Abstract
Major structural discontinuities in the Abitibi greenstone belt acted as conduits for outgassing of the Archean crust, as reflected in fixation of a select group of lithophile elements including Si, C, K, Rb, Ba, Li, Cs, B and Pb, in metasomatized faults. For two of the largest structures, the Destor-Porcupine (DP) and Kirkland Lake — Cadillac (KC) fault zones ∼6×1015 g Si, 3×1015 g CO2 and 1015 g K were introduced into the faults during expulsion of an estimated 6×1018 g aqueous fluids. Strontium isotope ratios of tourmaline, piemontite, actinolite and scheelite mineral separates, characterized by Rb/Sr≤0.02, are concordant with respect to 87Sr/86Sr initial ratios over local sectors of the faults. The Sr isotope data record geographic variations which, from east to west on the KC fault is 0.7031–0.7041 (Val d'Or), 0.7008–0.7022 (Bourlemaque), 0.7017–0.7019 (Bousquet), 0.7029–0.7031 (Noranda), and 0.7013 to 0.7015 (Kirkland Lake). At Timmins, on the PD fault, 87Sr/86Sr initial ratios cluster at 0.7010 to 0.7020. Metasomatised fault zones are systematically more radiogenic than contiguous host lithologies, and imply a source reservoir (0.7010 to 0.7041) generally more radiogenic than the upper mantle at 2690 Ma (0.700±0.001), or contemporaneous volcanic rocks of mafic to ultramafic composition (0.700 to 0.7012). Whereas certain minerals are concordant and retentive, Rb-Sr isochrons based on suites of rocks at progressive intensities of metasomatism, have been systematically reset over an elpased time of ∼200 Ma after termination of outgassing, due to disturbance accompanying incremental displacements on structures.
Carbon isotope compositions of ferroan dolomites in faults are tightly clustered along local fault sectors, but also display a marked provinciality: from east to west δ 13C=−6.0 to −8.5 (Malartic), −8.0 to −9.0 (Cadillac), −2.0 to −4.5 (Kirkland Lake), and −0.5 to −3.5 (Timmins). The observed provinciality of both δ 13C values and 87Sr/86Sr initial ratios is interpreted to reflect compositional heterogeneities in a radiogenic sialic crust and the green-stone belt supracrustal sequence, both of which supplied volatiles, magmas and lithophile elements to the fault structures during late stage transpressive tectonics.
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References
Abbott JT (1972) Rb-Sr study of isotopic redistribution in a Precambrian mylonite-bearing shear zone, Northern Front Range, Colorado. GSA Bull 83:487–494
Andrews AJ, Masliewec A, Morris WA, Owsiaki L, York D (1986) The silver deposits at Cobalt and Gowganda, Ontario: an experiment in age determinations employing radiometric and palaeomagnetic measurements. Can J Earth Sci (in press)
Bell K, Blenkinsop J (1976) A Rb-Sr whole-rock isochron from the Otto Stock. Can J Earth Sci 13:998–1002
Bell K, Blenkinsop J (1978) Reset Rb/Sr whole-rock systems and chemical control. Nature 273:532–534
Birk D, McNutt RH (1981) Geochronology of Wabigoon belt granitoids, northwestern Ontario: Rb/Sr isochrons for seven late-tectonic plutons. Can J Earth Sci 18:157–175
Bolke JK, Kistler RW (1986) Rb-Sr, K-Ar, and stable isotope evidence for the ages and sources of fluid components of gold bearing quartz veins in the Northern Sierra Nevada Foothills Metamorphic Belt, California. Econ Geol 81:296–322
Bradbury HJ, Rye DM (1987) Dewatering of Pyrenean thrust sheets. Am J Sci (in press)
