Abstract
Riebeckite-arfvedsonite amphiboles occur in very low-grade metamorphosed doleritic sills at various localities within the Iberian Pyrite Belt. The alkali-amphiboles grew during sub-solidus hydrothermal ‘spilitization’ of basalt associated with submarine massive sulphide ore formation. The riebeckite-arfvedsonite is only very rarely preserved, being converted to albite-chlorite during regional metamorphism. In the South Portuguese zone Hercynian regional metamorphic grade increases in a northward direction from zeolite facies south of the Pyrite Belt through prehnite-pumpellyite facies to the greenschist facies in its northernmost zone. Compositional and mineralogical data indicate a geothermal gradient in the order of 40–50 °C/km.
Volcanism in the Pyrite Belt is essentially representative of a bimodal association of twoleiitic to alkalic basalt and dacite/rhyolite. Geochemical data for the Pyrite Belt mafic meta-volcanics contrast with available data for subduction related volcanic suites in orogenic belts but exhibit similarities with the basaltic members of basalt-rhyolite associations found in areas of extensional tectonics. It is proposed that the Iberian Pyrite Belt volcanism represents magmatic activity in an intra-continental basin undergoing rifting during the late Devonian and lower Carboniferous times.
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References
Anderson, T.A.: Carboniferous subduction in the Harz Mountains, Germany. Geol. Soc. Am. Bull. 86, 77–82 (1975)
Andrews, A.J.: Low temperature fluid alteration of oceanic layer 2 basalts, DSDP leg. 37. Can. J. Earth Sci. 14 (4), 911–926 (1977)
Andrews, A.J., Fyfe, W.S.: Metamorphism and massive sulphide generation in oceanic crust. Geoscience Canada 3 (2), 84–94 (1976)
Arculus, R.J., Johnson, R.W.: Criticism to generalised models for the magmatic evolution of arc-trench systems. Earth Planet. Sci. Lett. 39, 118–126 (1978)
Badham, J.P.N., Halls, C.: Microplate tectonics, oblique collisions and evolution of the Hercynian orogenic systems. Geology 3, 373–376 (1975)
Bard, J.-P.: Le Metamorphism regional progressif des Sierras d'Aracena en Andalousie Occidentale (Espagne); sa place dans le segment Hercynian Sud-Iberique. Thesis, Fac. Sci. Montpellier 397 p. (1969)
Bard, J-P.: Sur l'alternance des zones metamorphiques et granitiques dans le segment Hercynian Sud-Iberique; comparaison de la variabilite des caracteres geotectoniques de ces zones avec les orogens ‘orthotectoniques’. Bol. Geol. Min. Espana, T. LXXXII-III-IV 324–345 (1971)
Bard, J-P., Capdevilla, R., Matte, P.: La structure de la Chaine Hercynienne de la Meseta Iberique. Histoire Structurale du Golfe de Gascogne. Editions Technip, Paris, pp. 1.41 to 1.468 (1971)
Bard, J-P.: Capdevilla, R., Matte, P., Ribeiro, A.: Geotectonic model for the Iberiam Variscan orogen. Nature Phys. Sci. 241, 50–52, (1973)
Bishop, D.G.: Progressive metamorphism from prehnite-pumpellyite to greenschist facies in the Dansey Pass area, Otago, New Zealand. Geol. Soc. Am. Bull. 83, 3177–3198 (1972)
Black, P.M.: Co-existing glaucophane and riebeckite-arfvedsonite from New Caledonia. Am. Mineralogist 55, 1060–1064 (1970)
