Summary
Phase separation temperatures have been determined in the system PMMA/chlorobutane + amyl acetate. This liquid mixture is a co-nonsolvent (co-precipitant) of the polymer. The molecular origin of such co-nonsolvency is discussed in terms of the interactions pressumably present in the system.
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CHEN, S. A. and LAI, W. J.: J. Appl. Polym. Sci. 23, 319 (1979)
CRUZ, C. A., BARLOW, J. W. and PAUL, D. R.: Macromolecules 12, 726 (1979)
DEB, P. C. and PALIT, S.: Makromol. Chem. 166, 227 (1973)
GEE, G.: Trans. Faraday Soc. 40, 468 (1944)
FERNANDEZ-PIEROIA, I. and HORTA, A.: Makromol. Chem. 181, 000 (1980)
MICHEL, H. and LIPPERT, E. in “Organic Liquids: Structure, Dynamics, and Chemical Properties”, BUCKINGHAM, A. D., LIPPERT, E. and BRATOS, S., editors, John Wiley & Sons, New York 1978
SPĚVÁČEK, J. and SCHNEIDER, B.: Makromol. Chem. 176, 3409 (1975)
SUZUKI, H., HIYOSHI, T. and INAGAKI, H.: J. Polym. Sci. Polym. Symposia 61, 291 (1977)
WOLF, B. A. and BLAUM, G.: J. Polym. Sci. Polym. Phys. 13, 1115 (1975)
WOLF, B. A. and MILLMS, M. M.: Makromol. Chem. 179, 2265 (1978)
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Fernández-Piérola, I., Horta, A. Co-nonsolvency of PMMA. Polymer Bulletin 3, 273–278 (1980). https://doi.org/10.1007/BF00254873
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DOI: https://doi.org/10.1007/BF00254873