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Voltammetric method for the determination of H2O2 in rainwater

  • General And Aquatic Analytical Chemistry
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Summary

Presented below is an electrochemical method for the determination of hydrogen peroxide levels in the atmospheric liquid water. The hydrogen peroxide concentration is determined by a voltammetric method involving a rotating disk electrode. The oxidation limiting current at +0.4 V/SCE is proportional to the concentration of hydrogen peroxide found in 1 mol/l KNO3 containing a phosphate buffer, pH 7.5. An analytical blank is prepared ‘in situ’ by addition of catalase enzyme to avoid interferences. The detection limit obtained is 5×10−9 mol/l.

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References

  1. Penkett S-A, Jones B-M, Brice K-A, Eggleton A-E (1979) Atmos Environ 13:123–127

    Google Scholar 

  2. Chameides W-L, Davis D-D (1982) J Geophys Res 87:4863

    Google Scholar 

  3. Lazrus A-L, Kok G-L, Gitlin S-N, Lind J-A, McLaren S-E (1985) Anal Chem 57:917–922

    Google Scholar 

  4. Beilke S, Elshout A-J (1982) Acid Deposition. Reidel Publishing Company, Dordrecht Boston Lancaster

    Google Scholar 

  5. Heikes B-G, Lazrus A-L, Kok G-L, Kunen S-M, Gandrud B-W, Gitlin S-N, Sperry P-D (1982) J Geophys Res 87:3045

    Google Scholar 

  6. Kok G-L, Holler T-P, Lopez M-B, Nachtrieb H-A, Yuan M (1978) Environ Sci Technol 12:1072

    Google Scholar 

  7. Ibusuki T (1983) Atmos Environ 17:393

    Google Scholar 

  8. Shaw F (1980) The Analyst 105:11

    Google Scholar 

  9. Klockow D, Jacob P (1986) Nato asi series G6: chemistry of multiphase atmospheric system. Jaeschke, Berlin

    Google Scholar 

  10. Scott G, Seitz W-R, Ambrose J (1980) Anal Chim Acta 115:221

    Google Scholar 

  11. Williams III D-C, Huff G-F, Seitz W-R (1976) Anal Chem 48:1003

    Google Scholar 

  12. Williams III D-C, Seitz W-R (1976) Anal Chem 48:1478

    Google Scholar 

  13. Frew J-E, Jones P, Scholes G (1983) Anal Chim Acta 155:139

    Google Scholar 

  14. Tamaoku K, Murao Y, Akiura K, Ohkura Y (1982) Anal Chim Acta 136:121

    Google Scholar 

  15. Lazrus A-L, Kok G-L, Lind J-A, Gitlin S-N, Heikes B-G, Shetter R-E (1986) Anal Chem 58:594

    Google Scholar 

  16. Peinato J, Toribio F, Perez-Bendito D (1986) Anal Chem 58:1725

    Google Scholar 

  17. Lagrange J, Lagrange P (1990) Analusis (in press)

  18. Kusu F, Nishikawa Y, Takamura K (1980) Tokyo Yakka Daigaku Kenkyu Nempo 30:1363

    Google Scholar 

  19. Gutz G-R, Klockow D (1989) Fresenius Z Anal Chem 335:919

    Google Scholar 

  20. Masuch G, Kettrup A, Mallant RKAM, Slanina J (1986) Int J Environ Anal Chem 27:183

    Google Scholar 

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Lagrange, J., Lagrange, P. Voltammetric method for the determination of H2O2 in rainwater. Fresenius J Anal Chem 339, 452–454 (1991). https://doi.org/10.1007/BF00323796

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  • DOI: https://doi.org/10.1007/BF00323796

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