Skip to main content
Log in

The thermal effect in the photomechanical conversion of a photochromic polymer

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The effect of radiation on the mechanical behaviour of the crosslinked copolymer of maleic anhydride and styrene containing photochromic azo groups was investigated. The analysis of results of the observed photomechanical conversion proved a considerable influence of the thermal effect in addition to the effect of photoisomerization of the photochrome. The interpretation of some photomechanical experiments described earlier may be obscured by a rise in temperature caused by the absorption of radiation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • CHUANG J.C, DE SORGO M. and PRINS W.: J. Mechanochem. Cell. Motility, 2, 105 (1973)

    Google Scholar 

  • CORRUCCINI R.J. and GILBERT E.C.: J. Amer. Chem. Soc., 61, 2925 (1939)

    Google Scholar 

  • FLORY P.J., HOEVE C.A.J. and CIFFERI A.: J. Polym. Sci., 34, 337 (1959)

    Google Scholar 

  • MATĚJKA L.: PhD. Thesis, ÚMCH, Prague 1977

    Google Scholar 

  • MATĚJKA L., NEŠPŮREK S., KUCHARSKI M. and DUŠEK K.: Polym. Bull., 1, 167 (1978)

    Google Scholar 

  • SMETS G. and EVENS G.: Pure Appl. Chem., Macromol. Chem., 8, 357 (1973)

    Google Scholar 

  • SMETS G. and DE BLAUTE P.: Pure Appl. Chem., 39, 225 (1974)

    Google Scholar 

  • SMETS G.: J. Polym. Sci., Polym. Chem. Ed., 13, 2223 (1975)

    Google Scholar 

  • SMETS G., BRAEKEN J. and IRIE M.: Pure Appl.Chem., 50, 845 (1978)

    Google Scholar 

  • VAN DER VEEN G. and PRINS W.: Nature Phys. Sci., 230, 70 (1971)

    Google Scholar 

  • VAN DER VEEN G.: Thesis, University Groningen, 1972

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Matějka, L., Dušek, K. & Ilavský, M. The thermal effect in the photomechanical conversion of a photochromic polymer. Polymer Bulletin 1, 659–664 (1979). https://doi.org/10.1007/BF00254147

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00254147

Keywords

Navigation