Abstract
Rb-Sr whole rock isochrons for the Monchique and Mt. Kenya complexes, together with a series of 87Sr/86Sr ratios for 7 other alkaline suites, reveal limited initial ratio variation within the oceanic basalt range. Such variation is ubiquitous in alkaline suites and renders interpretation of their Sr behaviour highly subjective; this has led to major interpretive inconsistencies between previous studies. A consideration of wall-rock reaction, responsible for a few anomalous ratios in the present data, is believed to reconcile many of these inconsistencies; the subjective element can also be minimised by using the total of available data as a basis for comparative interpretation instead of interpreting individual sets of data absolutely. This approach shows available data to be remarkably unified, implying less diversified petrogenesis than is apparent from the sum of interpretations for individual alkaline complexes. In particular, Sr data lend little support to various models invoking crustal participation in the origin of nephelinites, nepheline syenites, ijolites or peralkaline oversaturated rocks, but suggest that these generally are straight-forward derivatives of mantle liquids. The consanguinity of most alkaline complexes is also confirmed.
Similar content being viewed by others
References
Baker, B.H.: The alkaline igneous complex of Jombo Hill. Geol. Surv. Kenya Report 24, 32–48 (1953)
Baker, B.H.: Geology of the Mt. Kenya area. Geol. Surv. Kenya Report 79 (1967)
Baker, B.H., Williams, L.A.J., Miller, J.A., Fitch, F.J.: Kenya Rift volcanics-geochronology. Tectonophysics 11, 191–215 (1971)
Barker, D.S., Long, L.E.: Felspathoidal syenite in a quartz diabase sill. New Jersey. J. Petrol. 10, 202–220 (1969)
Bell, K., Dawson, J.B., Farquhar, R.M.: Sr isotopic studies of alkali rocks: the active carbonatite volcano Ol Doinyo Lengai. Bull. Geol. Soc. Am. 84, 1019–1030 (1973)
Bell, K., Powell, J.L.: Sr isotopic studies of alkalic rocks: the K-rich lavas of the Birunga and Toro-Ankole regions, Equatorial Africa. J. Petrol. 10, 536–572 (1969)
Bell, K., Powell, J.L.: Sr isotopic studies of alkalic rocks: the alkalic complexes of East Uganda. Bull. Geol. Soc. Am. 81, 3481–3490 (1970)
Bell, K., Powell, J.L.: Isotopic composition of strontium in alkaline rocks. In: Sorensen (1974), qv., pp. 412–421
Bishop, W.W., Miller, J.A., Fitch, F.J.: New Potassium-argon age determinations relevant to the Miocene fossil mammal sequence in E. Africa. Am. J. Sci. 267, 669–699 (1969)
Clarke, G.S., Subbarao, K.V.: Rb-Sr isotopic age of the Kunavaram series, a group of alkaline rocks from India. Can. J. Earth Sci. 8, no. 12, 1597–1602 (1971)
Czygan, W.: Petrographie und Alkali-Verteilung im Foyait der Serra de Monchique, Süd-Portugal. Neues Jahrb. Mineral. Abhandl. 111, 32–73 (1969)
Dawson, J.B.: Ol Doinyo Lengai — an active volcano with sodium carbonatite lava flows. In: Carbonatites, O.F. Tuttle and J. Gittins, Eds., pp. 155–168. New York: Wiley 1966
De Sousa, F.P.: La Serra de Monchique. Bull. Geol. Soc. France, 4 ser. 26, 321–350 (1926)
Fairbairn, H.W., Faure, G., Pinson, W., Hurley, P.M., Powell, J.L.: Initial ratio of 87Sr/86Sr whole-rock age and discordant biotite in the Monteregian igneous province. J. Geophys. Res. 68, 6515–6522 (1963)
Faure, G., Powell, J.L.: Strontium isotope geology. Berlin-Heidelberg-New York: Springer 1972
Ferguson, J., Currie, K.L.: Evidence of liquid immiscibility in alkaline ultrabasic dykes at Callender Bay, Ontario. J. Petrol. 12, 561–585 (1971)
Griffin, W.L.: Lherzolite nodules from the Fen Alkaline Complex. Contrib. Mineral. Petrol. 38, 135–146 (1973)
Hamilton, E.I.: The isotopic composition of strontium applied to problems of the origins of alkalic rocks. In: Radiometric dating for geologists, E.I. Hamilton and R.M. Farquhar, Eds., pp. 437–463. New York: Wiley 1968
Heier, K.S., Compston, W.: Rb-Sr isotopic studies of the plutonic rocks of the Oslo region. Lithos 2, 133–148 (1969)
Heinrich, E.W.: The geology of carbonatites. Chicago: Rand McNally 1966
Higazy, R.A.: Trace elements in volcanic ultrabasic potassic rocks of S.W. Uganda and adjoining parts of the Belgian Congo. Bull. Geol. Soc. Am. 65, 39–70 (1954)
Hoefs, J., Wedepohl, K.H.: Strontium isotopic studies on young volcanic rocks from Germany and Italy. Contrib. Mineral. Petrol. 19, 328–388 (1968)
Holmes, A.: Petrogenesis of katungite and its associates. Am. Mineralogist. 35, 772–792 (1950)
Johnson, R.L.: The geology of the Dorowa and Shawa carbonatite complexes. Trans. Geol. Soc. S. Africa 64, 101–147 (1961)
King, B.C., LeBas, M.J., Sutherland, D.S.: The history of the alkaline volcanoes and intrusive complexes of E. Uganda and W. Kenya. Quart. J. Geol. Soc. 128, 173–205 (1972)
