Skip to main content
Log in

Low-temperature coherent exsolution in alkali feldspars from high-grade metamorphic rocks of Sri Lanka

  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

In the alkali feldspars of the amphibolite- and granulite-facies rocks of Sri Lanka, a late-stage, final exsolution event is observed which produced film lamellae and fine-scale spindles. These were investigated by optical, microprobe, single-crystal, transmission electron microscopy and atomic resolution microscopy techniques. The lamellae and spindles exsolved below the coherent solvus at temperatures as low as 300 to 350° C. Precession photographs and ARM micrographs show that the intergrowth is perfectly coherent. In sections ‖ (010) the rhombic section of the Pericline twins corresponds to analbite or high albite. The albite lamellae and spindles nucleated and grew at low temperatures in a metastable disordered structural state within a tweed-orthoclase matrix and became periodically twinned analbite or high albite, which subsequently developed only a slight increase in Al, Si order. The relationship between twin periodicity and lamellar width, predicted for coherent intergrowths by Willaime and Gandais (1972), is obeyed. In Or-rich grains, in which coherent exsolution is the only exsolution event, the film lamellae tend to be restricted to the rim, the fine-scale spindles to the centre of the grains. The films nucleated heterogeneously at grain boundaries and grew towards the grain centres. Fine-scale spindles probably nucleated homogeneously in the interior part of grains. Heterogeneous nucleation and coherent growth are not mutually exclusive.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Bence AE, Albee AL (1968) Empirical correction factors for the electron microanalysis of silicates and oxides. J Geol 76:382–403

    Google Scholar 

  • Bohlen SR, Essene EJ (1977) Feldspar and oxide thermometry of granulites in the Adirondack Highlands. Contrib Mineral Petrol 62:153–169

    Google Scholar 

  • Brady JB, Yund RA (1983) Interdiffusion of K and Na in alkali feldspars: homogenization experiments. Am Mineral 68:106–111

    Google Scholar 

  • Brown WL, Parsons I (1983) Nucleation of perthite-perthite boundaries and exsolution mechanisms in alkali feldspars. Phys Chem Miner 10:55–61

    Google Scholar 

  • Brown WL, Parsons I (1984) The nature of potassium feldspar, exsolution microtextures and development of dislocations as a function of composition in perthitic alkali feldspars. Contrib Mineral Petrol 86:335–341

    Google Scholar 

  • Brown WL, Willaime C (1974) An explanation of exsolution orientations and residual strain in cryptoperthites. In: MacKenzie WS, Zussman J (eds) The feldspars. Manchester Univ Press, pp 440–459

  • Buntebarth G (1991) Thermal models of cooling. In: Voll G, Töpel J, Pattison DRM, Seifert F (eds) Equilibrium and kinetics in contact metamorphism. Springer, Berlin Heidelberg New York, pp 267–473

    Google Scholar 

  • Büsch W, Mehnert KR (1991) Antiperthites in granulites and similar structures in migmatites of the Black Forest. Neues Jahrb Mineral Abh 162:117–133

    Google Scholar 

  • Cahn JW (1962) Coherent fluctuations and nucleation in isotropic solids. Acta Crystallogr 10:907–913

    Google Scholar 

  • Cahn JW (1968) Spinodal decomposition. Trans Metall Soc AIME 242:166–180

    Google Scholar 

  • Carpenter MA, Salje E (1993) Thermodynamics of non-convergent cation ordering in minerals. III. Order parameter coupling in K-feldspar. Am Mineral (in press)

  • Christofferson RG, Yund RA, Tullis J (1983) Inter-diffusion of K and Na in alkali feldspars: diffusion couple experiments. Am Mineral 68:1126–1133

    Google Scholar 

  • Day HW, Brown VM (1980) Evolution of perthite compositions and microstructure during progressive metamorphism of hypersolvus granite, Rhode Island, USA. Contrib Mineral Petrol 72:353–365

    Google Scholar 

  • Dodson MH (1973) Closure temperature in cooling geochronological and petrological systems. Contrib Mineral Petrol 40:259–274

    Google Scholar 

  • Dodson MH (1986) Closure profiles in cooling systems. Mater Sci For 7:145–154

    Google Scholar 

  • Elkins LT, Grove TL (1990) Ternary feldspar experiments and thermodynamic models. Am Mineral 75:544–559

    Google Scholar 

  • Evangelakakis C (1992) Die Entmischungs- und Umwandlungsgefüge der granulitfaziellen Feldspäte Sri Lankas — lichtmikroskopische und elektronenmikroskopische, röntgenographische und mikroanalytische Untersuchungen. PhD thesis, Westfälische Wilhelms-Universität Münster, Germany

  • Foland KA (1974) Alkali diffusion in orthoclase. In: Hofmann AW, Gilett BJ, Yoder HS Jr, Yund RA (eds) Geochemical transport and kinetics. Carnegie Inst Washington Academic Press, New York, pp 77–98

