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 918–919, July, 1971.