Abstract
According to the multiresidue analysis method DFG S 19, different approaches for the substitution of dichloromethane in the liquid/liquid partition step were investigated. Due to maximum residue limits (MRL), fortification experiments with 17 GC/ECD and GC/NPD detectable pesticides were carried out in concentrations of 1 and 0.1 mg/kg apples, 1 and 0.05 mg/kg tomatoes, 1 and 0.1 mg/kg lettuce, respectively. In supplementary greenhouse experiments, lettuce was cultivated and a mixture of 10 plant protection products was applied in commonly used amounts. In both cases, the comparison of pesticide recoveries shows that several less toxic solvents like cyclohexane, light petroleum and tertiary butyl methyl ether are suitable substitutes for the more toxic and persistent dichloromethane.
Similar content being viewed by others
References
(1991) 1. Verordnung zum Schutz des Verbrauchers vor bestimmten aliphatischen Chlorkohlenwasserstoffen. BGBl 1:1059
Gunschera J, Lorenz W, Bahadir M (1992) Fresenius Environ Bull 1:197–202
Specht W, Tillkes M (1985) Fresenius Z Anal Chem 322:443–455
DFG Pesticide Commission (1987) Manual of pesticide residue analysis. VCH, Weinheim
Andersson A, Pålsheden H (1991) Fresenius J Anal Chem 339:365–367
Koinecke A (1992) Diploma Thesis, Institute of Ecological Chemistry and Waste Analysis, Technical University of Braunschweig
Ebing W (1987) Fresenius Z Anal Chem 327:539–543
Koinecke A, Bahadir M, Kreuzig R, Nolting H-G, Siebers J (1992) Mitt Biol Bundesanst Land-Forstwirtsch 283:128
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Koinecke, A., Kreuzig, R., Bahadir, M. et al. Investigations on the substitution of dichloromethane in pesticide residue analysis of plant materials. Fresenius J Anal Chem 349, 301–305 (1994). https://doi.org/10.1007/BF00323208
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00323208