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Deformation twinning in calcite, dolomite, and other rhombohedral carbonates

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Abstract

Transmission electron microscope (tem) observations of single and multiple twins in calcite and dolomite are presented, and the results are analysed by means of selected area diffraction and trace analysis. Simple twinning in rhodochrosite and kutnahorite is also analysed. It is shown that the ordered carbonates, such as dolomite, have a common twinning plane {01\(\bar 1\)2} and this appears to be their only mode of deformation twinning. The carbonates with higher symmetry, such as calcite, have {01\(\bar 1\)8} as the primary twinning plane but calcite itself has other twinning mechanisms, of which the most important is illustrated. Crossing and stopping twins are also discussed. It is shown that twinning in calcite, which occurs predominantly at low temperatures, is characterized by the generation of large numbers of glide dislocations.

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References

  • Barber, D.J.: Dislocation structures in deformed and recovered dolomites. Tectonophysics 39, 193–213 (1977)

    Google Scholar 

  • Barber, D.J., Heard, H.C., Paterson, M.S., Wenk, H.R.: Stacking faults in dolomite. Nature 269, 789–790 (1977)

    Google Scholar 

  • Barber, D.J., Wenk, H.R.: Defects in deformed calcite and carbonate rocks. In: Electron microscopy in mineralogy, Wenk, H.R. (ed.). Berlin, Heidelberg, New York: Springer 1976, pp. 428–442

    Google Scholar 

  • Barber, D.J., Wenk, H.R.: On geological aspects of calcite microstructure. Tectonophysics 54, 45–60 (1979)

    Google Scholar 

  • Baumhauer, H.: Über künstliche Kalkspath-Zwillinge nach — 1/2 R. Z. Kristallogr. 3, 588–591 (1879)

    Google Scholar 

  • Borg, I., Turner, F.J.: Deformation of Yule Marble Part VI. Bull. Geol. Soc. Am. 64, 1343–1352 (1953)

    Google Scholar 

  • Bowden, F.P., Cooper, R.E.: Velocity of twin propagation in crystals. Nature 195, 1091–1092 (1962)

    Google Scholar 

  • Bradley, W.F., Burst, J.F., Graf, D.L.: Crystal chemistry and differential thermal effects of dolomite, Ill. Geol. Surv. Rept. 167, 207–217 (1953)

    Google Scholar 

  • Braillon, P., Serughetti, J.: Mechanical twinning in calcite. Phys. Status Solidi A: 33, 405–413 (1976)

    Google Scholar 

  • Cahn, R.W.: Plastic deformation of alpha-uranium; twinning and slip. Acta Metall. 1, 49–70 (1953)

    Google Scholar 

  • Cahn, R.W.: Twinned crystals. Philos. Mag. [Suppl.] 3, 363–445 (1954)

    Google Scholar 

  • Cahn, R.W.: Mechanical twinning in molybdenum. J. Inst. Met. 83, 493–496 (1955)

    Google Scholar 

  • Coe, R.W., Kirby, S.H.: The orthoenstatite to clinoenstatite transformation by shearing and reversion by annealing: Mechanism and potential applications. Contrib. Mineral. Petrol. 52, 29–55 (1975)

    Google Scholar 

  • Deer, W.A., Howie, R.A., Zussman, J.: Rock forming minerals, vol. 5. London: Longmans 1962, pp. 242–243

    Google Scholar 

  • Dove, H.W.: Optische Notizen. Ann. Phys. 110, 286–290 (1860)

    Google Scholar 

  • Fairbairn, H.W., Hawkes, H.E.: Dolomite orientation in deformed rocks. Am. J. Sci. 239, 617–632 (1941)

    Google Scholar 

  • Garber, R.I.: Residual stresses in plastically deformed crystals of rock-salt. Zh. Eksp. Theor. Fiz. 8, 746–752 (1938)

