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40Ar/39Ar dating of white micas from an Alpine high-pressure metamorphic belt on Naxos (Greece): the resetting of the argon isotopic system

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Abstract

Overprinting of white micas from high pressure, low to medium temperature (M 1) metamorphic assemblages in pelitic schists on Naxos during subsequent thermal dome (M 2) metamorphism ranges from minor in the southeast of the island to complete recrystallization in the amphibolite facies rocks near the migmatites in the centre of the dome. The original (M 1) minerals are phengites (Si4+=6.7–7.0) and the overprinting minerals are muscovites (Si4+=6.0–6.45). 40Ar/39Ar step heating analyses of white mica separates from rocks in the area where phengite and muscovite occur together yield complex age spectra, characterized by low apparent ages in the first and the last stages of gas release and high apparent ages in between. These upward-convex age spectra are shown to be caused by mixing of two generations of micas, each of which has a different age spectrum and argon release pattern. Seemingly good plateaus in some age spectra from white micas of the area must be interpreted as providing meaningless intermediate ages. Further, the upward-convex age spectra have been used to trace the isotopic signature of phengites toward increasing M 2 metamorphic grade, and suggest that as long as phengites can be observed in the rocks upward-convex age spectra occur. On Naxos, crystallization of muscovite at the expense of phengite appears to be the main mechanism of resetting argon isotopic ages in white micas. However, there is also good evidence for argon loss by volume diffusion from phengites. Simple diffusion calculations suggest that the M 2 metamorphism was caused by a shortlived heat source.

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References

  • Altherr R, Schliestedt M, Okrusch M, Seidel E, Kreuzer H, Harre W, Lenz H, Wendt I, Wagner GA (1979) Geochronology of high pressure rocks on Siphnos (Cyclades, Greece). Contrib Mineral Petrol 70:245–255

    Google Scholar 

  • Andriessen PAM (1978) Isotopic age relations within the polymetamorphic complex of the island Naxos (Cyclades, Greece) Verhandelingen ZWO Laboratorium voor Isotopen Geologie no 3

  • Andriessen PAM, Boelrijk NAIM, Hebeda EH, Priem HNA, Verdurmen EATh, Verschure RH (1979) Dating the events of metamorphism and granitic magmatism in the Alpine Orogen at Naxos (Cyclades, Greece). Contrib Mineral Petrol 69:215–225

    Google Scholar 

  • Bonneau M, Geyssant J, Kienast JR, Lepvrier C, Maluski H(1980) Tectonique et metamorphisme haute pression d'age Eocene dans les Hellenides: exemple de File de Syros (Cyclades, Greece). CR Acad Sci Paris 291D:171–174

    Google Scholar 

  • Chopin C, Maluski H (1980) 40Ar/39Ar dating of high pressure metamorphic micas from the Gran Paradiso area (W. Alps): Evidence against the blocking temperature concept. Contrib Mineral Petrol 74:109–122

    Google Scholar 

  • Fechtig H, Kalbitzer S (1966) The diffusion of argon in K bearing solids. In: Schaeffer OA, Zahringer J (eds) Potassium Argon dating. Springer, Berlin Heidelberg New York

    Google Scholar 

  • Feenstra A (1985) Metamorphism of bauxites on Naxos, Greece. PhD Thesis RU Utrecht

  • Foland KA (1983) 40Ar/39Ar incremental heating plateaus for biotites with excess argon. Isotope Geosci 1:3–21

    Google Scholar 

  • Frey M, Hunziger JC, O'Neil JR, Schwander HW (1976) Equilibrium-disequilibrium relation in the Mte Rosa granite (W. Alps). Petrological, Rb/Sr and stable isotope data. Contrib Mineral Petrol 55:147–179

    Google Scholar 

  • Giletti BJ (1974) Diffusion related to geochronology. In: Hoffman AW et al. (eds) Geochemical transport and kinetics. Carnegie Inst Washington publ 634, pp 61–76

  • Hammerschmidt K (1983) Hump shaped 40Ar/39Ar age spectra. Indication of excess argon in white micas from the Swiss Alps. Fortschr Mineral [Beiheft 1] 61:78

    Google Scholar 

  • Hanson GM, Gast PW (1967) Kinetic studies in contact metamorphic zones. Geochim Cosmochim Acta 31:1119–1153

    Google Scholar 

  • Harrison TM, McDougall I (1980) Investigations of an intrusive contact, northwest Nelson, New Zealand. Geochim Cosmochim Acta 44:1985–2003

    Google Scholar 

  • Hart SR (1964) The petrology and isotopic mineral age relations of a contact zone in the Front Range, Colorado. J Geol 72:493–525

    Google Scholar 

  • Henjes-Kunst F (1980) Alpidische Einformung des PraeAlpidischen Kristallins und seiner Mesozoischen Hülle auf los (Kykladen, Griechenland). Thesis, University of Braunschweig