Brooks C (1980) The Rb/Sr geochronology of the Archean Chibougamau pluton, Quebec. Can J Earth Sci 17:776–783
Brooks C, Ludden J, Pigeon Y, Hubregtse JJMW (1982) Volcanism of shoshonite to high-K andesite affinity in an Archean arc environment, Oxford Lake, Manitoba. Can J Earth Sci 19:55–67
Claesson S (1980) A Rb-Sr isotope study of granitoids and related mylonites in the Tannas Augen Gneiss Nappe, southern Swedish Caledonides. Geol Fœren Stockholm Fœrh 102:403–420
Clark GS, Cheung S-P (1980) Rubidium-strontium ages from the Oxford Lake-Knee Lake greenstone belt, northern Manitoba. Can J Earth Sci 17:560–568
Clark GS, Bald R, Ayres LD (1981) Geochronology of orthogneiss adjacent to the Archean Lake of the Woods Greenstone Belt, Northwestern Ontario: a possible basement complex. Can J Earth Sci 18:94–102
Clayton RN, Muffler LJP, White DE (1968) Oxygen isotope study of calcite and silicates of the River Branch No. 1 well, Salton Sea geothermal field, California. Am J Sci 266:968–979
Collerson KD, Fryer BJ (1978) Role of fluids in the formation and subsequent development of early continental crust. Contrib Mineral Petrol 67:151–167
Colvine AC, Andrews AJ, Cherry ME, Durocher ME, Fyon AJ, Lavigne MJ Jr, Macdonald AJ, Marmot S, Poulsen KH, Troop DG (1984) An integrated model for the origin of Archean gold deposits. Ontario Geological Survey, Open File Report 5524, p 98
Costa UR, Barnett RL, Kerrich R (1983) The Mattagami Lake mine Archean Zn-Cu sulphide deposit, Quebec: hydrothermal coprecipitation of talc and sulfides in a sea-floor brine pool — evidence from geochemistry. 18O/16O, and mineral chemistry. Econ Geol 78:1144–1203
Dickin AP, Rice CM, Harmon RS (1986) A strontium and oxygen isotope study of Laramide magmatic and hydrothermal activity near Central City, Colorado. Econ Geol 81:904–914
Eliopoulos D (1984) The Dumagami Mine, Quebec. MSc thesis, University of Western Ontario, London, Canada, p 214
Fairbairn HW, Hurley PM, Card KD, Knight CJ (1969) Correlation of radiometric ags of Nipissing diabse and Huronian metasediments with Proterozoic orogenic events in Ontario. Can J Earth Sci 66:489–497
Faure G (1977) Principles of isotope geology. John Wiley and Sons, Toronto, p 464
Floyd PA, Winchester JA (1978) Identification and discrimination of altered and metamorphosed volcanic rocks using immobile elements. Chem Geol 21:291–306
Foy R (1984) Geochemistry of the Kirkland Lake Larder Lake Fault. BSc thesis, University of Western Ontario, London, Canada
Franklin JM, Roscoe SM, Loveridge WD, Sangster DF (1983) Lead isotope studies in Superior and Southern provinces. Geol Surv Can Bull 351:60
Frarey MJ, Krogh TE (1986) U-Pb zircon ages of late internal plutons of the Abitibi and eastern subprovinces, Ontario and Quebec. Geol Surv Can Current Res A:43–48
Friedman I, O'Neil JR (1977) Compilation of stable isotope fractionation factors of geochemical interest. Chapter XX. Data of geochemistry. US Geol Surv Prof Pap 440-KK
Frith RA, Doig R (1975) Pre-Kenoran tonalitic gneisses in the Grenville province. Can J Earth Sci 12:844–849
Fryer BJ, Kerrich R, Hutchinson RW, Peirce MG, Rodgers DS (1979) Archean precious metal hydrothermal systems, Dome Mine, Abitibi greenstone belt. I. Can J Earth Sci 16:421–439
Fyon JA, Crocket JN, Schwartz HP (1983) Application of stable isotopes studies to gold metallogeny in the Timmins-Porcupine camp. Ont Geol Surv Open File Rep 5464:182
