Abstract
Fresh snowfall was collected on the surface of 8 lakes across a 350 km west-east transect from northeastern New York state to the coast of Maine after a single storm. In addition, every snowfall event during the winter of 1993 was collected on a single lake near the center of the transect. Across the transect, midwestern sources appear to dominate Pb and Cd concentrations, while Sb appears to be derived from midwestern sources as well as local and/or industrial East Coast sources. In all samples, the highest Na, Cl and Mg concentrations reflect a marine influence, but at some transect sites roadspray aerosol appears to contribute to Na and Cl concentrations. The regional pattern of Ca, K, Mn and Sr concentrations and Mn/Sr ratios indicate that woodsmoke may be an important winter source of these elements at some sites. In all samples, H+ is strongly correlated with NO3 − (R2 = 0.97) and mean NO3 −/SO4 2− molar ratios of 6.4 for transect samples, and 4.7 for temporal samples, are higher than mean NO3 −/SO4 2− reported for other precipitation studies in the same region. The contribution of NO3 − to the snowpack greatly exceeds that of SO4 2−, and may be a major source of acidity in aquatic ecosystems during snowmelt.
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Aber, J., Nadelhoffer, K. J., Steudler, P. and Melillo, J. M.: 1989, Bioscience 39, 378.
Andersson, R., Lofvendahl, R. and Aberg, G.: 1990, Atmospheric Environ. 24A, 2601.
April, R., Newton, R. and Coles, L. T.: 1986, Geol. Soc. of Am. Bull. 97, 1232.
Cadle, S. H., Dasch, J. M. and Mulawa, P. A.: 1985, Atmospheric Environ. 19, 1819.
Dasch, J. M. and Cadle, S. H.: 1986, Water, Air, and Soil Pollut. 29, 297.
Daum, P. H., Kelly, T. J., Tanner, R. L., Tang, X., Anlauf, K., Bottenheim, J., Brice, K. A. and Wiebe, H. A.: 1989, Atmospheric Environ. 23, 161.
De Walle, D. R., Swistock, B. R., Sayre, R. G. and Sharpe, W. E.: 1991, J. Environ. Qual. 20, 486.
Driscoll, C. T. and Van Dreason, R.: 1993, Water, Air, and Soil Pollut. 67, 319.
Erel, Y., Morgan, J. J. and Patterson, C. C.: 1991, Geochim. Cosmochim. Acta 55, 707.
Faust, B. C., Anatasio, C., Allen, J. M. and Arakaki, T.: 1993, Science 260, 73.
Galloway, J. N., Thornton, J. D., Norton, S. A., Volchok, H. L. and McLean, R. A.: 1982, Atmospheric Environ. 16, 1677.
Heaton, R. W., Rahn, K. A. and Lowenthal, D. H.: 1990, Atmospheric Environ. 24A, 147.
Heaton, R. W., Rahn, K. A. and Lowenthal, D. H.: 1992, Atmospheric Environ. 26A, 1529.
Hedin, L. O., Granat, L., Likens, G. E., Buishand, T. A., Galloway, G. N., Butler, T. J. and Rodhe, H.: 1994, Nature 367, 351.
Hedin, L. O., Granat, L., Likens, G. E. and Rodhe, H.: 1990, Tellus 42B, 454.
Heintzenberg, J. and Rummukainen, M.: 1993, J. Glaciology 39, 239.
Hopper, J. F. and Barrie, L. A.: 1988, Tellus 40B, 446.
Husain, L. and Dutkiewicz, V. A.: 1990, Atmospheric Environ. 24A, 1175.
Isaac, G. A. and Daum, P. H..: 1987, Atmospheric Environ. 21, 1587.
Likens, G. E. and Bormann, F. H.: 1970, Chemical Analysis of Plant Tissues from the Hubbard Brook Ecosystem in New Hampshire, Yale University, New Haven, pp. 12–13.
Likens, G. E., Bormann, F. H., Pierce, R. S., Eaton, J. S. and Johnson, N. M.: 1977, Biogeochemistry of a Forested Ecosystem, Springer-Verlag, New York, p. 44.
McClenahen, J. R. and Vimmerstedt, J. P.: 1993, J. Environ. Qual. 22, 23.
Miller, E. K., Blum, J. D. and Friedland, A. J.: 1993a, Nature 362, 438.
Miller, E. K., Panek, J. A., Friedland, A. J., Kadlecek, J. and Mohnen, V. A.: 1993b, Tellus 45B, 209.
Miller, E. K.: 1994, Doctoral Thesis, Dartmouth College.
Mohnen., V. A. and Kadlecek, J. A.: 1989, Tellus 41B, 79.
Möller, D.: 1990, Tellus 41B, 254.
Munn, R. E., Likens, G. E., Weisman, B., Hornbeck, J. W., Martin, C. W. and Bormann, F. H.: 1984, Atmospheric Environ. 18, 2775.
Murdoch, P. S. and Stoddard, J. L.: 1993, Water, Air, and Soil Pollut. 67, 367.
National Research Council: 1980, Trace-Element Geochemistry of Coal Resource Development Related to Environmental Health and Quality, National Academy Press, Washington, D.C., p. 82.
National Oceanic and Atmospheric Administration (NOAA): 1993, Daily Weather Maps, U.S. Government Printing Office, Washington, D.C.
Norton, G. A., Malaby, K. L. and DeKalb, E. L.: 1988, Environ. Sci. Technol. 22, 1279.
Parekh, P. P. and Husain, L.: 1987, Atmospheric Environ. 21, 1707.
Rahn, K. A. and Lowenthal, D. H.: 1984, Science 223, 132.
Richardson, S. M. and McSween, H. Y.: 1989, Geochemistry: Pathways and Processes, Prentice-Hall, Englewood Cliffs, New Jersey, p. 84.
Schaefer, D. A. and Driscoll, C. T.: 1993, Water, Air, and Soil Pollut. 67, 345.
Schwartz, S. E.: 1989, Science 243, 753.
Shanley, J. B.: 1994, J. Environ. Qual. 23, 977.
Shepard, J. P., Mitchell, M. J. and Scott, T. J.: 1990, Canadian Journal of Forest Research 20, 818.
Stoddard, J. L. and Kellogg, J. H.: 1993, Water, Air, and Soil Pollut. 67, 301.
Summers, P. W. and Barrie, L. A.: 1986, Water, Air, and Soil Pollut. 30, 275.
Summers, P. W. and Fricke, W.: 1989, Tellus 41B, 286.
Taylor, D. R., Tompkins, M. A., Kirton, S. E., Mauney, T. and Natusch, F. S.: 1982, Environ. Sci. Technol. 16, 148.
Wagner, G. H. and Steele, K. F.: 1989, Tellus 41B, 444.
Waring, R. H. and Schlesinger, W. H.: 1985, Forest Ecosystems: Concepts and Management, Academic Press, London, p. 151.
Whittaker, R. H., Bormann, F. H., Likens, G. E. and Siccama, T. G.: 1974, Ecological Monographs 44, 233.
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Baisden, W.T., Bluh, J.D., Miller, E.K. et al. Elemental concentrations in fresh snowfall across a regional transect in the northeastern U.S.: Apparent sources and contribution to acidity. Water Air Soil Pollut 84, 269–286 (1995). https://doi.org/10.1007/BF00475344
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DOI: https://doi.org/10.1007/BF00475344