Abstract
The elemental composition and speciation of four southern Ontario municipal solid waste landfill leachates were investigated. Leachate samples were analyzed for major cations and anions, together with the trace heavy metals Cd, Cu, Fe, Mn, Ni, Ph, and Zn. The leachates were found to contain high concentrations of alkali and alkaline earth metals and also of chloride ions. Cadmium concentrations in all of the leachate samples exceeded maximum acceptable levels for potable water. The computer model SOILCHEM was used to calculate the speciation of elements in the landfill leachates. Alkali and alkaline earth metals were predicted to exist primarily as uncomplexed metals. The heavy metals were predicted to exist as either free metals or as complexes with chloride, fulvic acid, hydroxide or sulphate. The speciation of Cd as a function of pH was investigated further for each of the leachates. Humic acid and chloride complexes dominated the aqueous chemistry of leachate Cd.
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Bennett, O. L., Menser, H. A., and Winant, W. M.: 1975, Proc. 2nd Natl. Conf. on Compl. Wat. Reuse A.I.C.E. and E.P.A. Tech. Trans. 789.
Behel, D., Nelson, D. W., and Sommers, L. E.: 1983, J. Environ. Qual. 12, 181.
Buffle, J., Deladoey, P., Greter, F. L., and Haerdi, W.: 1980, Anal. Chim. Acta 116, 255.
Chian, E. S. K. and DeWalle, F. B.: 1976, J. Environ. Eng. Div. A.S.C.E. 102, 411.
Dudley, L. M., McNeal, B. L., Baham, J. E., Coray, C. S., and Cheng, H. H.: 1987, J. Environ. Qual. 16, 341.
Emmerich, W. E., Lund, L. J., Page, A. L., and Chang, A. C.: 1982, J. Environ. Qual. 11, 182.
Evans, L. J.: 1989, Environ. Sci. Technol. 23, 1046.
Florence, T. M. and Batley, G. E.: 1980, CRC Crit. Rev. Anal. Chem. 10, 219.
Gupta, U. C., Jame, Y. W., Campbell, C. A., Leyshon, A. J. and Nicholaichuk, W.: 1985, Can. J. Soil. Sci. 65, 381.
Hahne, H. C. H. and Kroontje, W.: 1973, J. Environ. Qual. 2, 444.
Harrington, D. W., Biol, A. I., and Maris, P. J.: 1986, Water Pollut. Control 85, 45.
Hirsch, D. and Banin, A.: 1990, J. Environ. Qual. 19, 366.
Johansen, O. J. and Carlson, D. A.: 1976, Water Res. 10, 1129.
Karanassios, V. and Horlick, G.: 1986, Appl. Spear. 40, 813.
Levy, G. M. and Quaglia, A., Lazure, R. E., and McGeorge, S. W.: 1987, Spectrochim. Acta 42B, 341.
Lövgren, L. and Sjöberg, S.: 1989, Water Res. 23, 327.
Oliver, B. G., Thurman, E. M., and Malcolm, R. L.: 1983, Geochim. Cosmochim. Acta 47, 2031.
Ontario Ministry of the Environment: 1983, ‘Ontario Drinking Water Objectives’, Toronto, p. 103.
Robinson, H. D. and Maris, P. J.: 1985, J. Water Pollut. Contr. Fed. 57, 30.
Spiers, G. A., Evans, L. J., McGeorge, S. W., Moak, H. W., and Su, C.: 1990, Comm. in Soil Sci. Plant Anal. 21(13–16), 1645.
Sposito, G.: 1981, Environ. Sci. Tech. 15, 396.
Sposito, G., Bingham, F. T., Yadav, S. S., and Inouye, C. A.: 1982, Soil Sci. Soc. Am. J. 46, 51.
Sposito, G. and Coves, J.: 1988, ‘SOILCHEM: A Computer Program for the Calculation of Chemical Speciation in Soils’, The Kearney Foundation of Soil Science, University of California.
Sposito, G., Holtzclaw, K. M., and LeVesque-Madore, C. S.: 1981, Soil Sci. Soc. Am. J. 45, 465.
Sposito, G. and Mattigod, S. V.: 1979, ‘GEOCHEM: A Computer Program for the Calculation of Chemical Equilibria in Soil Solutions and Other Natural Water Systems’, Department of Soil and Environmental Sciences, University of California, Riverside, p. 110.
Technicon 1978. ‘Total Organic Carbon-Dissolved Organic Carbon in Water and Waste Water’, Ind. Method No. 455-76W/A, Tarrytown, New York.
Tipping, E. and Hurley, M. A.: 1988, J. Soil Sci. 39, 505.
Turner, D. R., Whitfield, M., and Dickson, A. G.: 1981, Geochim. Cosmochim. Acta 45, 855.
Zirino, A. and Yamamoto, S.: 1972, Limnol. Oceanogr. 17, 661.
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Bolton, K.A., Evans, L.J. Elemental composition and speciation of some landfill leachates with particular reference to cadmium. Water Air Soil Pollut 60, 43–53 (1991). https://doi.org/10.1007/BF00293965
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DOI: https://doi.org/10.1007/BF00293965