Boogard, M. Van Den: Conodonts of upper Devonian and Loer Carboniferous age from Southern Portugal. Geol. Mijnb. 42, 248–259 (1963)
Boogard, M. Van Den: Geology of the Pomarao region (Southern Portugal). Univ. Amsterdam, Rotterdam Delko, 113p. (1967)
Boogard, M. Van Den, Schermerhorn, L.J.G.: Conodont faunas from Portugal and Southwestern Spain; part 2/3 — A Famennian conodont fauna at Cabezas del Pasto; part 3 — Carboniferous conodont at Sotiel Coronada. Scripta Geol. 28, 1–43 (1975)
Borg, I.Y.: Optical properties and cell parameters in the glauco-phane-riebeckite series. Contrib. Mineral. Petrol. 15, 67–92 (1967)
Brown, E.H.: Comparison of the mineralogy and phase relations of blueschists from the Northern Cascades, Washington, and the greenschists from Otago, New Zealand. Geol. Soc. Am. Bull. 85, 333–344 (1974)
Brown, E.H.: The crossite content of Ca-amphibole as guide to pressure of metamorphism. J. Petrol. 18 (1) 58–72 (1977)
Burke, K., Sawkins, F.J.: Were the Rammeisberg, Meggen, Rio Tinto and related ore deposits formed in a Devonian rifting event? Econ. Geol. 73, 308 (1978)
Burret, C.F.: Plate tectonics and the Hercynian orogeny. Nature 239, 155–157 (1972)
Carvalho, D.: The metallogenetic consequences of plate tectonics and the upper Palaezoic evolution of Southern Portugal. Est. Not. Trab. Serv. Fom. Min. 20, 297–320 (1972)
Carvalho, D., Goinhas, J., Oliveira, V. Ribeiro, A.: Observações sobre a geologia do Sul de Portugal e consequencias metalogeneticas. Est. Not. Trab. Serv. Fom. Min. 20, (1–2), 153–199 (1971)
Coleman, R.G., Papike, J.J.: Alkali amphiboles from blueschists of Cazadero, California. J. Petrol. 9, 105–122 (1968)
Coombs, D.S.: Lower grade mineral facies in New Zealand. Internat. Geol. Cong., 21st, Copenhagen, Rep., pt. XIII, 339–351 (1960)
Coombs, D.S.: Present status of the zeolite facies. In: Molecular Sieve Zeolites (R.F. Gould, ed.). I. Am. Chem. Soc. Advances in Chemistry Ser. 101, 317–327 (1971)
Coombs, D.S., Horodyski, R.J., Naylor, R.S.: Occurrence of prehnite-pumpellyite facies metamorphism in Northern Maine. Am. J. Sci. 268, 142–156 (1970)
Coombs, D.S., Kawachi, Y., Houghton, B.F., Hyden, G., Pringle, I.J., Williams, J.G.: Andradite and andradite-grossular solid solutions in very low-grade regionally metamorphosed rocks in Southern New Zealand. Contrib. Mineral. Petrol. 63, 229–246 (1977)
Coombs, D.S., Nakamura, Y., Vuagnat, M.: Pumpellyite-actinolite facies schists of the Taveyanne Formation near Loeche, Valais, Switzerland. J. Petrol. 17, 440–471 (1976)
Deer, W.A., Howie, R.A., Zussman, J.: Rock Forming Minerals. Vol. 2. Chain Silicates. New York: John Wiley & Sons, Inc. 1963
Delaney, J.R., Muenow, D.W., Graham, D.G.: Abundance and distribution of water, carbon and sulfur in the glassy rims of submarine pillow basalts. Geochim. Cosmochim. Acta 42, 581–594 (1978)
Dewey, J.: Evolution of the Appalachian/Caledonian orogen. Nature 222, 124–129 (1969)
Dewey, J., Bird, J.M.: Mountain belts and the new global tectonics. J. Geophys. Res. 75, 2625–2647 (1970)
Dewey, J., Burke, K.C.A.: Tibetan Variscan and Precambrian basement reactivation: products of continental collision. J. Geol. 81, 683–692 (1973)