    Google Scholar 

  • Fuhrman ML, Lindsley DH (1988) Ternary-feldspar modeling and thermometry. Am Mineral 73:201–215

    Google Scholar 

  • Ganguly J, Saxena SK (1987) Mixtures and mineral reactions. Springer, Berlin Heidelberg New York

    Google Scholar 

  • Geological Map of Sri Lanka, 8 miles to one inch (1982) Geol Surv Dep, Colombo, Sri Lanka

  • Hölzl S, Köhler H, Kröner A, Jaeckel P, Licw TC (1991) Geochronology of the Sri Lankan basement. In: Kröner A (ed) The crystalline crust of Sri Lanka. I. Summary of research of the German-Sri Lankan Consortium. Geol Surv Dep of Sri Lanka, Prof Pap 5:237–257

  • Hovis GL, Delbove F, Bose MR (1991) Gibbs energies and entropies of K−Na mixing for alkali feldspars from phase equilibrium data: implications for feldspar solvi and short-range order. Am Mineral 76:913–927

    Google Scholar 

  • Kay SM (1977) The origin of antiperthites in anorthosites. Am Mineral 62:905–912

    Google Scholar 

  • Kleinschrodt R (1993) Large scale thrusting in the lower crustal basement of Sri Lanka. Precambrian Res (in press)

  • Kleinschrodt R, Voll G, Kehelpannala W (1991) A layered basic intrusion, deformed and metamorphosed in granulite facies of the Sri Lanka basement. Geol Rundsch 80:779–800

    Google Scholar 

  • Kroll H (1984) Thermal expansion of alkali feldspars. In: Brown WL (ed) Feldspars and Feldspathoids. Reidel Publ Co, Dordrecht, pp 163–205

    Google Scholar 

  • Kroll H, Ribbe PH (1987) Determining (Al,Si) distribution and strain in alkali feldspars using lattice parameters and diffraction-peak positions: a review. Am Mineral 72:491–506

    Google Scholar 

  • Kroll H, Krause C, Voll G (1991) Disordering, re-ordering and unmixing in alkali feldspars from contact-metamorphosed quartzites. In: Voll G, Töpel J, Pattison DRM, Seifert F (eds) Equilibrium and kinetics in contact metamorphism. Springer, Berlin Heidelberg New York, pp 267–473

    Google Scholar 

  • Kroll H, Evangolakakis C, Voll G (1993) Two-feldspar geothermometry: a review and revision for slowly cooled rocks. Contrib Mineral Petrol 114:510–518

    Google Scholar 

  • Kusatz B, Kroll H, Kaiping A, Pentinghaus H (1987) Mechanismus und Kinetik von Entmischungsvorgängen am Beispiel Ge-substituierter Alkalifeldspäte. Fortschr Mineral 65:203–248

    Google Scholar 

  • McLaren AC (1974) Transmission electron microscopy of the feldspars. In: McKenzie WS, Zussman J (ed) The feldspars. Manchester Univ. Press, Manchester, pp 378–423

    Google Scholar 

  • Medenbach O (1986) Ein modifiziertes Kristallbohrgerät nach Verschure (1978) zur Isolierung kleiner Einkristalle aus Dünnschliffen. Fortschr Mineral 64 Beihe 1:113

    Google Scholar 

  • Mora CI, Valley JW (1985) Ternary feldspar thermometry in granulites from the Oaxacan Complex, Mexico. Contrib Mineral Petrol 89:215–225

    Google Scholar 

  • Parsons I (1978) Feldspars and fluids in cooling plutons. Mineral Mag 42:1–17

    Google Scholar 

  • Parsons I, Brown WL (1984) Feldspars and the thermal history of igneous rocks. In: Brown WL (ed) Feldspars and feldspathoids, D Reidel Publ Co, Dordrecht, pp 317–371

    Google Scholar 

  • Parsons I, Brown WL (1991) Mechanisms and kinetics of exsolution-structural control of diffusion and phase transformations in alkali feldspars. In: Ganguly J (ed) Diffusion, atomic ordering, and mass transport. (Advances in physical geochemistry, vol 8) Springer, Berlin Heidelberg New York, pp 304–344

    Google Scholar 

  • Pouchou J-L, Pichoir F (1984) A new model for quantitative X-ray microanalysis. Rech Aerosp 3:13–38

    Google Scholar 

  • Raith M, Faulhaber S, Hoffbauer R, Spiering B (1991) Characterization of high-grade metamorphism in the southern part of Sri Lanka. In: Kröner A (ed) The crystalline crust of Sri Lanka. I. Summary of research of the German-Sri Lankan Consortium. Geol Surv Dep of Sri Lanka, Prof Pap 5, pp 164–177