Fyon JA, Schwarcz HP, Crocket JH (1984) Carbonatization and gold mineralization in the Timmins area, Abitibi greenstone belt: genetic links with Archean mantle CO2-degassing and lower crust granulitization. Geol Assoc Can 9:65
Gariepy C (1984) U-Pb isotopic evidence for the presence of pre-2.7 Ga sialic crust in the Abitibi greenstone Belt, Quebec. Geol Assoc Can 9:65
Gariepy C, Allegre CJ (1985) The lead isotope geochemistry and geochronology of late-kinematic intrusives from the Abitibi greenstone belt, and the implications for crustal evolution. Geochim Cosmochim Acta 49:2371–2383
Gates TM, Hurley PM (1973) Evaluation of Rb-Sr dating methods applied to Matachewan Abitibi, Mackenzie and Sudbury dike swarms in Canada. Can J Earth Sci 10:900–1919
Gower CF, Crocket JH, Kabir A (1983) Petrogenesis of Archean granitoid plutons from the Kenora area, English River Subprovince, Northwest Ontario, Canada. Precamb Res 22:245–270
Hart SR, Brooks C (1977) The geochemical evolution of Early Precambrian mantle. Contrib Mineral Petrol 61:109–128
Hickman MH, Glassley WE (1984) The role of metamorphic fluid transport in the Rb-Sr isotopic resetting of shear zones: evidence from Nordre Stromfjord, West Greenland. Contrib Mineral Petrol 87:265–281
Hoefs J (1978) Some peculiarities in the carbon isotope composition of ‘juvenile’ carbon. Dep Sci Industr Res Bull 200:181–184
Jahn B, Murthy VR (1975) Rb-Sr ages of the Archean rocks from the Vermilian district, northeastern Minnesota. Geochim Cosmochim Acta 39:1679–1689
Javoy M, Pineau F, Delorme H (1986) Carbon and nitrogen isotopes in the mantle. Chem Geol 57:41–62
Jensen LS, Langford FF (1985) Geology and petrogenesis of the Archean Abitibi Belt in the Kirkland Lake Area, Ontario. Ont Geol Surv Misc Pap 123:130
Kerrich R (1983) Geochemistry of gold deposits in the Abitibi greenstone belt. CIM Spec Pap 27:75
Kerrich R (1985) Archean lode gold deposits: the solute source problem. GSA 1985 Orlando, Florida
Kerrich R (1986) Fluid transport in lineaments. Philos Trans R Soc London A317:219–251
Kerrich R (1987) The stable isotope geochemistry of Au-Ag vein deposits in metamorphic rocks. In: Kyser TK (ed) Stable isotope geochemistry of low temperature processes. GAC-MAC Short Course 11:318–361
Kerrich R, Allison I (1978) Vein geometry and hydrostatics during Yellowknife mineralization. Can J Earth Sci 15:1653–1660
Kerrich R, Fryer BJ (1979) Archaean precious-metal hydrothermal systems, Dome Mine, Abitibi Greenstone Belt. II. REE and oxygen isotope relations. Can J Earth Sci 16:440–458
Kerrich R, Watson GP (1984) The Macassa Mine Archean lode gold deposit, Kirkland Lake, Ontario: geology, patterns of alteration, and hydrothermal regimes. Econ Geol 79:1104–1130
Kerrich R, Kishida A, Willmore LM (1984) Timing of Abitibi Belt lode gold deposits: evidence from 39A/40Ar and 87Rb86Sr. Geol Assoc Can 9:78
Kesler SE, Jones LM (1981) Sulfur- and strontium-isotope geochemistry of celestite, barite and gypsum from the Mesozoic basins of northeastern Mexico. Chem Geol 31:211–224
Kesler SE, Russell N, Seaward M, Rivera J, McCurdy K, Cumming GL, Sutter JF (1981) Geology and geochemistry of sulfide mineralization underlying the Pueblo Viejo gold-silver oxide deposit, Dominican Republic. Econ Geol 76:1096–1117
King RW, Kerrich R (1987) Fluorapatite fenitization and gold enrichment in sheeted trondhjemites with the Destor-Porcupine fault zone, Taylor Township, Ontario. Can J Earth Sci 24:479–502