Dietrich, V., Vuagnat, M., Bertrand, J.: Alpine metamorphism of mafic rocks. Schweiz. Mineral. Petrog. Mitt. 54, 2/3, 291–332 (1974)
Ernst, W.G.: Synthesis, stability relations and occurrence of riebeckite and riebeckite-arfvedsonite solid solutions. J. Geol. 70, 679–736 (1962)
Floor, P.: Petrology of an aegirine-riebeckite gneiss-bearing part of the Hesperian Massif: the Galinero and surrounding areas, Vigo, Spain. Leidse Geol. Meded. 36, 1–204, (1966)
Floyd, P.A.: Geochemistry, origin and tectonic environment of the basic and acidic rocks of Cornubia, England. Proc. Geol. Assoc. 83, 385–404 (1972)
Floyd, P.A.: Geochemical variations in the greenstones of SW England. J. Petrol. 17, 522–545 (1976)
Floyd, P.A., Winchester, J.A.: Magma type and tectonic discriminiation using immobile elements. Earth Planet. Sci. Lett. 27, 211–218 (1975)
Frischmuth, E.: Sedimentation and Tektonik in der subvariszischen Vortiefe von Süd-Portugal. Muntessclare Forsch., Geol. Palaont. 4, Munster (1968)
Glassley, W.E.: A model for phase equilibria in the prehnite-pumpellyite facies. Contrib. Mineral. Petrol. 43, 317–332 (1974)
Hashimoto, M.: On the prehnite-pumpellyite metagreywacke facies. J. Geol. Soc. Japan 72, 253–265 (1966)
Hashimoto, M.: Glaucophanitic metamorphism of the Katsuyama District, Okayama Prefecture, Japan. Tokyo Univ. Fac. Sci. J. Sect. 2, 17, 99–162 (1968)
Hashimoto, M.: Reactions producing actinolite in basic metamorphic rocks. Lithos 5 (1), 19–32 (1972)
Hegelson, H.C.: A chemical and thermodynamic model of ore deposition in hydrothermal systems. Mineral. Soc. Am. Spec. Papers 3, 155–186 (1970)
Henley, R.W.: Arfvedsonite in basalt dykes, Buchans, Newfoundland. Am. Mineralogist 63, 413–414 (1978)
Herrmann, A.G., Potts, M.J., Knake, D.: Geochemistry of the rare earth elements in spilites from the oceanic and continental crust. Contrib. Mineral. Petrol. 44, 1–16 (1974)
Holdaway, M.J.: Thermal stability of Al-Fe epidote as a function of f o 2 and Fe content. Contrib. Mineral. Petrol. 37, 307–340 (1972)
Kawachi, Y.: Pumpellyite-actinolite and contiguous facies metamorphisim in part of upper Wakatipu District, South Island, New Zealand. New Zealand J. Geol. Geophys. 18, 401–441 (1975)
Krebs, W., Wachendorf, H.: Proterozoic-Palaeozoic geosynclinal and orogenic evolution of Central Europe. Geol. Soc. Am. Bull. 84, 2611–2630 (1973)
Kuniyoshi, S., Liou, J.G.: Contact metamorphism of the Karmutsen volcanics, Vancouver Island, British Columbia. J. Petrol. 17 (1), 73–99 (1976a)
Kuniyoshi, S., Liou, J.G.: Burial metamorphism of the Karmutsen volcanic rocks, Northeastern Vancouver Island, British Columbia. Am. J. Sci. 276, 1096–1119 (1976b)
Laurent, R.: The Hercynides of South Europe: a model. Int. Geol. Congr., 24th, Montreal 3, 363–370 (1972)
Lecolle, M., Roger, G.: Metamorphisme regional hercynien de ‘faible degree’ dans la province pyrito-cuprifere de Huelva (Espagne). Consequences petrologiques. Bull. Soc. Geol. France, (7), T. XVIII, (6), 1687–1698 (1976)
Liou, J.G.: P/T stabilities of laumontite, wairakite, lawsonite, and related minerals in the system CaAl2Si2O8-H2O-SiO2. J. Petrol. 12, 379–411 (1971)
Liou, J.G.: Synthesis and stability relations of epidote, Ca2Al2Fe-Si3(OH). J. Petrol. 14 (3), 381–413 (1973)
