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Application of direct on-line coupling of HPLC and SFC with 1HNMR spectroscopy for the investigation of monomeric acrylates

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  • Polymers
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Abstract

The separation of monomeric acrylates was performed with High Performance Liquid Chromatography (HPLC) and Supercritical Fluid Chromatography (SFC). A direct on-line structural assignment of all compounds by continuous-flow 1HNMR spectroscopy is possible with both separation techniques. The direct SFC-NMR coupling offers the advantage that the recorded continuous-flow 1HNMR spectrum is not obscured by solvent signals.

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Authors and Affiliations

  1. Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, D-72076, Tübingen, Germany

    Klaus Albert & Ulrich Braumann

  2. Dow Deutschland Inc., Industriestr. 1, D-77836, Rheinmünster, Germany

    Roman Streck

  3. Bruker Analytische Meßtechnik, Silberstreifen, D-76287, Rheinstetten, Germany

    Manfred Spraul

  4. Hewlett Packard GmbH, Ermlis-Allee, D-76337, Waldbronn, Germany

    Rainer Ecker

Authors
  1. Klaus Albert
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  2. Ulrich Braumann
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  3. Roman Streck
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  4. Manfred Spraul
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  5. Rainer Ecker
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Additional information

Dedicated to Professor Dr. H. Kriegsmann on the occasion of his 70th birthday

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Albert, K., Braumann, U., Streck, R. et al. Application of direct on-line coupling of HPLC and SFC with 1HNMR spectroscopy for the investigation of monomeric acrylates. Fresenius J Anal Chem 352, 521–528 (1995). https://doi.org/10.1007/BF00323378

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  • DOI: https://doi.org/10.1007/BF00323378

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