Kishida A, Kerrich R (1987) Hydrothermal alteration zoning and gold concentration at the Kerr-Addison Archean lode gold deposit, Kirkland Lake, Ontario. Econ Geol (in press)
Krogh TE, Davis GL (1971) Zircon U-Pb ages of Archean metavolcanic rocks in the Canadian Shield. Carnegie Inst Washington Yearb 70:241–242
Krogh TE, Davis DW, Nunes PD, Korfu F (1982) Archean evolution from precise U-Pb isotopic dating. Geol Assoc Can 7:61
Lamb W, Valley JW (1984) Metamorphism of reduced granulites in low-CO2 vapour-free environment. Mature 312:56–58
Maas R, McCulloch MT, Campbell IH, Coad PR (1986) Sm-Nd and Rb-Sr dating of an Archean massive sulphide deposit, Kidd Creek, Ontario. Geology 14:585–588
Machado N, Brooks C, Hart SR (1986) Determination of initial 87Sr/86Sr and 143Nd/144Nd in primary minerals from mafic and ultramafic rocks: experimental procedure and implications for the isotopic characteristics of the Archean mantle under the Abitibi greenstone belt, Canada. Geochim Cosmochim Acta 50:2335–2348
McCrea JM (1950) The isotopic chemistry of carbonates and a palaeotemperature scale. J Chem Phys 18:849
McNeil AM, Kerrich R (1986) Archean lamprophyric dykes and gold mineralization, Matheson, Ontario: the conjunction of LIL-enriched mafic magmas, deep crustal structures and Au concentration. Can J Earth Sci 23:324–342
Muehlenbachs K, Clayton RN (1972a) Oxygen isotope studies of the fresh and weathered submarine basalts. Can J Earth Sci 9:172–184
Muehlenbachs K, Clayton RN (1972b) Oxygen isotope geochemistry of submarine greenstones. Can J Earth Sci 9:471–478
Newton RC, Smith JV, Windley BF (1980) Carbonic metamorphism, granulites, and crustal growth. Nature 288:45–50
Norman DI, Landis GP (1983) Source of minerlization components in hydrothermal ore fluids as evidenced by 87Sr/86Sr and stable isotope data from the Pasto Bueno Deposit, Peru. Econ Geol 78:451–465
Nunes PD, Jensen LS (1980) Geochronology of the Abitibi metavolcanic belt, Krikland Lake area — progress report. In: Pye EG (ed) Summary of geochronology studies 1977–1979. Ont Geol Surv Misc Pap 92:40–45
Nunes PD, Pyke DR (1980) Geochronology of the Abitibi Metavolcanic Belt, Timmins-Matachewan Area — progress report. In: Pye EG (ed) Summary of geochronology studies 1977–1979. Ont Geol Surv Misc Pap 92:34–38
Ohmoto H, Rye RO (1979) Isotopes of sulphur and carbon. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 2nd. John Wiley and Sons, New York, pp 509–562
Pearce JA, Cann JR (1973) Tectonic setting of basic volcanic rocks determined using trace element analysis. Earth Planet Sci Lett 19:290–300
Percival JA, Krogh TE (1983) U-Pb zircon geochronology of the Kapuskasing structural zone and vicinity in the Chapleau-Foleyet area, Ontario. Can J Earth Sci 20:830–843
Peterman ZE, Goldich SS, Doe BR, Naesar CW, Rasholt JN, Zartman RE, Kamineni DC (1985) Isotopic studies of core samples from the Eye Dashwa Lakes pluton, Atikokan, Ontario. Atomic Energy of Canada Ltd., Technical Record 299:642–644
Priem HNA, Boelrijk NAIM, Hebeda EH, Schermerhorn LJG, Verdurmen EATH, Verschure RH (1978) Sr isotope homogenisation through whole-rock systems under low-greenschist facies metamorphism in carboniferous pyroclastics at Aljustrel (southern Portugal). Chem Geol 21:307–314
Purdy JW, York D (1968) Rb-Sr whole-rock and K-Ar mineral ages of rocks from the Superior Province near Kirkland Lake, northeastern Ontario, Canada. Can J Earth Sci 5:699–705