    Google Scholar 

  • Garber, R.I.: Mechanism of twinning of calcite and sodium nitrate during plastic deformation. Zh. Eksp. Theor. Fiz. 17, 48–62 (1947)

    Google Scholar 

  • Geothem, L. Van, Landuyt, J. Van, Amelinckx, S.: The alpha-beta transition in amethyst quartz as studied by electron microscopy and diffusion. Phys. Status Solidi A: 41, 129–137 (1977)

    Google Scholar 

  • Goetze, C., Kohlstedt, D.L.: The dislocation structure of experimentally deformed marble. Contrib. Mineral. Petrol. 59, 293–306 (1977)

    Google Scholar 

  • Goldsmith, J.R.: Some aspects of the geochemistry of carbonates. In: Researches in geochemistry, vol. I, Abelson, A. (ed.). New York: John Wiley & Sons 1959, pp. 336–358

    Google Scholar 

  • Griggs, D.T.: Hydrolytic weakening of quartz and other silicates. Geophys. J.R. Astron. Soc. 14, 19–31 (1967)

    Google Scholar 

  • Griggs, D.T., Turner, F.J., Borg, I., Sosoka, J.: Deformation of Yule marble: Part V, Effects at 300° C. Bull. Geol. Soc. Am. 64, 1327–1342 (1953)

    Google Scholar 

  • Griggs, D.T., Turner, F.J., Heard, H.C.: Deformation of rocks at 500° C to 800° C. In: Rock deformation, Griggs, D.T. and Handin, J. (eds.). Geol. Soc. Am. Mem. 79, 39–104 (1960)

    Google Scholar 

  • Hauser, J., Wenk, H.R.: Optical properties of composite material (microtwins, exsolution lamellae, solid solution). Z. Kristallogr. 143, 188–219 (1976)

    Google Scholar 

  • Heard, H.C., Wenk, H.R., Barber, D.J.: Experimental deformation of dolomite single crystals to 800° C. Eos Trans. Am. Geophys. Union 59, 249–249 (1978)

    Google Scholar 

  • Higgs, D.V., Handin, J.: Experimental deformation of dolomite single crystals. Bull. Geol. Soc. Am. 70, 245–278 (1961)

    Google Scholar 

  • Johnsen, A.: Biegungen und Translationen. Neues. Jahrb. Mineral. 2, 133–153 (1902)

    Google Scholar 

  • Keith, R.E., Gilman, J.J.: Dislocation etch pits and plastic deformation in calcite. Acta Metall. 8, 1–10 (1960)

    Google Scholar 

  • Klassen-Neklyudova, M.V.: Mechanical twinning of crystals. New York: (trans. J.E.S. Bradley) Consultants Bureau 1964

    Google Scholar 

  • Laves, F.: Über den Einfluß von Ordnung und Unordnung auf mechanische Zwillingsbildung. Naturwissenschaften 30, 546 (1952a)

    Google Scholar 

  • Laves, F.: Mechanische Zwillingsbildung in Feldspaten in Abhängigkeit von Ordnung-Unordnung der Si/Al-Verteilung innerhalb des (Si, Al)4O8 Gerüstes. Naturwissenschaften 30, 546–547 (1952b)

    Google Scholar 

  • Laves, F.: I feldspati e le loro relazioni di fase. Rend. Soc. Mineral. Ital. 16, 69–100 (1960)

    Google Scholar 

  • Mahajan, S., Chin, G.Y.: The interaction of twins with existing substructure and twins in cobalt-iron alloys. Acta Metall. 22, 1113–1119 (1974)

    Google Scholar 

  • Mügge, O.: Beiträge zur Kenntnis der Strukturflächen des Kalkspathes. Neues Jahrb. Mineral. 1, pp. 32–54; 81–85 (1883)

    Google Scholar 

  • Nicholas, J.F.: The simplicity of Miller-Bravais indexing. Acta Crystallogr. 21, 880–881 (1966)

