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Bestimmung von stickstoffhaltigen Pesticiden durch Hochleistungsflüssigkeits-Chromatographie mit Diodenarray-Detektion

Determination of nitrogen-containing pesticides by HPLC with diode-array detection

  • Original Papers
  • Pesticide Residue Analyses
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Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Summary

An analytical procedure is described, which allows the simultaneous determination of 22 pesticides in drinking, ground and surface water.

In case of higher-loaded waters the sample has to be submitted to a clean-up step after CH2Cl2 extraction. The following HPLC is carried out on a Hypersil-column, 3 μm ODS by gradient elution using CH3CN-H2O (phosphate buffer, pH 7) as eluent. The detection of the single components is achieved by a diode-array detector according to their absorption maximal at 220, 230, 245 nm, the verification being supported by comparison of the absorption spectra. As the factor of enrichment is about 1000 a detection limit of 50 μg/l for any pesticide can be obtained. The recovery is higher than 90%.

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Literatur

  1. Bundesgesetzblatt 1986, Teil 1, S 760–773

  2. Steinheimer TR, Brooks MG (1984) Int J Environ Anal Chem 17:97–111

    Article  CAS  Google Scholar 

  3. Oehmichen U, Haberer K (1986) Gewässerschutz Wasser Abwasser 88:216–227

    CAS  Google Scholar 

  4. Martisova E, Krupcik J (1981) J Chromatogr 205:464–469

    Article  Google Scholar 

  5. Lekova K, Kardjieva L, Hlebarova N, Natan V (1981) J Chromatogr 212:85–91

    Article  CAS  Google Scholar 

  6. Xu Y, Lorenz W, Pfister G, Bahadir M, Korte F (1986) Fresenius Z Anal Chem 325:377–380

    Article  CAS  Google Scholar 

  7. Vermeulen NMJ, Apostolides Z, Potgieter DIJ (1982) J Chromatogr 240:247–253

    Article  CAS  Google Scholar 

  8. Dufek P, Pacakova V, Tesarova E (1980) J Chromatogr 191:115–120

    Article  CAS  Google Scholar 

  9. Subach J (1981) Chromatographia 14:371–373

    Article  CAS  Google Scholar 

  10. Van Dyk LP, Lotter L, De Beer PR, Reyskens DHJP, Viljoen AJ, Prinsloo SM (1985) Analyst 110:1053–1058

    Article  Google Scholar 

  11. Grubert G, Reupert R, in Vorbereitung

  12. De Kok A, Vos YJ, Van Garderen C, De Jong T, Van Opstal M, Frei RW, Geerdink B, Brinkmann UAT (1984) J Chromatogr 288:71–89

    Article  Google Scholar 

  13. Ogiermann L (1985) Fresenius Z Anal Chem 320:365–368

    Article  Google Scholar 

  14. Grob Jr K (1981) J Chromatogr 208:217–229

    Article  CAS  Google Scholar 

  15. De Kok A, Roorda IM, Frei RW, Brinkmann UAT (1981) Chromatographia 14:579–586

    Article  Google Scholar 

  16. Stöber I, Reupert R (1978) Vom Wasser 51:273–283

    Google Scholar 

  17. Maris FA, Geerdink RB, Van Delft R, Brinkmann UAT (1985) Bull Environ Contam Toxicol 35:711–715

    Article  CAS  Google Scholar 

  18. Walters SM, Westerby BC, Gilvydis DM (1984) J Chromatogr 317:533–544

    Article  CAS  Google Scholar 

  19. Chiavari G, Bergamini C (1985) J Chromatogr 346:369–375

    Article  CAS  Google Scholar 

  20. Nielen MWF, Koomen G, Frei RW, Brinkmann UAT (1985) J Liquid Chromatogr 8:315–332

    Article  CAS  Google Scholar 

  21. Deutsche Einheitsverfahren zur Wasser-Abwasser- und Schlammuntersuchung (1986) DIN 38402 Teil 51:1–16

    Google Scholar 

Download references

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Authors and Affiliations

  1. Landesamt für Wasser und Abfall NRW, Auf dem Draap 25, D-4000, Düsseldorf 1, Bundesrepublik Deutschland

    R. Reupert & E. Plöger

Authors
  1. R. Reupert
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  2. E. Plöger
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Reupert, R., Plöger, E. Bestimmung von stickstoffhaltigen Pesticiden durch Hochleistungsflüssigkeits-Chromatographie mit Diodenarray-Detektion. Z. Anal. Chem. 331, 503–509 (1988). https://doi.org/10.1007/BF00467039

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  • DOI: https://doi.org/10.1007/BF00467039

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