Ruiz J, Jones LM, Kelly WC (1984) Rubidium-strontium dating of ore deposits hosted by Rb-rich rocks, using calcite and other common Sr-binding minerals. Geology 12:259–262
Rye RO, Ohmoto H (1974) Sulfur and carbo isotopes and ore genesis: a review. Econ Geol 69:826–842
Schoell M, Wellmer FW (1981) Anomalous 13C depletions in early Precambrian graphites from Superior Province, Canada. Nature 290:696–699
Spooner ETC, Chapman HJ, Sinewing DJ (1977) Strontium isotope contamination and oxidation during ocean floor hydrothermal metamorphism of the ophiolitic rocks of the Troodos Massif Cyprus. Geochim Cosmochim Acta 41:873–890
Strauss H (1986) Carbon and sulfur isotopes in Precambrian sediments from the Canadian Shield. Geochim Cosmochim Acta 50:2653–2662
Taylor BE (1986) Magmatic volatiles: isotopic variations of C, H, and S. In: Valley JW, Taylor HP Jr, O'Neil Jr (eds) Stable isotopes in high temperature geological processes. Mineral Soc Am 16, Bookcrafters Inc., Michigan, pp 185–226
Taylor RP, Fryer BJ (1983) Strontium isotope geochemistry of the Santa Rita porphyry copper deposit, New Mexico. Econ Geol 78:170–174
Thompson JE (1941a) Geology of Gauthier Township, east Kirkland Lake area. Ont Dep Mines Ann Rep 50:80
Thompson JE (1941b) Geology of McGarry and McVittie Townships, Larder Lake Area. Ont Dep Mines Ann Rep 50:99
Thurston PC, Fryer BJ (1983) Geochemistry of repetitive cyclical volcanism in the Uchi-Confederation greenstone belt, Canada. Contrib Mineral Petrol 83:204–226
Turek A, Smith PE, Vam Schmus WR (1982) Rb-Sr and U-Pb ages of volcanism and granite emplacement in the Michipicoten belt — Wawa, Ontario. Can J Earth Sci 19:1608–1626
Valley JW (1986) Stable isotope geochemistry of metamorphic rocks. In: Valley JW, Taylor HP Jr, O'Neil JR (eds) Stable isotopes in high temperature geologic processes. Mineralogical Society of America 16, Bookcrafters Inc., Michigan, 185–226
Veizer J (1976) 87Sr/86Sr Evolution of seawater during geological history and its significance as an index of crustal evolution. In: Windley BF (ed) The early history of the earth. John Wiley & Sons, London, pp 569–578
Verpaelst P, Brooks C, Franconi A (1980) The 2.5 Ga Duxbury massif, Quebec: a remobilized piece of pre-2.0 Ga sialic basemen(?). Can J Earth Sci 17:1–18
Wickman FE, Aberg G, Levi B (1983) Rb-Sr dating of alteration events in granitoids. Contrib Mineral Petrol 83:358–362
Wyman DA, Kerrich R (1987) Archean lymprophyres. I. Distribution and tectonic setting. Geol Assoc Can 7:102
Wyman DA, Kerrich R, Fryer BJ (1986) Gold mineralization overprinting iron formation at Agnico-Eagle Deposit, Quebec, Canada: mineralogical, microstructural and geochemical evidence. In: Macdonald AJ (ed) Proceedings of Gold '86. Toronto 1986, pp 108–123
Zeck HP, Wallin B (1980) A 1220±60 M.Y. Rb-Sr isochron age representing a Taylor-convection caused recrystallization event in a granitic rock suite. Contrib Mineral Petrol 74:45–53
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Kerrich, R., Fryer, B.J., King, R.W. et al. Crustal outgassing and LILE enrichment in major lithosphere structures, Archean Abitibi greenstone belt: evidence on the source reservoir from strontium and carbon isotope tracers. Contr. Mineral. and Petrol. 97, 156–168 (1987). https://doi.org/10.1007/BF00371236
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DOI: https://doi.org/10.1007/BF00371236