  • Horvath F, Berckhemer H (1982) Mediterranean backarc basins. In: Berckhemer H, Hsü K (eds) Alpine and Mediterranean geodynamics. Geodynamcis series Vol 7. AGU/GSA 1982

  • Hoschek G (1969) The stability of chloritoid and staurolite. Contrib Mineral Petrol 22:208–232

    Google Scholar 

  • Jansen JBH (1977) Metamorphism on Naxos, Greece. PhD Thesis RU Utrecht

  • Jansen JBH, Schuiling RD (1976) Metamorphism on Naxos. Petrology and geothermal gradients. Am J Sci 276:1225–1253

    Google Scholar 

  • Jost W (1952) Diffusion in solids, liquids, gases. 558 pp, Acad Press, New York

    Google Scholar 

  • Kreulen R (1980) CO2 rich fluids during regional metamorphism on Naxos, Greece: Carbon isotopes and fluid inclusions. Am J Sci 280:745–771

    Google Scholar 

  • Le Pichon X, Angelier J (1979) The Helenic arc and trench system. Tectonophys 60:1–42

    Google Scholar 

  • Lister GS, Banga G, Feesntra A (1984) Metamorphic core complexes of the Cordilleran type in the Cyclades, Greece. Geology 12:211–225

    Google Scholar 

  • McDougall (1966) Precision methods of potassium argon isotopic age determination on young rocks. In: Runcorn K (ed) Methods and Techniques in Geophysics, Vol 2. pp 279–304. Interscience, New York

    Google Scholar 

  • McDougall I (1974) The 40Ar/39Ar method of K-Ar age determination of rocks using HIFAR reactor. Atomic Energy in Australia 17:3–12

    Google Scholar 

  • McDougall I, Roksandic Z (1974) Total fusion 40Ar/39Ar ages using HIFAR reactor. J Geol Soc Austr 21:81–89

    Google Scholar 

  • McDougall I, Schmincke H (1977) Geochronology of Gran Canaria, Canary Islands. Bull Volcanol 40:57–77

    Google Scholar 

  • McKenzie DP (1978) Active tectonics of the Alpine Himalayan belt: the Aegean Sea and surroundings. Geophys JR Astronom Soc 55:217–254

    Google Scholar 

  • Mussett AE (1969) Diffusion measurements and the potassium argon method of dating. Geophys JR Astronom Soc 18:259–303

    Google Scholar 

  • Pankhurst RJ, Moorbath S, Rex DC, Turner G (1973) Mineral age patterns in a ca 3700 Ma old rock from W. Greenland. Earth Plan Sci Lett 20:157–170

    Google Scholar 

  • Robbins GA (1972) Radiogenic argon diffusion in muscovite under hydrothermal conditions. MSc thesis Brown University

  • Steiger R, Jäger E (1977) Subcommission on Geochronology: Convention on the use of decay constants in geoand cosmochronology. Earth Plan Sci Lett 36:359–362

    Google Scholar 

  • Tetley NW (1978) Geochronology by the 40Ar/39Ar technique. Unpubl PhD Thesis, ANU, Canberra

    Google Scholar 

  • Tetley NW, McDougall I, Heydegger HR (1980) Thermal neutron interferences in the 40Ar/39Ar dating technique. J Geophys Res 85:7201–7205

    Google Scholar 

  • Turner G (1968) The distribution of potassium and argon in chondrites. In: Ahrens LH (ed) Origin and distribution of the elements, pp 387–398, Pergamon Press, New York

    Google Scholar 

  • Turner G, Miller JA, Grasty RL (1966) The thermal history of the Bruderheim meteorite. Earth Plan Sci Lett 1:155–157

    Google Scholar 

  • Verschure RH, Andriessen PAM, Boelrijk NAIM, Hebeda EH, Maijer C, Priem HNA, Verdurmen EATh (1979) On the thermal stability of Rb/Sr and K/Ar biotite systems. Evidence from coexisting Sveconorwegian (ca. 870 Ma) and Caledonian (ca. 400 Ma) biotites in SW Norway. Contrib Mineral Petrol 74:245–252

    Google Scholar 

  • Wijbrans JR (1985) Geochronology of metamorphic terrains by the 40Ar/39Ar age spectrum method. Unpubl PhD thesis, ANU, Canberra

    Google Scholar 

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Now at Department of Geology, University of Alberta, Edmonton T6G 2E3, Canada

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Wijbrans, J.R., McDougall, I. 40Ar/39Ar dating of white micas from an Alpine high-pressure metamorphic belt on Naxos (Greece): the resetting of the argon isotopic system. Contr. Mineral. and Petrol. 93, 187–194 (1986). https://doi.org/10.1007/BF00371320

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  • DOI: https://doi.org/10.1007/BF00371320

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