Liou, J.G., Kuniyoshi, S., Ito, K.: Experimental studies of the phase relations between greenschist and amphibolite in a basaltic system. Am. J. Sci. 274, 613–632 (1974)
Lister, C.R.B.: On the thermal balance of a mid-ocean ridge. Geophys. J. Roy Astron. Soc. 26, 515–535 (1972)
Lotze, F.: Zur Gliederung der Varisziden der Iberischen Meseta. Geotekt. Forsch. 6, 78–92 (1945)
Lyons, P.C.: The chemistry of riebeckites of Massachusets and Rhode Island. Mineral. Mag. 40, 473–479 (1976)
MacDonald, R.: Tectonic settings and magma associations. Bull. Volcanol. 38, 575–593 (1975)
Milton, C., Ingram, B., Breger, I.: Authigenic magnesioarfvedsonite from the Green River Formation, Duchesne County, Utah. Am. Mineralogist 59, 830–836 (1974)
Mitchel, A.H., Reading, H.G.: Continental margins, geo-synclines and ocean floor spreading. J. Geol. 77, 629–646 (1969)
Miyashiro, A.: The chemistry, optics, and genesis of the alkaliamphiboles. Tokyo Univ. Fac. Sci. J. Sect. 2, 11, 57–83 (1957)
Miyashiro, A.: Chemical composition of rocks in relation to metamorphic facies. Jap. J. Geol. Geogr. 38, 149–157 (1967)
Miyashiro, A.: Volcanic rocks series in island arcs and active continental margins. Am. J. Sci. 274, 321–355 (1974)
Moore, J.G.: Water content of basalt erupted on the ocean floor. Contrib. Mineral. Petrol. 28, 272–279 (1970)
Munhá, J.: Nota preliminar sobre o metamorfismo na Faixa Piritosa Portuguesa. Com. Serv. Geol. Portugal, T.LX, 151–161 (1976)
Nicholas, A.: Was the Hercynian orogenic belt of the Andean type? Nature 236, 221–223 (1972)
Nitsch, K.H.: Stabilitätsbeziehungen von prehnit- und pumpellyithaltigen paragenesen. Contrib. Mineral. Petrol. 30, 240–260 (1971)
Noble, D.C.: Some observations on the Cenozoic volcano-tectonic evolution of the Great Basin, Western United States. Earth Planet. Sci. Lett. 17, 142–150 (1972)
Onuki, H., Ernst, W.G.: Coexisting sodic amphiboles and sodic pyroxenes from blueschist facies metamorphic rocks. Min. Soc. Am. Spec. Pap. 2, 241–250 (1969)
Papike, J.J., Cameron, K.L., Baldwin, K.: Amphiboles and pyroxenes: characterisation of other than quadrilateral components and estimates of ferric iron from microprobe data. Geol. Soc. Am. Program. Abstr. 6, 1053–1054 (1974)
Pearce, J.A., Cann, J.R.: Tectonic setting of basic volcanic rocks determined using trace element analysis. Earth Planet. Sci. Lett. 19, 290–300 (1973)
Priem, H.N.A., Boelrijk, N.A.I.M., Hebeda, E.H., Schermerhorn, L.J.G., Verdurmen, E.A.Th., Verschure, R.H.: Sr isotopic homogenization through whole-rock systems under low greenschist facies metamorphism in Carboniferous pyroclastics at Aljustrel (Southern Portugal). Chem. Geol. 21, 307–314 (1978)
Pruvost, P.: Observations sur les terrains Devoniens et Carboniferes du Portugal et sur leur faune. Com. Serv. Geol. Portugal, T.X. 1–21 (1914)
Rankin, D.W.: The continental margin of Eastern North America in the Southern Appalachians: the opening and closing of the Proto-Atlantic ocean. Am. J. Sci. 275a, 298–336 (1976)
Riding, R.: Model for the Hercynian fold belt. Earth Planet. Sci. Lett. 24, 125–135 (1974)
Ritcher, D.A., Roy, D.C.: Prehnite-pumpellyite facies metamorphism in Central Aroostock County, Maine. Geol. Soc. Am. Mem 146, 239–262 (1976)
