Skip to main content
Log in

Petrochemical variations among mildly peralkaline (comendite) obsidians from the oceans and continents

  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

Eleven new analyses and modes of comendite obsidians are presented, and compared with all available data on similar rocks. Most specimens are aphyric or contain only sparse phenocrysts, most commonly alkali feldspar. The oxides SiO2, Al2O3, Na2O and K2O total over ninety percent by weight in all analyses. Iron, as FeO, is the only other constituent rising above one percent by weight. When the analyses are projected into the system Na2O-K2O-Al2O3-SiO2, oceanic and continental samples group differently. Oceanic specimens have a compositional spread ranging from trachytic to the quartz-feldspar cotectic zone, consistent with derivation through a trachyte magma stem. Continental comendites show a strong correlation with the experimentally determined quartz-feldspar minima along a path of increasing peralkalinity. These differences presumably reflect the contrasting environments of magma generation, and suggest an origin by partial melting within the continental crust for the continental comendite obsidians.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Bailey, D. K.: Volatile flux, heat-focusing and the generation of magma. Geol. J. Special. Issue 2, 177–186 (1970).

    Google Scholar 

  • —, Macdonald, R.: Alkali-feldspar fractionation trends and the derivation of peralkaline liquids. Am. J. Sci. 267, 242–248 (1969).

    Google Scholar 

  • —, Schairer, J. F.: Feldspar-liquid equilibria in peralkaline liquids — the orthoclase effect. Am. J. Sci. 262, 1198–1206 (1964).

    Google Scholar 

  • — —: The system Na2O-Al2O3-Fe2O3-SiO2 at 1 atmosphere, and the petrogenesis of alkaline rocks. J. Petrol. 7, 114–170 (1966).

    Google Scholar 

  • Baker, P. E.: Preliminary account of recent geological investigations on Easter Island. Geol. Mag. 104, 116–122 (1967).

    Google Scholar 

  • Bowen, N. L.: Recent high-temperature research on silicates and its significance in igneous geology. Am. J. Sci. 33, 1–21 (1937).

    Google Scholar 

  • —: Phase equilibria bearing on the origin and differentiation of alkaline rocks. Am. J. Sci., Daly Vol. 243-A, 75–89 (1945).

    Google Scholar 

  • Broch, O. A.: Lavas of Bouvet Island. In: Two contributions to Antarctic petrography. Scient. Results Norw. Antarct. Exped., No. 25, 3–26 (1946).

    Google Scholar 

  • Carmichael, I. S. E.: Pantelleritic liquids and their phenocrysts. Mineral. Mag. 33, 86–113 (1962).

    Google Scholar 

  • —: The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates. Contr. Mineral. and Petrol. 14, 36–64 (1967).

    Google Scholar 

  • —, MacKenzie, W. S.: Feldspar-liquid equilibria in pantellerites an experimental study. Am. J. Sci. 261, 382–396 (1963).

    Google Scholar 

  • Chayes, F., Zies, E. G.: Sanidine phenocrysts in some peralkaline volcanic rocks. Ann. Rept. Geophys. Lab. Yearbook 61, 112–118 (1962).

    Google Scholar 

  • Coombs, D. S.: Trends and affinities of basaltic magmas and pyroxenes as illustrated on the diopside-olivine-silica diagram. Mineralog. Soc. Am. Spec. Papers 1, 227–250 (1963).

    Google Scholar 

  • Edwards, A. B.: Tertiary lavas from the Kerguelen archipelago. B.A.N.Z. Antarctic Res. Exped. (1929–1931) 2, 69–100 (1938).

    Google Scholar 

  • Lacroix, A.: Les rhyolites et les trachytes hyperalcalins quartzifères á propos de ceux de la Corée. Compt. Rend. 185, 1410–1415 (1927).

    Google Scholar 

  • —: Volcanisme et lithologie. Mission au Tibesti (1930–1931) dirigée par M. Dalloni. Mém. Acad. Sci. (Paris) 61, 169-(1934).

    Google Scholar 

  • —: Composition chimique des laves de l'Ile de Pâques. Compt. Rend. 202, 601–605 (1936).

    Google Scholar 

  • Macdonald, R., Bailey, D. K.: The chemistry of peralkaline oversaturated obsidians. U. S. Geol. Survey, Profess. Papers 440-N, part 1 (in press).

  • Merlin, O. H.: Le vulcaniti acide dell'Africa Orientale. Centro Studi Pet. Geol. dell Cons. Kaz. Richerche, Univ. Padova (1953).

  • Morgan, W. R.: A note on the petrology of some lava types from East New Guinea. J. Geol. Soc. Aust. 13(2), 583–591 (1966).

    Google Scholar 

  • Noble, D. C.: Gold Flat Member of the Thirsty Canyon Tuff — a pantellerite ash-flow sheet in southern Nevada. U.S. Geol. Survey, Profess. Papers 525-B, 85–90 (1965).

    Google Scholar 

  • —: Systematic variation of major elements in comendite and pantellerite glasses. Earth and Planet. Sci. Letters 4, 167–172 (1968).

    Article  Google Scholar 

  • —, Haffty, J.: Minor-element and revised major-element contents of some Mediterranean pantellerites and comendites. J. Petrol. 10, 502–509 (1969).

    Google Scholar 

  • - Sarjent, K. A., Mehnert, H. H., Ekren, E. B., Byers, F. M., Jr.: Silent Canyon Volcanic Centre. In: Eckel, E. B. (ed.), Nevada Test Site. Geol. Soc. Am. Mem. 110, 65–75 (1968).

  • Schairer, J. F., Bowen, N. L.: The system K2O-Al2O3-SiO2. Am. J. Sci. 253, 681–746 (1955).

    Google Scholar 

  • —: The system Na2O-Al2O3-SiO2. Am. J. Sci. 254, 129–195 (1956).

    Google Scholar 

  • Tuttle, O. F., Bowen, N. L.: Origin of granite in the light of experimental studies in the system NaAlSi3O8-KAlSi3O8-SiO2-H2O. Geol. Soc. Am. Mem. 74, 1–153 (1958).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bailey, D.K., Macdonald, R. Petrochemical variations among mildly peralkaline (comendite) obsidians from the oceans and continents. Contr. Mineral. and Petrol. 28, 340–351 (1970). https://doi.org/10.1007/BF00388955

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00388955

Keywords

Navigation