  • Ribbe PH (1983) Aluminum-silicon order in feldspars: domain textures and diffraction patterns. In: Ribbe PH (ed) Feldspar Mineralogy. (Reviews in mineralogy, 2, 2nd edn) Mineral Soc Am, Washington DC, pp 21–55

    Google Scholar 

  • Salje E, Kuscholke B, Kroll H (1985) Thermodynamics of sodium feldspar. II. Experimental results and numerical calculations. Phys Chem Miner 12:99–107

    Google Scholar 

  • Schenk V, Raase P, Schumacher R (1991) Metamorphic zonation and P−T history of the highland complex in Sri Lanka. In: Kröner A (ed) The crystalline crust of Sri Lanka. I. Summary of research of the German-Sri Lankan Consortium. Geol Surv Dep of Sri Lanka, Prof Pap 5:150–163

  • Schumacher R, Faulhaber S (1993) Evaluation of P−T estimates on garnet-pyroxene-plagioclase-quartz bearing granulite-facies rocks from Sri Lanka. Precambrian Res (in press)

  • Schumacher R, Schenk V, Raase P, Vitanage PW (1990) Granulite facies metamorphism of metabasic and intermediate rocks in the Highland Series of Sri Lanka. In: Ashworth JR, Brown M (eds) High-grade metamorphism and crustal anatexis. Allen and Unwin, London, pp 235–271

    Google Scholar 

  • Sipling PJ, Yund RA (1976) Experimental determination of the coherent solvus for sanidine-high albite. Am Mineral 61:897–906

    Google Scholar 

  • Smith JV (1974) Feldspar minerals. I. Crystal structure and physical properties. Springer, Berlin Heidelberg New York

    Google Scholar 

  • Smith JV, Brow WI (1988) Feldspar minerals, vol 1, 2nd edn. Springer Verlag, Berlin Heidelberg New York

    Google Scholar 

  • Speer JA, Ribbe PH (1973) The feldspars of the Kiglapait intrusion, Labrador. Am J Sci 273A:468–478

    Google Scholar 

  • Voll G (1969) Klastische Mineralien aus den Sedimentserien der Schottischen “Highlands” und ihr Schicksal bei aufsteigender Regional- und Kontaktmetamorphose. Habilitation thesis, Berlin

  • Voll G, Kleinschrodt R (1991) Sri Lanka: structural, magmatic and metamorphic development of a Gondwana fragment. In: Kröner A (ed) The crystalline crust of Sri Lanka. I. Summary of research of the German-Sri Lankan Consortium. Geol Surv Dep of Sri Lanka, Prof Pap 5, pp 22–51

  • Voll G, Evangelakakis C, Kroll H (1993) Revised two-feldspar geothermometry applied to Sri Lankan feldspars. Precambrian Res (in press)

  • Willaime C, Gandais M (1972) Study of exsolution in alkali feldspars calculation of elastic stresses inducing periodic twins. Phys Status Solidi 9:529–539

    Google Scholar 

  • Worden RH, Walker FDL, Parsons I, Brown WL (1990) Development of microporosity, diffusion channels and deuteric coarsening in perthitic alkali feldspars. Contrib Mineral Petrol 104:507–515

    Google Scholar 

  • Yund RA (1983a) Microstructure, kinetics and mechanisms of alkali feldspar exsolution. In: Ribbe PH (ed) Feldspar mineralogy. (Reviews in mineralogy, vol 2, 2nd edn) Mincral Soc Am, Washington DC, pp 177–202

    Google Scholar 

  • Yund RA (1983b) Diffusion in feldspars. In: Ribbe PH (ed) Feldspar mineralogy. (Reviews in mineralogy, vol 2, 2nd edn) Mincral Soc Am, Washington DC, pp 203–239

    Google Scholar 

  • Yund RA (1984) Alkali feldspar exsolution: kinetics and dependence on alkali interdiffusion. In: Brown WL (ed) Feldspars and feldspathoids, D Reidel Publ Co, Dordrecht, pp 281–315

    Google Scholar 

  • Yund RA, Ackermand D (1979) Development of perthite and microstructures in the Storm King Granite, N.Y. Contrib Mineral Petrol 70:273–280

    Google Scholar 

  • Yund RA, Tullis J (1983) Strained cell parameters for coherent lamellae in alkali feldspars and iron-free pyroxenes. Neues Jahrb Miner Monatsh 1:22–34

    Google Scholar 

  • Yund RA, Ackermand D, Seifert F (1980) Microstructures in the alkali feldspars from the granulite complex of Finnish Lapland. Neues Jahrb Mineral Monatsh 3:109–117

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Evangelakakis, C., Kroll, H., Voll, G. et al. Low-temperature coherent exsolution in alkali feldspars from high-grade metamorphic rocks of Sri Lanka. Contr. Mineral. and Petrol. 114, 519–532 (1993). https://doi.org/10.1007/BF00321756

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00321756

Keywords

Navigation