Salpeteur, I.: Etude structurale et petrographique de la zone de Paymogo (Nord de la Province d'Huelva). Metallogenese des amas sulfures associes. Thesis, Univ. Nancy, 232 p. (1976)
Schermerhorn, L.J.G.: Mafic geosynclinal volcanism in the lower Carboniferous of South Portugal. Geol. Mijnb. 46 (9), 439–450 (1970)
Schermerhorn, L.J.G.: An otuline stratigraphy of the Iberian Pyrite Belt. Bol. Geol. Minero, T. LXXXII-III-IV, 239–268 (1971)
Schermerhorn, L.J.G.: Pumpellyite facies metamorphism in the Spanish Pyrite Belt. Petrologie 1 (1), 71–86 (1975a)
Schermerhorn, L.J.G.: Spilites, regional metamorphism and subduction in the Iberian Pyrite Belt: some comments. Geol. Mijnb. 54 (1), 23–35 (1975b)
Schermerhorn, L.J.G., Stanton, W.I.: Folded overthrusts at Aljustrel (South Portugal). Geol. Mag. 106, 130–141 (1969)
Seki, Y.: Glaucophanitic regional metamorphism in the Kanto Mountains, central Japan. J. Geol. Geogr. 29, 233–258 (1958)
Seki, Y.: Facies series in low-grade metamorphism. J. Geol. Soc. Japan 75, 255–266 (1969)
Seki, Y.: Metamorphic facies of propylitic alteration. J. Geol. Soc. Japan 79, 771–780 (1973)
Seki, Y., Oki, Y., Matsuda, T., Mikami, K., Okumura, K.: Metamorphism in the Tanzawa Mountains, central Japan. J. Japan. Assoc. Min. Pet. Econ. Geol. 61, 1–75 (1969)
Seki, Y., Onuki, H., Oba, T., Mori, R.: Sanbagawa metamorphism in the central Kii Peninsula. Japan. Jap. J. Geol. Geogr. 1, 65–78 (1971)
Spooner, E.T.C., Fyfe, W.S.: Sub-sea-floor metamorphism, heat and mass transfer. Contrib. Mineral. Petrol. 42, 287–304 (1973)
Strauss, G.K., Madel, J., Alonso, F.F.: Exploration practice for strata-bound volcanogenic sulphide deposits in the Spanish-Portuguese Pyrite Belt: In: Time-and-Strata-Bound Ore Deposits (D.D. Klemm, H.Y. Schneider, eds.), pp. 56–91. Berlin-Heidelberg-New York: Springer 1977
Thompson, A.B.: P CO2 in low-grade metamorphism: zeolite, carbonate, clay mineral, prehnite relations in the system CaO-Al2O3-SiO2-CO2-H2O. Contrib. Mineral. Petrol. 63, 145–161 (1971)
Vallance, T.G.: Concerning spilites. Proc. Linn. Soc. N.S.W. 85, 7–52 (1960)
Vallance, T.G.: Spilites again: some consequences of the degradation of basalts. Proc. Linn. Soc. N.S.W. 94, 8–51 (1969)
Vegas, R., Munoz, M.: El contacto entre las zonas Surportuguesa y Ossa-Morena en SW Espana. Una nueva interpretacion. Comm. Serv. Geol. Portugal, T. LX, 31–52 (1976)
White, A.J.R.: Aegerine-riebeckite schists from South Westland, New Zealand. J. Petrol. 3, 38–48 (1962)
Wolery, T.J., Sleep, N.H.: Hydrothermal circulation and geochemical flux at mid-ocean ridges. J. Geol. 84, 249–275 (1976)
Zen, E-an: The zeolite facies: an interpretation. Am. J. Sci. 401–409 (1961)
Zwart, H.J.: The duality of the orogenic belts. Geol. Mijnb. 46, 288–309 (1967)
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On leave from: Mineralogia e Geologia, Faculdade de Ciencias, Lisboa-2, Portugal
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Munhá, J. Blue amphiboles, metamorphic regime and plate tectonic modelling in the Iberian Pyrite Belt. Contr. Mineral. and Petrol. 69, 279–289 (1979). https://doi.org/10.1007/BF00372330
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DOI: https://doi.org/10.1007/BF00372330