    Google Scholar 

  • Pabst, A.: Transformation of indices in twin gliding. Bull. Geol. Soc. Am. 66, 897–912 (1955)

    Google Scholar 

  • Palache, C., Berman, H., Frondel, C.: The system of mineralogy of Dana, vol. 2. New York: Wiley 1951, pp. 141–217

    Google Scholar 

  • Paterson, M.S., Turner, F.J.: Experimental deformation of strained calcite crystals in extension. In: Experimental and natural rock deformation, Paulitsch, P. (ed.). Berlin, Heidelberg, New York: Springer 1970, pp. 109–141

    Google Scholar 

  • Pfaff, F.: Versuche über den Einfluß des Drucks auf die optischen Eigenschaften doppeltbrechender Krystalle. Ann. Phys. 107, 333–338 (1859)

    Google Scholar 

  • Reusch, E.: Über eine besondere Gattung von Durchgängen in Steinsalz und Kalkspath. Ann. Phys. 132, 441–451 (1867)

    Google Scholar 

  • Rogers, A.F.: Polysynthetic twinning in dolomite. Am. Mineral. 14, 245

  • Rose, G.: Über die im Kalkspath vorkommenden hohlen Canäle. Abh. Konig. Akad. Wiss. Berlin. 23, 57–79 (1868)

    Google Scholar 

  • Startsev, V.I., Bengus, V.Z., Lavrent'ev, F.F., Soifer, L.M.: Formation of dislocations in the twinning of calcite. Kristallogr. 5, 737–743 (1960)

    Google Scholar 

  • Tenderloo, G. Van, Landuyt, J. Van, Amelinckx, S.: Electron microscopic observations of domain structure and the diffuse electron scattering in quartz and in aluminum phosphate in the vicinity of the α-β transition. Phys. Status Solidi A.: 30, K. 11 (1975)

    Google Scholar 

  • Turner, F.J.: Some geometrical aspects of experimentally induced twinning in minerals. In: Deformation twinning, vol. 25: Reed-Hill, R.E., Hirth, J.P., Rogers, H.C. (eds.). Met. Soc. (AIME) Conf. Proc. London: Gordon & Breach Scientific Publishers 1963, pp. 156–176

    Google Scholar 

  • Turner, F.J., Griggs, D.T., Heard, H.: Experimental deformation of calcite crystals. Bull. Geol. Soc. Am. 65, 883–934 (1954)

    Google Scholar 

  • Turner, F.J., Griggs, D.T., Weiss, L.E., Heard, H.: Plastic deformation of dolomite rock at 380 deg C. Am. J. Sci. 252, 477–488 (1954)

    Google Scholar 

  • Turner, F.J., Orozco, M.: Crystal bending in metamorphic calcite and its relation to associated twinning. Contrib. Mineral. Petrol. 57, 83–97 (1976)

    Google Scholar 

  • Venables, J.A.: The electron microscopy of deformation twinning. Phys. Chem. Solids 25, 685–692 (1964a)

    Google Scholar 

  • Venables, J.A.: Nucleation and propagation of deformation twins. Phys. Chem. Solids 25, 693–700 (1964b)

    Google Scholar 

  • Weiss, L.E., Turner, F.J.: Some observations on translation gliding and kinking in experimentally deformed calcite and dolomite. In: Fracture and flow of rocks, Monograph 16: Heard, H.C. et al. (eds.). Am. Geophys. Union Monograph. 1972, pp. 95–107

  • Wenk, H.R., Maurizio, R.: Kutnahorite, a rare Mn mineral from Piz Cam (Bergell Alps). Schweiz. Mineral. Petrogr. Mitt. 58, 97–100 (1978)

    Google Scholar 

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Barber, D.J., Wenk, H.R. Deformation twinning in calcite, dolomite, and other rhombohedral carbonates. Phys Chem Minerals 5, 141–165 (1979). https://doi.org/10.1007/BF00307550

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