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Voltammetric determination of nickel and palladium in plating baths

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  • Metal Analysis
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Summary

A simultaneous determination of nickel and palladium in plating baths was carried out at the hanging mercury drop electrode (HMDE), using the dc and ac single-sweep techniques, direct in the bath sample diluted with ammonia buffer. The influences of Co, Pb, Zn, Cd and the concentration of ammonia buffer on the peak shapes of Ni and Pd and on their resolution were studied. The possible determination of Cd and Pb contamination in plating baths in the same solution by anodic stripping voltammetry is also indicated. The essential advantages of the described method are: its simplicity, rapidity and very small consumption of mercury. The detailed analytical procedure is given. Relative standard deviations were found to be 3.1% for Pd and 2.6% for Ni.

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References

  1. Raoot S, Raoot KN (1986) Talanta 33:544–546

    Google Scholar 

  2. Roshokova TS (1982) Sredstwa Svyazu 1:67–68

    Google Scholar 

  3. Danilov IP (1982) Vestn Khark Politekh Inst 195:69–70

    Google Scholar 

  4. Childers TC, Moricuse P, Reiss JJ, Vohra SK (1985) Int Lab 1–2:70–77

    Google Scholar 

  5. Sacha S (1984) Chem Anal (Warsaw) 29:449–453

    Google Scholar 

  6. Romanova AD, Michnik MA (1984) Zav Lab 50:13–14

    Google Scholar 

  7. Heigl A (1978) Chimia 32:339–350

    Google Scholar 

  8. Lostura ID (1983) Plating Surf Finish 70:70–73

    Google Scholar 

  9. Rubel S, Golimowski J, Wojciechowski M (1974) Chem Anal (Warsaw) 19:41–52

    Google Scholar 

  10. Golimowski J, Rubel S (1974) Chem Anal (Warsaw) 19:1155–1166

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, University of Warsaw, Poland

    J. Golimowski

  2. Institute for Technology of Electronic Materials, Warsaw, Poland

    E. Najdeker

Authors
  1. J. Golimowski
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  2. E. Najdeker
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Golimowski, J., Najdeker, E. Voltammetric determination of nickel and palladium in plating baths. Fresenius J Anal Chem 339, 868–870 (1991). https://doi.org/10.1007/BF00321666

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  • DOI: https://doi.org/10.1007/BF00321666

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