Abstract
A sensitive and reliable method is described for the determination of aromatic and chlorinated hydrocarbons (benzene, toluene, o-, m-, p-xylene, trichloromethane, trichloroethane, trichloroethene and tetrachloroethene) in indoor and outdoor air at environmental concentration levels. The procedure can be easily extended to other VOCs. Using passive samplers the VOCs have been adsorbed onto charcoal during a four-week sampling period and subsequently desorbed with carbon disulfide. After injection with a cold split-splitless multi-injector the VOCs have been separated by capillary gas chromatography. Quantification has been achieved using an electron capture detector (ECD) and a flame ionization detector (FID) switched in series. A limit of about 1 μg/m3 for aromatic hydrocarbons and of about 0.01 μg/m3 for chlorinated hydrocarbons has been obtained. The procedure has been successfully applied in the framework of a field study to measure indoor and outdoor air concentrations in Essen and Borken, two differently polluted areas of Northrhine-Westphalia.
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Seifert B, Abraham HJ (1982) Ecotox Environ Safety 6:190–192
Seifert B, Abraham HJ (1983) Intern J Anal Chem 13:237–253
Seifert B, Ullrich D, Nagel R (1984) Schr-R Verein WaboLu 59:1–13
Seifert B (1988) Sampling and analysis of ambient and indoor air. In: Fishbein L, O'Neill IK (eds) Environmental carcinogens — methods of analysis and exposure measurement, vol 10, pp 165–178. IARC Science Publications No 85
Seifert B, Mailahn W, Schulz C (1989) Environ Int 15:397–408
Cohen MA, Ryan B, Yanagisawa Y, Hammond SK (1990) J Air Waste Manage 40:993–997
Krause C, Mailahn W, Nagel R (1987) Occurance of volatile organic compounds in the air of 500 homes in the Federal Republic of Germany. In: Seifert B et al. (eds) Proceedings of the 4th Int Conf Indoor Air Quality 1987, vol 1: 102–106. Institute for Water, Soil and Air Hygiene, Berlin
Shields HC, Weschler CJ (1987) JAPCA 37:1039–1045
Bundesgesundheitsamt (1988) Bundesgesundheitsbl 31:99–101
Eller PM (ed) (1984) NIOSH manual of analytical methods, 3rd edn, vol 1. DHHS (NIOSH) Publication 84–100
3M Deutschland GmbH (1986) Technische Informationen 3M Monitore
Rodriguez ST, Gosselink DW, Mullins HE (1982) Am Ind Hyg Assoc J 43:569–573
Begerow J, Jermann E, Keles T (1994) Environ Res (submitted for publication)
Porstmann F, Böke J, Hartwig S (1994) Staub-Reinhalt Luft 54:147–153
Lautenberger WJ, Kring EV, Morello JA (1980) Am Ind Hyg Assoc J 4:737
Wallace LA, Pellizzari ED, Hartwell TD (1987) Environ Res 43:290–307
Bruckmann P, Kersten W, Hagedorn B, Ball M, Päpke O, Funcke W, Theisen J (1989) VDI-Berichte Nr. 745:209–234
Pfeffer H.-U., Ellermann K (1992) LIMES-Jahresbericht 1990 — Diskontinuierliche Messungen Reihe B — Schwebstaub und Inhaltsstoffe, Kohlenwasserstoffe. In: Landesanstalt für Immissionsschutz Nordrhein-Westfalen (Hrsg), Berichte über die Luftqualität in Nordrhein-Westfalen
Buck M, Ellermann K (1989) Die Immissionsbelastung durch Benzol in Nordrhein-Westfalen. Landesanstalt für Immissionschutz Nordrhein-Westfalen (Hrsg), LIS-Berichte Nr 82
Harkov R, Kebbekus B, Bozzelli JW (1984) Sci Total Environ 38: 259–274
Shields HC, Weschler CJ (1990) Indoor Air '90 Vol 2:771–776
Gilli G, Bono R, Scursatone E (1990) Arch Environ Health 45:101–106
Lebret E, van de Wiel HJ, Bos HP (1986) Environ Intern 12:323–332
Pristas R (1991) Am Ind Hyg Assoc J 52:297–304
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Begerow, J., Jermann, E., Keles, T. et al. Passive sampling for volatile organic compounds (VOCs) in air at environmentally relevant concentration levels. Fresenius J Anal Chem 351, 549–554 (1995). https://doi.org/10.1007/BF00322731
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DOI: https://doi.org/10.1007/BF00322731