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On the possibility of mechanodestruction of poly(vinyl alcohol) molecules under moderate freezing of its concentrated water solutions

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Summary

The freezing of the concentrated PVA water solutions results in obtaining (after thawing) hydrogels of non-covalent nature. In the course of a single freezing-thawing cycle there is no any noticeable destruction or covalent cross-linking of PVA macromolecules.

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References

  1. M.M.Kukharchik and N.K.Baramboim, Vysokomolekul.soed., 12B, 843 (1972).

    Google Scholar 

  2. T.Hatakeyama, Rep.Progr.Polymer Phys.Jap., 24, 211 (1981).

    Google Scholar 

  3. M.Watase, K.Nishinari and M.Nambu, Cryo-Letters, 4, 197 (1983).

    Google Scholar 

  4. V.E.Gul', L.I.Bulatnikova, O.N.Belyatskaya, E.V.Ermakova and L.V.Bykova, Vysokomolekul.soed., 18A, 118 (1976).

    Google Scholar 

  5. V.E.Gul', E.V.Ermakova, L.I.Bulatnikova, O.N.Belyatskaya, A.M.Vasserman, E.A.Penskaya and A.M.Solov'ev, Vysokomolekul.soed., 20B, 43 (1978).

    Google Scholar 

  6. V.E.Gul', E.V.Popova, L.I.Bulatnikova and O.N.Belyatskaya, Vysokomolekul.soed., 24A, 517 (1982).

    Google Scholar 

  7. L.I.Bulatnikova, E.V.Popova, O.N.Belyatskaya and V.E.Gul', Vysokomolekul.soed., 25B, 614 (1983).

    Google Scholar 

  8. M.Watase, Nippon Kagaku Kaisi, No.7, 973 (1983).

  9. M.Watase, Nippon Kagaku Kaisi, No.9, 1254 (1983).

  10. S.V.Rogozhin, V.I.Lozinsky, E.S.Vainerman, L.V.Domotenko, A.M.Mamtsis, S.A.Ivanova, M.I.Shtil'man and V.V.Korshak, Dokl.Akad.nauk SSSR, 278, 129 (1984).

    Google Scholar 

  11. V.I.Lozinsky, E.S.Vainerman, L.V.Domotenko, A.M.Mamtsis, E.F.Titova, E.M.Belavtseva and S.V.Rogozhin, Colloid & Polymer Sci., 264 (1986) — in press.

  12. M.Watase, K.Nishinari and M.Nambu, Polymer Communications, 24, 52 (1983).

    Google Scholar 

  13. M.Nagura, M. Nagura and H.Ishikawa, Polymer Communications, 25, 313 (1984).

    Google Scholar 

  14. M.Watase and K.Nishinari, J.Polym.Sci.,Polym.Phys.Ed., 23, 1803 (1985).

    Google Scholar 

  15. A.A.Berlin and E.A.Penskaya, Dokl.Akad.nauk SSSR, 110, 585 (1956).

    Google Scholar 

  16. A.A.Berlin, E.A.Penskaya and G.I.Volkova, J.Polym.Sci., 56, 477 (1962).

    Google Scholar 

  17. A.A.Berlin, Biofizika, 8, 28 (1963).

    Google Scholar 

  18. F.Patat and W.Högner, Makromol.Chem., 75, 85 (1964).

    Google Scholar 

  19. S.Opria and K.Simionescu, Vysokomolekul.soed., 8, 1132 (1966).

    Google Scholar 

  20. H.H.G.Jellinek and S.Y.Fok, Makromol.Chem., 104,18 (1967).

    Google Scholar 

  21. K.B.Abbas and R.S.Poster, J.Polym.Sci.,Polym.Chem.Ed., 14, 553 (1976).

    Google Scholar 

  22. K.B.Abbas, T.Kirschner and R.S.Poster, Eur.Polym.J., 14, 361 (1978).

    Google Scholar 

  23. O.Güven and V.Deniz, Chim.Acta Turcica, 10, 277 (1982).

    Google Scholar 

  24. V.A.Kargin and T.I.Sogolova, Zhurn.fiz.khim., 23, 540(1949).

    Google Scholar 

  25. The Encyclopaedia of Polymers, Sovetskaya Entsiklopediya Publ., Moscow, 1972, v.1, p.572.

  26. S.N.Ushakov, Poly(vinyl alcohol) and its Derivatives, Akad. nauk SSSR Publ., Leningrad, 1960, v.2, p.603.

    Google Scholar 

  27. J.G.Pritchard, Poly(vinyl alcohol). Basic Properties and Uses., Gordon & Breach Sci.Publ., London e.a., 1970, p.15.

    Google Scholar 

  28. S.P.Papkov, The Gelatinous State of Polymers., Khimia Publ., Moscow, 1974, p.20.

    Google Scholar 

  29. W.Kuhn, E.Peterli and H.Majer, J.Polym.Sci., 16, 539 (1955).

    Google Scholar 

  30. W.Kuhn and H.Majer, Angew.Chem., 68, 345 (1956).

    Google Scholar 

  31. G.B.Sergeev and V.A.Batyuk, Cryochemistry, Khimia Publ., Moscow, 1977, p182.

    Google Scholar 

  32. V.I.Lozinsky, E.S.Vainerman and S.V.Rogozhin, Inventor's Certificate of the USSR No.1008214 (1982).

  33. V.I.Lozinsky, E.S.Vainerman and S.V.Rogozhin, Colloid & Polymer Sci., 260, 776 (1982).

    Google Scholar 

  34. V.I.Lozinsky, E.S.Vainerman, G.F.Korotaeva and S.V.Rogozhin, Colloid & Polymer Sci., 262, 617 (1984).

    Google Scholar 

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Lozinsky, V.I., Domotenko, L.V., Vainerman, E.S. et al. On the possibility of mechanodestruction of poly(vinyl alcohol) molecules under moderate freezing of its concentrated water solutions. Polymer Bulletin 15, 333–340 (1986). https://doi.org/10.1007/BF00254852

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  • DOI: https://doi.org/10.1007/BF00254852

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