King, B.C., Sutherland, D.S.: Alkaline rocks of Eastern and Southern Africa. Sci. Progr. (London) 48, 298–318, 504–523, 709–720 (1960)
Klerx, J., Deutsch, S., De Paepe, P.: Rb-Sr contents and Sr isotopic composition of strongly alkalic rocks from the Cape Verde Is. Contrib. Mineral. Petrol. 45, 107–118 (1974)
LeBas, M.J.: The production of nepheline syenites in association with ijolitic intrusions. Paper delivered to 8th African Colloquium, Leeds, January 1975
Macdonald, R.: The role of fractional crystallisation in the formation of alkaline rocks. In: Sorensen (1974), qv., pp. 442–458
McGall, G.J.H.: Geology of the Gwasi area. Geol. Surv. Kenya Report 45, (1958)
McKyntyre, G.A., Brooks, C., Compston, W., Turek, A.: The statistical assessment of Rb-Sr isochrons. J. Geophys. Res. 71, 5459–5468 (1966)
Mendes, F.: Strontium ages and ratios of some Portuguese rocks (in French). Bol. Mus. Lab. Min. Geol. Fac. Ciências Lisboa 11, pt. 1, 155 pp (1971)
Mitchell, R.H., Crocket, J.H.: Isotopic composition of Strontium in rocks of the Fen Alkaline Complex. J. Petrol. 13, 83–97 (1972)
Mitchell, J.G., Macintyre, R.A., Pringle, I.R.: K-Ar and Rb-Sr isotopic age studies on the Wolf Rock nosean phonolite, Cornwall. Geol. Mag. 112, 55–61 (1975)
Oates, F.: Collection of Tertiary lavas from the Northern province, Tanganyika. Geol. Surv. Report for 1933 (1934)
O'Nions, R.K., Pankhurst, R.J.: Petrogenetic significance of Isotope & Trace Element variations in volcanic rocks. J. Petrol. 15, 603–634 (1974)
Pankhurst, R.J.: Sr isotopic studies related to petrogenesis in the Caledonian Basic Igneous Province of N.E. Scotland. J. Petrol. 10, 115–143 (1969)
Pecora, W.T.: Carbonatite problem in the Bearpaw Mountains. In: Petrological Studies. Geol. Surv. Am., Buddington Volume, 83–104 (1962)
Peterman, Z.E., Hedge, C.E.: Related Sr isotopic and chemical variation in oceanic basalts. Bull. Geol. Soc. Am. 82, 493–499 (1971)
Philpotts, R.A.: The Monteregian Province. In: The alkaline rocks, H. Sorensen, Ed., pp. 293–310. New York: Wiley & Sons 1974
Powell, J.L., Bell, K.: Strontium isotopic studies of alkalic rocks — localities from Australia, Spain and the Western U.S.A. Contrib. Mineral. Petrol. 27, 1–10 (1970)
Powell, J.L., Hurley, P.M., Fairbairn, H.W.: The Strontium isotopic composition and origin of carbonatites. In: Carbonatites, O.F. Tuttle and J. Gittins, Eds., pp. 365–378. New York: Wiley & Sons 1966
Price, R.C., Compston, E.: Geochemistry of the Dunedin volcano: Sr isotopic chemistry. Contrib. Mineral. Petrol. 42, 55–61 (1973)
Rock, N.M.S.: The role of CO2 in alkali rock genesis. Geol. Mag. (in press, 1976a)
Rock, N.M.S.: Petrogenetic significance of some new xenolithic alkaline rocks from East Africa. Mineral. Mag. (in press, 1976b)
Rock, N.M.S.: Fenitisation around the Monchique alkaline complex, Portugal. Lithos (in press, 1976c)
Rubie, D.C.: The Kisingiri nephelinite volcano. Unpublished Ph.D. thesis, University of Leicester, (1971)
Searle, D.L.: Geology of the area N.W. of Kitale township. Geol. Surv. Kenya Report 19, (1952)
Sorensen, H.: The alkaline rocks. New York: Wiley & Sons 1974
Sturt, B.A., Ramsay, D.M.: The alkaline complex of the Breivikbotn area, Soroy, Norway. Norges Geol. Unders., No. 131, 1–142 (1965)
Taylor, H.P., Forester, R.W.: Low-O18 igneous rocks from the intrusive complexes of Skye, Mull and Ardnamurchan. J. Petrol. 12, 465–497 (1971)
Tilley, C.E.: Problems of alkali rock genesis. Quart. J. Geol. Soc. 113, 323–360 (1958)
Van Breeman, O., Upton, B.C.J.: Age of some Gardar intrusive complexes, S. Greenland. Bull. Geol. Soc. Am. 83, 3381–3390 (1972)
Van Groos, A.F.K.: The effect of high \({\text{P}}_{{\text{CO}}_{\text{2}} }\) on alkali rocks and its bearing on the genesis of alkali ultrabasic rocks and carbonatites. Am. J. Sci. 275, 163–185 (1975)
Wimmenauer, W.: The eruptive rocks and carbonatites of the Kaiserstuhl, Germany. In: Carbonatites, O.F. Tuttle and J. Gittins, Eds., pp. 183–204. New York: Wiley & Sons 1966
Wyllie, P.J.: Limestone assimilation. In: Sorensen (1974), qv., pp. 459–472
Wyllie, P.J., Tuttle, O.F.: Hydrothermal melting of shales. Geol. Mag. 98, 56–66 (1961)
Zartman, R.E., Brock, M.R., Heyl, A.V., Thomas, H.H.: K-Ar and Rb-Sr ages of some alkalic intrusive rocks from Central and Eastern United States. Am. J. Sci. 265, 848–870 (1967)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rock, N.M.S. The comparative strontium isotopic composition of alkaline rocks: New data from Southern Portugal and East Africa. Contr. Mineral. and Petrol. 56, 205–228 (1976). https://doi.org/10.1007/BF00399605
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00399605